scispace - formally typeset
Open AccessBook

Principles and applications of organotransition metal chemistry

Reads0
Chats0
TLDR
A perspective survey of organotransition metal complexes according to ligand substitution processes can be found in this paper, with a focus on transition metal complexes with metal carbon-bonded ligands.
Abstract
A perspective Bonding Survey of organotransition metal complexes according to ligand Ligand substitution processes Oxidative-addition and reductive elimination Intramolecular insertion reactions Nucleophilic attack on ligands coordinated to transition metals Electrophilic attacks on coordinated ligands Metallacycles Homogeneous catalytic hydrogenation, hydrosilation, and hydrocyanation Catalytic polymerization of olefins and acetylenes Catalytic reactions involving carbon monoxide Synthetic applications of transition metal hydrides Synthetic applications of transition metal complexes containing metal carbon bonds Synthetic applications of transition metal carbonyl compounds Synthetic application of transition metal carbenes and metallacycles Synthetic applications of transition metal alkene, diene, and duenyl complexes Synthetic applications of transition metal alkyne complexes Synthetic applications of -allyl transition metal complexes Synthetic applications of transition metal arene complexes.

read more

Citations
More filters
Journal ArticleDOI

Asymmetric Transition Metal-Catalyzed Allylic Alkylations.

TL;DR: The focus of this review is on the area of enantioselective transition metal-catalyzed allylic alkylations which may involve C-C as well as C-X (X ) H or heteroatom) bond formation.
Journal ArticleDOI

Understanding and exploiting C–H bond activation

TL;DR: The recent development of promising catalytic systems highlights the potential of organometallic chemistry for useful C-H bond activation strategies that will ultimately allow us to exploit Earth's alkane resources more efficiently and cleanly as discussed by the authors.
Journal ArticleDOI

Olefin Metathesis and Beyond

TL;DR: In this paper, the authors provide an overview of the development of catalysts for olefin metathesis which combine high activity, durability, and excellent tolerance towards polar functional groups.
Journal ArticleDOI

Metal-Initiated Amination of Alkenes and Alkynes.

TL;DR: The catalytic production of organic molecules is one of the most important applications of organometallic chemistry and enantioselective syntheses of molecules bearing an amine functionality use classical stoichiometric reactions with chiral auxiliaries or utilize enantiomerically pure starting material.