scispace - formally typeset
Journal ArticleDOI

Quantum Dot Solar Cells. Semiconductor Nanocrystals as Light Harvesters

Prashant V. Kamat
- 18 Oct 2008 - 
- Vol. 112, Iss: 48, pp 18737-18753
Reads0
Chats0
TLDR
In this paper, three major ways to utilize semiconductor dots in solar cell include (i) metal−semiconductor or Schottky junction photovoltaic cell, (ii) polymer−smiconductor hybrid solar cell, and (iii) quantum dot sensitized solar cell.
Abstract
The emergence of semiconductor nanocrystals as the building blocks of nanotechnology has opened up new ways to utilize them in next generation solar cells. This paper focuses on the recent developments in the utilization of semiconductor quantum dots for light energy conversion. Three major ways to utilize semiconductor dots in solar cell include (i) metal−semiconductor or Schottky junction photovoltaic cell (ii) polymer−semiconductor hybrid solar cell, and (iii) quantum dot sensitized solar cell. Modulation of band energies through size control offers new ways to control photoresponse and photoconversion efficiency of the solar cell. Various strategies to maximize photoinduced charge separation and electron transfer processes for improving the overall efficiency of light energy conversion are discussed. Capture and transport of charge carriers within the semiconductor nanocrystal network to achieve efficient charge separation at the electrode surface remains a major challenge. Directing the future resear...

read more

Citations
More filters
Journal ArticleDOI

Unexpected Size Effect Observed in ZnO-Au Composite Photocatalysts

TL;DR: Mechanistic investigations revealed that the photoreduction of azobenzene proceeded via a proton-coupled electron transfer process, demonstrating that the multielectron/multiproton process was controlled by the charge separation and transfer in the nanocomposites.
Journal ArticleDOI

Functionalization of Carbon Nanoparticles and Defunctionalization-Toward Structural and Mechanistic Elucidation of Carbon "Quantum" Dots

TL;DR: In this article, small carbon nanoparticles were functionalized by low-molecular weight amino compound 3-ethoxypropylamine (EPA) for ultracompact carbon dots of bright fluorescence emissions.
Journal ArticleDOI

Carrier multiplication detected through transient photocurrent in device-grade films of lead selenide quantum dots.

TL;DR: Ultrafast electro-optical studies of device-grade films of electronically coupled quantum dots are reported that allow us to observe multiplication directly in the photocurrent and demonstrate that extra charges produced by carrier multiplication can be extracted from the quantum dots before they are lost to Auger recombination and hence can contribute to photocurrent of practical devices.
Journal ArticleDOI

Design, fabrication and modification of metal oxide semiconductor for improving conversion efficiency of excitonic solar cells

TL;DR: In this article, a review on the recent work on the design, fabrication and surface modification of nanostructured MOSs to improve the performance of excited solar cells is presented.
Journal ArticleDOI

Type-II Quantum-Dot-Sensitized Solar Cell Spanning the Visible and Near-Infrared Spectrum

TL;DR: In this article, a type-II heterostructured CdTe/CdSe core/shell nanocrystals (quantum dots, QDs) are explored as sensitizers in a QD-sensitized photoelectrochemical solar cell.
References
More filters
Journal ArticleDOI

Detailed Balance Limit of Efficiency of p‐n Junction Solar Cells

TL;DR: In this article, an upper theoretical limit for the efficiency of p−n junction solar energy converters, called the detailed balance limit of efficiency, has been calculated for an ideal case in which the only recombination mechanism of holeelectron pairs is radiative as required by the principle of detailed balance.
Journal ArticleDOI

Carbon Nanotubes--the Route Toward Applications

TL;DR: Many potential applications have been proposed for carbon nanotubes, including conductive and high-strength composites; energy storage and energy conversion devices; sensors; field emission displays and radiation sources; hydrogen storage media; and nanometer-sized semiconductor devices, probes, and interconnects.
Journal ArticleDOI

Polymer photovoltaic cells : enhanced efficiencies via a network of internal donor-acceptor heterojunctions

TL;DR: In this paper, the carrier collection efficiency and energy conversion efficiency of polymer photovoltaic cells were improved by blending of the semiconducting polymer with C60 or its functionalized derivatives.
Journal ArticleDOI

The Optical Properties of Metal Nanoparticles: The Influence of Size, Shape, and Dielectric Environment

TL;DR: In this paper, the authors describe recent progress in the theory of nanoparticle optical properties, particularly methods for solving Maxwell's equations for light scattering from particles of arbitrary shape in a complex environment.
Journal ArticleDOI

Semiconductor Nanocrystals as Fluorescent Biological Labels

TL;DR: Semiconductor nanocrystals prepared for use as fluorescent probes in biological staining and diagnostics have a narrow, tunable, symmetric emission spectrum and are photochemically stable.
Related Papers (5)