Precipitation of the δ-Ni 3 Nb phase in two nickel base superalloys
01 Mar 1988-Metallurgical and Materials Transactions A-physical Metallurgy and Materials Science (Springer-Verlag)-Vol. 19, Iss: 3, pp 453-465
TL;DR: In this article, the precipitation of the metastable δ-Ni3Nb phase has been studied in two niobium bearing nickel base superalloys and the morphology and distribution of precipitates have been examined and the crystallographic orientation relationship between the austenite and the δ phases has been determined.
Abstract: The precipitation of the equilibrium δ-Ni3Nb phase has been studied in two niobium bearing nickel base superalloys—INCONEL 718 and INCONEL* 625—both of which are hardenable by the precipitation of the metastableγ″-Ni3Nb phase. The morphology and the distribution of precipitates have been examined and the crystallographic orientation relationship between the austenite and theδ phases has been determined. The nucleation of theδ phase at stacking faults within pre-existing δ" precipitates has been discussed.
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TL;DR: In this article, the δ phase evolution and its effect on the austenite grain growth in the solution treatment of superalloy GH4169 were investigated at the solution temperatures of 1233, 1253, 1273 and 1293 K and the holding time of 30, 45 and 60 min.
Abstract: The δ phase evolution and its effect on the austenite grain growth in the solution treatment of superalloy GH4169 were investigated at the solution temperatures of 1233, 1253, 1273 and 1293 K and the holding time of 30, 45 and 60 min. The δ phase is dissolved and transformed from short bars to fine bars or particles gradually with the increasing solution temperature. The holding time affects the morphology and the amount of δ phase slightly. The austenite grain grows with the increasing solution temperature and holding time. It grows slowly at the solution temperatures ranging from 1233 to 1373 K, but sharply from 1273 to 1293 K. The phenomenon suggests that the δ phase generates a pinning effect on the austenite grain growth. The kinetic analysis about the austenite grain growth was carried out at the solution temperatures ranging from 1233 to 1373 K. The grain growth exponent n value is calculated to be 1·2 which confirms the pinning effect of δ phase on the austenite grain growth, and activatio...
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TL;DR: In this article , a procedure for preparing atom probe tomography (APT) tips from mechanically prepared ribbons by using plasma focused ion beam microscopy (PFIB) is proposed.
Abstract: Abstract Plasma focused ion beam microscopy (PFIB) is a recent nanofabrication technique that is suitable for site-specific atom probe sample preparation. Higher milling rates and fewer artifacts make it superior to Ga+ FIBs for the preparation of samples where large volumes of material must be removed, for example, when trying to avoid lift-out techniques. Transmission Kikuchi diffraction (TKD) is a method that has facilitated phase identification and crystallographic measurements in such electron transparent samples. We propose a procedure for preparing atom probe tomography (APT) tips from mechanically prepared ribbons by using PFIB. This is highly suitable for the preparation of atom probe tips of interfaces such as interphase boundaries from challenging materials where lift-out tips easily fracture. Our method, in combination with TKD, allows the positioning of regions of interest such as interfaces close to the apex of the tip. We showcase the efficacy of the proposed method in a case study on Alloy 718, where the interface between γ-matrix and δ-phase has not been yet extensively explored through APT due to preparation challenges. Results show depletion of γ″-precipitates near the γ/δ interface. A quantitative evaluation of the composition of phases in the bulk versus near the interface is achieved.
5 citations
TL;DR: In this paper , two blocks of Inconel 625 (IN625) and Stainless steel 304L (SS304L) metal powders were deposited on an SS304L substrate using laser directed energy deposition (DED) technique.
Abstract:
Purpose
Prior to manufacturing, designing plays a vital role in the selection of materials and other design parameters. Therefore, during the deposition of materials, substrate materials provide support and affect the microstructure of the deposits, which may not be desirable in the manufactured product. Hence, the main purpose of the study is to analyse the behaviour of the microstructure at the interface of deposited material and substrate.
Design/methodology/approach
In this study, two blocks of Inconel 625 (IN625) and Stainless steel 304L (SS304L) metal powders were deposited on an SS304L substrate using laser directed energy deposition (DED) technique. Deposited blocks comprised 50% IN625 + 50% SS304L or 100% IN625. After deposition, microstructural behaviour at the interface of the deposits and substrates was analysed using different tests such as optical microscopy (OM), microhardness testing, X-ray diffraction (XRD), scanning electron microscopy (SEM) and energy dispersive X-ray spectroscopy (EDS). An improvement in microstructure was proposed by performing heat treatment of the deposited sample.
Findings
Formation of martensite and precipitates at the interface of the deposit and substrate was observed. Formation of martensite and precipitates such as α, carbide and δ phases were observed in OM and SEM images. Due to the formation of these phases, interface regions showed a peak in the hardness graphs. Post-heat treatment of the samples was one of the solutions to resolve these issues.
Originality/value
This paper suggests the formation of a heat-affected zone (HAZ) at the interface of the deposit and substrate, which may negatively affect the overall utility of the deposited part. The properties of the HAZ were investigated. To suppress these detrimental effects, post-heat treatment of the deposited sample was performed, and the samples were further analysed. The post-heat-treated samples exhibited as reduction in HAZ thickness and had more uniform hardness throughout the cross-section compared with the untreated samples.
5 citations
TL;DR: In this paper, a new alloy was used for confectioning the dies used for copper/brass hot extrusion made of tool steels and an experiment was performed to justify the migration to this new alloy.
Abstract: The dies used for copper/brass hot extrusion made of tool steels failed after a small number of runs. The die must be either refurbished (reconditioned) either discarded or replaced by a new die. These results are not satisfactory for a good production, so we took into account a new alloy to use for confectioning the dies. Before the first die was readily made, an experiment was performed to justify the migration to this new alloy. Heating cycles are performed to observe microstructure evolution in Rene 41. These heating cycles mimic the usage conditions of the die in service, except the stresses during extrusion. The alloy at specific number of cycles is analyzed by optic and electron microscopy (SEM), X-ray diffraction analysis (XRD), Vickers microhardness investigations and dilatometric tests. Minor changes occurred in the microstructure: M23C6 carbides appeared at grain boundary and depleted adjacent regions in alloying elements.
5 citations
01 Dec 2018
TL;DR: The orthorhombic DOa Ni3Nb delta phase is naturally presented in microstructure of cast or wrought Ni - Cr - Fe base alloy 718 as mentioned in this paper.
Abstract: The orthorhombic DOa Ni3Nb delta phase is naturally presented in microstructure of cast or wrought Ni - Cr - Fe base alloy 718. It is a reason of chemical composition heterogeneity. For delta phase formation is a minimum Nb content about 8% needed and temperature above 650°C and higher. A typical place, where delta phase is situated are grain boundaries in alloy 718, where its role is discutable. Some references saying about lowering the mechanical properties when delta phase is segregated at grain boundary. To approve or disprove of this fact, the wrought alloy 718 with ASTM 12 grain size was subjected to high-temperature loading at push - pull fatigue at low cycle and low frequency (LCLF) and obtained results were compared to results from very high cycle and frequency (VHCF) push - pull loading datas obtained in previous experiments done at room temperature. To support results about influence of delta phase formation an observation on light microscopy and SEM was made too. To increase and make easier identification of delta phase, the techniques of polarised light (DIC - Differential Interferential Contrast) and dark-field (DF) observation were used too.
5 citations
References
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Book•
01 Jan 1958
TL;DR: The Handbook of Lattice spacings and structures of metals and alloys as discussed by the authors is a handbook of argumentative essay structure spacing and lattice plane model modified by the incorporation of thermodynamic functions appropriate to the f.c.
Abstract: For the best product experience, a Handbook of of argumentative essay structure spacing Lattice Spacings and Structures of Metals and Alloys ScienceDirect. Get this from a library! A handbook of lattice spacings and structures of metals and alloys. (W B Pearson) Acm metal). Vol. lattice plane model modified by the incorporation of thermodynamic functions appropriate to the f.c.c. Al—Ag solid zones in the alloys. W. B. Pearson, Handbook of Lattice Spacings. Structures of Metals and Alloys.
3,090 citations
Book•
01 Jan 1962
TL;DR: Modern Physical Metallurgy as mentioned in this paper describes the fundamental principles of physical metallurgy and the basic techniques for assessing microstructure and provides a balanced coverage of properties, characterization, phase transformations, crystal structure, and corrosion not available in other texts.
Abstract: Modern Physical Metallurgy describes, in a very readable form, the fundamental principles of physical metallurgy and the basic techniques for assessing microstructure This book enables you to understand the properties and applications of metals and alloys at a deeper level than that provided in an introductory materials course The eighth edition of this classic text has been updated to provide a balanced coverage of properties, characterization, phase transformations, crystal structure, and corrosion not available in other texts, and includes updated illustrations along with extensive new real-world examples and homework problems It offers renowned coverage of metals and alloys from one of the world's leading metallurgy educators It covers new materials characterization techniques, including scanning tunneling microscopy (STM), atomic force microscopy (AFM), and nanoindentation It provides the most thorough coverage of characterization, mechanical properties, surface engineering and corrosion of any textbook in its field It includes new worked examples with real-world applications, case studies, extensive homework exercises, and a full online solutions manual and image bank
421 citations
TL;DR: In this article, a review of theoretical models applicable to concentrated solid solutions is presented, focusing on concentrated solutions because dilute ones can be considered as special cases and because the interesting effects of clustering and ordering are most apparent at high solute concentrations.
Abstract: Publisher Summary This chapter reviews current theoretical models applicable to concentrated solid solutions. It focuses on concentrated solutions because dilute ones can be considered as special cases and because the interesting effects of clustering and ordering are most apparent at high solute concentrations. The extended ranges of solubility are often found in metallic systems, and for this reason most examples selected will refer to metals and alloys, although the models presented are equally applied to off-stoichiometric compounds, metallic or inorganic, and to amorphous solids. The chapter provides description of the state of the order of the system through suitable averaging procedures. It discusses the internal energy of solutions, from both electronic and elastic standpoints. The chapter presents free energy models, such as generalized Bragg- Williams's model, Landau theory, and cluster variation method. These models are applied to the study of phase equilibrium.
308 citations
01 Jan 1971-Metallurgical and Materials Transactions B-process Metallurgy and Materials Processing Science
TL;DR: In this article, a heat treatment for 706 alloy was developed which effectively optimizes the 1200°F stress-rupture properties of the alloy by precipitation of globular to plate-like Ni3Cb/Ni3Ti at the grain boundaries in conjunction with maintaining a fine as-forged grain structure.
Abstract: Evaluation of a commercial heat treatment for 706 alloy indicated that it resulted in relatively low 1200° F stress rupture ductility. It was determined that this was caused by a solution treatment which dissolved all of the age-hardening phases in the alloy and caused a coarse grain size and supersaturated matrix condition. Based upon extensive fine structure study of the 706 alloy as well as previous experience with 718 alloy and other Fe−Ni-base superalloys, a heat treatment is developed which effectively optimizes the 1200°F stress-rupture properties of the alloy. The key to best properties was found to be the precipitation of globular to plate-like Ni3Cb/Ni3Ti at the grain boundaries in conjunction with maintaining a fine as-forged grain structure.
44 citations