Journal ArticleDOI
Positronium Annihilation in Molecular Substances
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TLDR
The behavior of the Ps atom in molecular substances, particularly liquids, is investigated in this article, where the pickoff rates of oPs in various liquid compounds are found to have a simple empirical relationship to the values of the surface tension of the liquids.Abstract:
The behavior of the Ps atom in molecular substances, particularly liquids, is investigated. The pickoff rates of o‐Ps in various liquid compounds are found to have a simple empirical relationship to the values of the surface tension of the liquids. The relationship is found to have a theoretical foundation. The Ps atom is highly localized in a cavity created by the balance of various molecular forces inside the liquid. From the above relationship, other simple relationships between the pickoff rates of o‐Ps and the various properties of the medium, e.g., polarizability, cohesive energy density, etc., and the temperature or pressure changes can be derived and explained. The diffusion of o‐Ps is discussed. A similar approach can also be used for molecular solids.read more
Citations
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Journal ArticleDOI
Exploitation of Intrinsic Microporosity in Polymer-Based Materials
Neil B. McKeown,Peter M. Budd +1 more
TL;DR: In this paper, a review of microporous materials with a particular emphasis on amorphous polymers that possess intrinsic microporosity (IM), which is defined as microporeosity that arises directly from the shape and rigidity of component macromolecules.
Journal ArticleDOI
Positron annihilation spectroscopy for chemical analysis: A novel probe for microstructural analysis of polymers☆
TL;DR: Positron annihilation spectroscopy for chemical analysis (PASCA) has been developed to analyze the microstructure of polymers as discussed by the authors, where the positronium atom is trapped in the atomic-scale holes which have a size ranging from 1 to 10 A. Theoretical aspects, experimental developments, and examples in analyzing the microstructures of epoxy, PEEK, and PMMA polymers are presented.
Journal ArticleDOI
Zeolitic imidazolate framework (ZIF-8) based polymer nanocomposite membranes for gas separation
Qilei Song,Sanna Kotrappanavar Nataraj,Mina Roussenova,Jin-Chong Tan,David J. Hughes,Wei Li,Pierre Bourgoin,M. Ashraf Alam,Anthony K. Cheetham,Shaheen A. Al-Muhtaseb,Easan Sivaniah +10 more
TL;DR: In this paper, the authors synthesized ZIF-8 nanoparticles (size ∼ 60 nm and specific surface area ∼ 1300-1600 m2 g−1) were directly incorporated into a model polymer matrix (Matrimid® 5218) by solution mixing.
Journal ArticleDOI
Defect identification in semiconductors with positron annihilation: Experiment and theory
Filip Tuomisto,Ilja Makkonen +1 more
TL;DR: Positron annihilation spectroscopy is particularly suitable for studying vacancy-type defects in semiconductors and combining state-of-the-art experimental and theoretical methods allows for detailed identification of the defects and their chemical surroundings as mentioned in this paper.
Journal ArticleDOI
Gas permeation parameters and other physicochemical properties of a polymer of intrinsic microporosity: Polybenzodioxane PIM-1
Peter M. Budd,Neil B. McKeown,Bader S. Ghanem,Kadhum J. Msayib,Detlev Fritsch,Ludmila Starannikova,N. A. Belov,Olga Sanfirova,Yuri Yampolskii,Victor P. Shantarovich +9 more
TL;DR: A detailed study of gas permeation, thermodynamic properties and free volume was performed for a novel polymer of intrinsic microporosity (PIM-1) using both gas chromatographic and barometric methods as discussed by the authors.
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Molecular theory of gases and liquids
TL;DR: Molecular theory of gases and liquids as mentioned in this paper, molecular theory of gas and liquids, Molecular theory of liquid and gas, molecular theories of gases, and liquid theory of liquids, مرکز