Processing-property relationships of polycarbonate/graphene composites
TL;DR: In this paper, graphite and functionalized graphene sheets (FGS) were used to construct polycarbonate composites with different degrees of graphite orientation and they were processed via injection, compression molding and long-term annealing.
About: This article is published in Polymer.The article was published on 2009-07-17. It has received 611 citations till now. The article focuses on the topics: Graphite & Graphene.
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TL;DR: An overview of the synthesis, properties, and applications of graphene and related materials (primarily, graphite oxide and its colloidal suspensions and materials made from them), from a materials science perspective.
Abstract: There is intense interest in graphene in fields such as physics, chemistry, and materials science, among others. Interest in graphene's exceptional physical properties, chemical tunability, and potential for applications has generated thousands of publications and an accelerating pace of research, making review of such research timely. Here is an overview of the synthesis, properties, and applications of graphene and related materials (primarily, graphite oxide and its colloidal suspensions and materials made from them), from a materials science perspective.
8,919 citations
TL;DR: Graphene and its derivatives are being studied in nearly every field of science and engineering as mentioned in this paper, and recent progress has shown that the graphene-based materials can have a profound impact on electronic and optoelectronic devices, chemical sensors, nanocomposites and energy storage.
3,118 citations
TL;DR: In this paper, the structure, preparation and properties of polymer/graphene nanocomposites are discussed in general along with detailed examples drawn from the scientific literature, and the percolation threshold can be achieved at a very lower filler loading.
2,999 citations
TL;DR: Graphene has emerged as a subject of enormous scientific interest due to its exceptional electron transport, mechanical properties, and high surface area, and when incorporated appropriately, these atomically thin carbon sheets can significantly improve physical properties of host polymers at extremely small loading.
Abstract: Graphene has emerged as a subject of enormous scientific interest due to its exceptional electron transport, mechanical properties, and high surface area. When incorporated appropriately, these atomically thin carbon sheets can significantly improve physical properties of host polymers at extremely small loading. We first review production routes to exfoliated graphite with an emphasis on top-down strategies starting from graphite oxide, including advantages and disadvantages of each method. Then solvent- and melt-based strategies to disperse chemically or thermally reduced graphene oxide in polymers are discussed. Analytical techniques for characterizing particle dimensions, surface characteristics, and dispersion in matrix polymers are also introduced. We summarize electrical, thermal, mechanical, and gas barrier properties of the graphene/polymer nanocomposites. We conclude this review listing current challenges associated with processing and scalability of graphene composites and future perspectives f...
2,979 citations
TL;DR: A survey of the literature on polymer nanocomposites with graphene-based fillers including recent work using graphite nanoplatelet fillers is presented in this article, along with methods for dispersing these materials in various polymer matrices.
2,782 citations
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24,580 citations
TL;DR: Graphene is established as the strongest material ever measured, and atomically perfect nanoscale materials can be mechanically tested to deformations well beyond the linear regime.
Abstract: We measured the elastic properties and intrinsic breaking strength of free-standing monolayer graphene membranes by nanoindentation in an atomic force microscope. The force-displacement behavior is interpreted within a framework of nonlinear elastic stress-strain response, and yields second- and third-order elastic stiffnesses of 340 newtons per meter (N m(-1)) and -690 Nm(-1), respectively. The breaking strength is 42 N m(-1) and represents the intrinsic strength of a defect-free sheet. These quantities correspond to a Young's modulus of E = 1.0 terapascals, third-order elastic stiffness of D = -2.0 terapascals, and intrinsic strength of sigma(int) = 130 gigapascals for bulk graphite. These experiments establish graphene as the strongest material ever measured, and show that atomically perfect nanoscale materials can be mechanically tested to deformations well beyond the linear regime.
18,008 citations
TL;DR: In this paper, it is shown that to answer several questions of physical or engineering interest, it is necessary to know only the relatively simple elastic field inside the ellipsoid.
Abstract: It is supposed that a region within an isotropic elastic solid undergoes a spontaneous change of form which, if the surrounding material were absent, would be some prescribed homogeneous deformation. Because of the presence of the surrounding material stresses will be present both inside and outside the region. The resulting elastic field may be found very simply with the help of a sequence of imaginary cutting, straining and welding operations. In particular, if the region is an ellipsoid the strain inside it is uniform and may be expressed in terms of tabulated elliptic integrals. In this case a further problem may be solved. An ellipsoidal region in an infinite medium has elastic constants different from those of the rest of the material; how does the presence of this inhomogeneity disturb an applied stress-field uniform at large distances? It is shown that to answer several questions of physical or engineering interest it is necessary to know only the relatively simple elastic field inside the ellipsoid.
11,784 citations
TL;DR: In this paper, a method of calculating the average internal stress in the matrix of a material containing inclusions with transformation strain is presented. But the authors do not consider the effects of the interaction among the inclusions and of the presence of the free boundary.
7,000 citations
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25 May 1984TL;DR: An overview of diffusion and separation processes brings unsurpassed, engaging clarity to this complex topic as mentioned in this paper, which is a key part of the undergraduate chemical engineering curriculum and at the core of understanding chemical purification and reaction engineering.
Abstract: This overview of diffusion and separation processes brings unsurpassed, engaging clarity to this complex topic. Diffusion is a key part of the undergraduate chemical engineering curriculum and at the core of understanding chemical purification and reaction engineering. This spontaneous mixing process is also central to our daily lives, with importance in phenomena as diverse as the dispersal of pollutants to digestion in the small intestine. For students, Diffusion goes from the basics of mass transfer and diffusion itself, with strong support through worked examples and a range of student questions. It also takes the reader right through to the cutting edge of our understanding, and the new examples in this third edition will appeal to professional scientists and engineers. Retaining the trademark enthusiastic style, the broad coverage now extends to biology and medicine.
5,195 citations