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Journal ArticleDOI

Quantum Dot Solar Cells. Semiconductor Nanocrystals as Light Harvesters

Prashant V. Kamat
- 18 Oct 2008 - 
- Vol. 112, Iss: 48, pp 18737-18753
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TLDR
In this paper, three major ways to utilize semiconductor dots in solar cell include (i) metal−semiconductor or Schottky junction photovoltaic cell, (ii) polymer−smiconductor hybrid solar cell, and (iii) quantum dot sensitized solar cell.
Abstract
The emergence of semiconductor nanocrystals as the building blocks of nanotechnology has opened up new ways to utilize them in next generation solar cells. This paper focuses on the recent developments in the utilization of semiconductor quantum dots for light energy conversion. Three major ways to utilize semiconductor dots in solar cell include (i) metal−semiconductor or Schottky junction photovoltaic cell (ii) polymer−semiconductor hybrid solar cell, and (iii) quantum dot sensitized solar cell. Modulation of band energies through size control offers new ways to control photoresponse and photoconversion efficiency of the solar cell. Various strategies to maximize photoinduced charge separation and electron transfer processes for improving the overall efficiency of light energy conversion are discussed. Capture and transport of charge carriers within the semiconductor nanocrystal network to achieve efficient charge separation at the electrode surface remains a major challenge. Directing the future resear...

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Citations
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Journal ArticleDOI

Solid-solid interface formation in TiO2 nanoparticle networks.

TL;DR: It was found that, after annealing up to 873 K and controlled sample purification in oxygen atmosphere, both types of samples exhibit high concentrations of particle-particle interfaces and comparable properties in terms of surface area, porosity, and microstructure.
Journal ArticleDOI

Effective nanostructred morphologies for efficient hybrid solar cells

TL;DR: The potential of hybrid solar cells over the other types are reviewed in this paper, where the ability of aligned nanofibers to provide higher solar conversion efficiency is discussed and the fabrication of various nanostructures such as thin films, quantum dots, nanoparticles and composite nanofiber is highlighted.
Journal ArticleDOI

Photoexcitation dynamics of coupled semiconducting carbon nanotube thin films

TL;DR: The photoexcitation dynamics of coupled, bandgap-selected, semiconducting carbon nanotubes in thin films tailored for photovoltaics are time-resolved and the flow of energy and charge in coupled nanotube materials and light-harvesting devices is understood.
Journal ArticleDOI

Maximizing the photo catalytic and photo response properties of multimodal plasmonic Ag/WO3−x heterostructure nanorods by variation of the Ag size

TL;DR: Metal plasmon-semiconductor exciton coupling, prominent plAsmon absorbance of metal nanoparticles, and formation of an epitaxial interface are found to be the important factors to achieve the maximum photocatalytic activity and fabrication of a high speed photodetector device by employing the heterostructures.
Journal ArticleDOI

Air Stable PbSe Colloidal Quantum Dot Heterojunction Solar Cells: Ligand-Dependent Exciton Dissociation, Recombination, Photovoltaic Property, and Stability

TL;DR: In this article, a planar heterojunction solar cell (FTO/TiO2/PbSe/Au) with relatively larger active area (0.25 cm2) using tetrabutylammonium iodide (TBAI, I-) as ligand in solid state ligand exchange process was fabricated.
References
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Journal ArticleDOI

Detailed Balance Limit of Efficiency of p‐n Junction Solar Cells

TL;DR: In this article, an upper theoretical limit for the efficiency of p−n junction solar energy converters, called the detailed balance limit of efficiency, has been calculated for an ideal case in which the only recombination mechanism of holeelectron pairs is radiative as required by the principle of detailed balance.
Journal ArticleDOI

Carbon Nanotubes--the Route Toward Applications

TL;DR: Many potential applications have been proposed for carbon nanotubes, including conductive and high-strength composites; energy storage and energy conversion devices; sensors; field emission displays and radiation sources; hydrogen storage media; and nanometer-sized semiconductor devices, probes, and interconnects.
Journal ArticleDOI

Polymer photovoltaic cells : enhanced efficiencies via a network of internal donor-acceptor heterojunctions

TL;DR: In this paper, the carrier collection efficiency and energy conversion efficiency of polymer photovoltaic cells were improved by blending of the semiconducting polymer with C60 or its functionalized derivatives.
Journal ArticleDOI

The Optical Properties of Metal Nanoparticles: The Influence of Size, Shape, and Dielectric Environment

TL;DR: In this paper, the authors describe recent progress in the theory of nanoparticle optical properties, particularly methods for solving Maxwell's equations for light scattering from particles of arbitrary shape in a complex environment.
Journal ArticleDOI

Semiconductor Nanocrystals as Fluorescent Biological Labels

TL;DR: Semiconductor nanocrystals prepared for use as fluorescent probes in biological staining and diagnostics have a narrow, tunable, symmetric emission spectrum and are photochemically stable.
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