Pyrolysis of waste animal fats in a fixed-bed reactor: Production and characterization of bio-oil and bio-char
TL;DR: In this paper, the main products (liquid bio-oil, solid bio-char and syngas) were obtained from pyrolysis of animal fatty wastes, and the maximum production of biooil was achieved at a pyroleysis temperature of 500 °C and a heating rate of 5 °C/min.
About: This article is published in Waste Management.The article was published on 2014-01-01. It has received 152 citations till now. The article focuses on the topics: Pyrolysis & Synthetic fuel.
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TL;DR: In this paper, the authors constructed the distillation curves for samples of bio-oils obtained from the thermal cracking of waste cooking oil (WCO) in order to predict the properties (such as molecular weight, viscosity and refractive index).
Abstract: Bio-oil obtained from thermal cracking of waste cooking oil (WCO) is a complex mixture of different chemical compounds and, like crude oil, it is composed mainly of hydrocarbons. The large number of compounds in bio-oil leads to complex and expensive methods for its properties determination. In this study, the distillation curves were constructed for samples of bio-oils obtained from the thermal cracking of WCO in order to predict the properties (such as molecular weight, viscosity and refractive index). Although it is not often employed for bio-oil analyses, the distillation curve method is commonly used in the petroleum industry. Atmospheric and vacuum distillations were performed according to ASTM D86 and ASTM D1160 standards, respectively, for six samples of bio-oil and one sample of crude oil. The results were converted to true boiling point (ASTM D2892) according to the API method (1997) and common petroleum refining correlations were employed. The estimated values for the properties showed little deviation in relation to the experimental data. The bio-oil and crude oil samples contained heavy compounds in their composition, and all samples studied are considered as heavy oils considering the °API range.
8 citations
01 Jan 2019
7 citations
Dissertation•
30 Jun 2015
TL;DR: In this paper, the evaluation of technologies and management systems applied to municipal solid waste (MSW) applied to Mexico City is reported, which with a population of approximately 9 million inhabitants and an estimated daily generation of 13,000 tonnes of waste, is encountering extreme waste management issues.
Abstract: The work reported involves the evaluation of technologies and management systems applied to Municipal Solid Waste (MSW). The study focuses on Mexico City, which with a population of approximately 9 million inhabitants and an estimated daily generation of 13,000 tonnes of waste, is encountering extreme waste management issues. The structures and public policies designed to provide waste management services have proved inadequate in relation to high rates of population growth and intensive business activities. The significant increase in demand has led the government of Mexico City to base public services on rudimentary techniques using obsolete equipment.The research approaches the problem through the analysis of several different aspects: (1) a comprehensive literature review of waste management including technologies and legal frameworks; (2) a general overview of the main demographic, geographic and economic aspects of Mexico City; (3) an extensive analysis of historic and future waste generation profiles and composition of waste in Mexico City; (4) an evaluation of the current status of the waste management system, including programmes, plans, facilities and infrastructure; and (5) a comparative study of the waste management system of Mexico City and the systems of selected international cities.The evaluation resulted in the identification of the following significant issues: (1) limitations in legislation related to waste management and environmental laws; (2) high population growth and increasing business activity, which contribute escalating generation of MSW; (3) ineffective public policies focused on waste management; (4) significant gaps in low levels of recycling activities; (5) obsolescence of equipment, infrastructure and facilities; (6) lack of diversification in treatment methods for MSW; and (7) failure to exploit market opportunities in the waste management sector.In addition to the evaluation of the system in Mexico City, the analysis of waste management systems in selected international cities allowed the author to identify key factors in order to develop integrated proposals. The analysis highlighted significant aspects including: legal frameworks, the participation of the private sector, waste hierarchy, and guiding principles for plans and programmes. The information enabled the design of a proposed development plan of a comprehensive waste management system in Mexico City through two main proposals.Firstly, an integrated programme for waste management in Mexico City was developed to provide feasible long-term strategies in the field of waste management. The specific objectives, goals, actions, responsibilities and time scales were defined in order to provide concrete activities under specific fields of operation.Secondly, a project to obtain funding for technology transfer structured according to technical, market and economic studies, was elaborated. The guide is aimed to exemplify an investment project through the analysis of a feasibility study related to generation of energy from biogas in a controlled landfill in Mexico City. The process may be adapted to the acquisition of technology in different sectors of the waste management process.
7 citations
Cites background from "Pyrolysis of waste animal fats in a..."
...The oil can be used directly as a liquid fuel or as a source of synthetic chemical feedstock (Hassen-Trabelsi et al., 2014)....
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TL;DR: In this article , the authors compared various conversion technologies for transforming food waste into liquid, solid, and gaseous biofuels and highlighted the challenges and opportunities for wider implementation, including the integration of supply chains and logistics of food waste management, the technological feasibility, and the persistent behaviors surrounding food waste and energy in Indonesia.
Abstract: Like many countries, Indonesia generates large quantities of food waste. Food waste is poorly managed due to inadequate treatment practices, which has a harmful impact on the environment. This paper demonstrates the high potential for food waste valorization in Indonesia and outlines the optimal valorization pathways to inform future decision-making surrounding the management of this waste. This paper also compares various conversion technologies for transforming food waste into liquid, solid, and gaseous biofuels. The challenges and opportunities for wider implementation are also considered, including the integration of supply chains and the logistics of food waste management, the technological feasibility, and the persistent behaviors surrounding food waste and energy in Indonesia. The economic and environmental benefits, the perspectives of improved food waste management practices and sustainable fuels, as well as the policy landscape surrounding waste and sustainable energy are also explored. The challenges of scalability and commercialization are also highlighted in this paper. This review demonstrates the best pathways from food waste valorization to bioenergy, including biogas or biodiesel integrated with a black soldier fly larvae (BSFL) composting system. Despite the scale of resources in Indonesia, the pathways and technologies for processing food waste are lacking. Further in-depth studies are required to demonstrate the sustainability and feasibility of food waste transformation into bioenergy to realize its high value.
7 citations
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TL;DR: A review of the recent developments in the wood pyrolysis and reports the characteristics of the resulting bio-oils, which are the main products of fast wood pyrotechnics, can be found in this paper.
Abstract: Fast pyrolysis utilizes biomass to produce a product that is used both as an energy source and a feedstock for chemical production. Considerable efforts have been made to convert wood biomass to liquid fuels and chemicals since the oil crisis in mid-1970s. This review focuses on the recent developments in the wood pyrolysis and reports the characteristics of the resulting bio-oils, which are the main products of fast wood pyrolysis. Virtually any form of biomass can be considered for fast pyrolysis. Most work has been performed on wood, because of its consistency and comparability between tests. However, nearly 100 types of biomass have been tested, ranging from agricultural wastes such as straw, olive pits, and nut shells to energy crops such as miscanthus and sorghum. Forestry wastes such as bark and thinnings and other solid wastes, including sewage sludge and leather wastes, have also been studied. In this review, the main (although not exclusive) emphasis has been given to wood. The literature on woo...
4,988 citations
"Pyrolysis of waste animal fats in a..." refers background in this paper
...For bio-oils from lignocellulosic biomass, the molecular composition is quite different since typical chemical substances related to the original polymers – cellulose, hemicellulose, and lignin – can be found (such as phenolic compounds: phenols, guaiacols, syringols and furans) besides the fatty acids, alkanes, alkenes, amides, aldehydes (Mohan et al., 2006)....
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TL;DR: Biodiesel (fatty acid methyl esters), which is derived from triglycerides by transesterification with methanol, has attracted considerable attention during the past decade as a renewable, biodegradable, and nontoxic fuel.
2,185 citations
"Pyrolysis of waste animal fats in a..." refers background in this paper
...Main research developed in the area of bio-fuels from fatty materials concerns bio-diesel production through transesterification process (Srivastava and Prasad, 2000; Fukuda et al., 2001; Demirbas, 2003; Tashtoush et al., 2004; Phan and Phan, 2008; Sabudak and Yildiz, 2010)....
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TL;DR: In this article, a review of thermal conversion processes and particularly the reactors that have been developed to provide the necessary conditions to optimise performance is presented, and the main technical and non-technical barriers to implementation are identified.
1,760 citations
"Pyrolysis of waste animal fats in a..." refers background or methods in this paper
...(Zanzi et al., 1996; Bridgwater, 2003)....
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...Pyrolysis is a thermal decomposition of organic substances under oxygen-deficient circumstances into various phases: liquid products (condensable vapors at cooling temperature); carbon-rich solid residues (bio-char); gaseous products (syngas which were not condensable gases) (Maschio et al., 1992; Bridgwater, 2003)....
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...Thermochemical processes include gasification, pyrolysis and combustion (Bridgwater, 2003; Goyal et al., 2008)....
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...%) for pyrolytic oils from different biomass resources (Bridgwater, 2003; Onay and Kochar, 2003; Demirbas, 2007; Ndiaye, 2008)....
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...The liquid product (bio-oil or pyrolytic oil), which is a complex mixture of oxygenated hydrocarbons and water, can be used directly as a liquid fuel or as source of synthetic chemical feedstocks (Bridgwater, 2003; Blin et al., 2007; Maher and Bressler, 2007)....
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TL;DR: The main advantages of using biodiesel are its renewability, better-quality exhaust gas emissions, its biodegradability and given that all the organic carbon present is photosynthetic in origin, it does not contribute to a rise in the level of carbon dioxide in the atmosphere and consequently to the greenhouse effect as mentioned in this paper.
Abstract: Efforts are under way in many countries, including India, to search for suitable alternative diesel fuels that are environment friendly. The need to search for these fuels arises mainly from the standpoint of preserving the global environment and the concern about long-term supplies of conventional hydrocarbon-based diesel fuels. Among the different possible sources, diesel fuels derived from triglycerides (vegetable oils/animal fats) present a promising alternative to substitute diesel fuels. Although triglycerides can fuel diesel engines, their high viscosities, low volatilities and poor cold flow properties have led to the investigation of various derivatives. Fatty acid methyl esters, known as biodiesel, derived from triglycerides by transesterification with methanol have received the most attention. The main advantages of using biodiesel are its renewability, better-quality exhaust gas emissions, its biodegradability and given that all the organic carbon present is photosynthetic in origin, it does not contribute to a rise in the level of carbon dioxide in the atmosphere and consequently to the greenhouse effect.
1,733 citations
"Pyrolysis of waste animal fats in a..." refers background in this paper
...Main research developed in the area of bio-fuels from fatty materials concerns bio-diesel production through transesterification process (Srivastava and Prasad, 2000; Fukuda et al., 2001; Demirbas, 2003; Tashtoush et al., 2004; Phan and Phan, 2008; Sabudak and Yildiz, 2010)....
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...In comparison to GC–MS compositions of bio-oils produced from triglycerides materials pyrolysis, great similarities in the detected compounds can be found (Srivastava and Prasad, 2000; Lima et al., 2004)....
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TL;DR: Fast pyrolysis for production of liquids has developed considerably since the first experiments in the late 1970s as mentioned in this paper, leading to significant advances in process development and a wide range of reactor configurations that have been developed to meet the stringent requirements for high yields of useful liquids, for use as a fuel in boilers, engines and turbines and as a source of chemical commodities.
Abstract: Fast pyrolysis for production of liquids has developed considerably since the first experiments in the late 1970s. Many reactors and processes have been investigated and developed to the point where fast pyrolysis is now an accepted feasible and viable route to renewable liquid fuels, chemicals and derived products. It is also now clear that liquid products offer significant advantages in storage and transport over gas and heat. These advantages have caused greater attention to be paid to fast pyrolysis, leading to significant advances in process development. The technology of fast pyrolysis for liquids is noteworthy for the wide range of reactor configurations that have been developed to meet the stringent requirements for high yields of useful liquids, for use as a fuel in boilers, engines and turbines and as a source of chemical commodities. This review summarizes the key features of fast pyrolysis and the resultant liquid product and describes the major reaction systems and processes that have been developed over the last 20 years.
1,686 citations