Journal ArticleDOI
Preparation and properties of aromatic-aliphatic cardopolyamides from phenoxathiins and thianthrenes
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TLDR
In this paper, several new aromatic-aliphatic cardopolyamides containing phenoxathiin and thianthrene derivatives were prepared by the direct polycondensation of 2,8-phenoxathyin-bis(γ-ketobutyric acid) (PA) or 2,7-thian-threne-bis (γ-ketabolitioned) (TA) with 3,3-bis-4-aminophenyl phthalide (PDA), 9,9-bis-(4-amino-phthalide)Abstract:
Several new aromatic-aliphatic cardopolyamides containing phenoxathiin and thianthrene derivatives were prepared by the direct polycondensation of 2,8-phenoxathiin-bis(γ-ketobutyric acid) (PA) or 2,7-thianthrene-bis(γ-ketobutyric acid) (TA) with 3,3-bis(4-aminophenyl phthalide) (PDA), 9,9-bis(4-aminophenyl fluorene (FDA), or 9,9-bis(4-aminophenyl) anthrone (ADA) in a triphenyl phosphite-pyridine system. The cardopolyamides were obtained in 80–95% yield and possessed viscosities in the range 0.90-1.35 dl/g. They showed better solubility and heat resistance than analogous noncardopolyamides derived from conventional diamines. All the polymers were characterised by IR spectra, density, solubility, crystallinity and thermal analysis. Integral procedural decomposition temperatures (IPDT) were calculated from the primary thermograms in the temperature range 100–650°C to give quantitative data regarding the thermal stabilities. The molecular weight and molecular weight distribution of the polyamides were determined by gel-permeation chromatography (GPC).read more
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Cardo polyheteroarylenes. Synthesis, properties, and characteristic features
TL;DR: The characteristic features of the synthesis and properties of cardo polyheteroarylenes (polyarylates, aromatic polyethers, polyamides, polyimides and polyoxadiazoles) are examined and surveyed in this paper.
Journal ArticleDOI
Synthesis and characterization of a novel polyamide: polycondensation of 2,5-diaminothiazole with terephthalic acid
TL;DR: In this article, a novel polyamide, i.e., poly(thiazoleterephthalamide), was synthesized by polycondensation of 2,5-diaminothiazole (DAT) with terephthalic acid (TPA) in N -methyl-2-pyrrolidone (NMP) as solvent at 225-230°C under nitrogen atmosphere.
Journal ArticleDOI
Synthesis of Polyester Containing Chalcone Linkage as Conducting Polymer
TL;DR: In this article, the synthesis and characterization of polyesters comprising 4,4′-dihydroxy bischalcone as main chain moiety was reported and the polymers were characterized by IR and elemental analysis.
References
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Estimating Thermal Stability of Experimental Polymers by Empirical Thermogravimetric Analysis
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Studies on reactions of the N‐phosphonium salts of pyridines. XIV. Wholly aromatic polyamides by the direct polycondensation reaction by using phosphites in the presence of metal salts
TL;DR: In this article, a poly-p-benzamide of high molecular weight (ηinh = ∼ in H2SO4) was obtained by direct polycondensation reaction of p-aminobenzoic acid (p-ABA) by means of diphenyl and triaryl phosphites in N-methylpyrrolidone (NMP)-pyridine solution containing lithium and calcium chlorides.
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A preliminary report of structural studies on polyethylene oxide-urea complex
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Aromatic polyamides. V. Substituent effect on thermal properties
Y. P. Khanna,Eli M. Pearce +1 more
TL;DR: In this paper, the effect of electron-withdrawing substituents such as chloro and nitro in increasing the thermo-oxidative resistance of the polyamides is pointed out.
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Preparation and properties of polymides from 3,4′‐ and 4,4′‐oxydianiline and various aliphatic and aromatic diacids
TL;DR: Aromatic-aliphatic polyamides of high molecular weight were obtained by direct polycondensation of 3,4′- and 4,4''-oxydianiline with aliphatic diacids with 4-10 methylene groups in a triphenyl phosphite/pyridine system.