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Journal ArticleDOI

Quantum Dot Solar Cells. Semiconductor Nanocrystals as Light Harvesters

Prashant V. Kamat
- 18 Oct 2008 - 
- Vol. 112, Iss: 48, pp 18737-18753
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TLDR
In this paper, three major ways to utilize semiconductor dots in solar cell include (i) metal−semiconductor or Schottky junction photovoltaic cell, (ii) polymer−smiconductor hybrid solar cell, and (iii) quantum dot sensitized solar cell.
Abstract
The emergence of semiconductor nanocrystals as the building blocks of nanotechnology has opened up new ways to utilize them in next generation solar cells. This paper focuses on the recent developments in the utilization of semiconductor quantum dots for light energy conversion. Three major ways to utilize semiconductor dots in solar cell include (i) metal−semiconductor or Schottky junction photovoltaic cell (ii) polymer−semiconductor hybrid solar cell, and (iii) quantum dot sensitized solar cell. Modulation of band energies through size control offers new ways to control photoresponse and photoconversion efficiency of the solar cell. Various strategies to maximize photoinduced charge separation and electron transfer processes for improving the overall efficiency of light energy conversion are discussed. Capture and transport of charge carriers within the semiconductor nanocrystal network to achieve efficient charge separation at the electrode surface remains a major challenge. Directing the future resear...

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Citations
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Journal ArticleDOI

Solar PV cell materials and technologies: Analyzing the recent developments

TL;DR: In this article, a comprehensive comparative study of PV cell parameters for all generation technologies is presented, in which the distinct roles of organic and nano-components are presented, and efforts have been made in this approach to appraise the progress of each technology in the near future.
Journal ArticleDOI

A facile and low cost strategy to synthesize Cd1−xZnxSe thin films for photoelectrochemical performance: effect of zinc content

TL;DR: In this article, a facile chemical route for the deposition of Cd1−xZnxSe thin films using a simple, self-organized arrested precipitation technique (APT) was reported.
Journal ArticleDOI

A Suitable Polysulfide Electrolyte for CdSe Quantum Dot-Sensitized Solar Cells

TL;DR: In this article, a polysulfide liquid electrolyte is developed for the application in CdSe quantum dot-sensitized solar cells (QDSSCs), and a solvent consisting of ethanol and water in the ratio of 8':'2 by volume has been found as the optimum solvent for preparing the liquid electrolytes.
Journal ArticleDOI

Layer-by-Layer Quantum Dot Assemblies for the Enhanced Energy Transfers and Their Applications toward Efficient Solar Cells.

TL;DR: OQD photoluminescence showed seven times faster decay, which is attributed to the combined effect of the efficient energy transfer from OQD to BQD with the FRET efficiency of 86% and fast electron transfer from B QD to TiO2 with the rate of 1.2 × 10(9) s(-1).
Journal ArticleDOI

CdSe nanoparticles grown via radiolytic methods in aqueous solutions

TL;DR: In this paper, Cadmium selenide (CdSe) nanoparticles were synthesized in aqueous solution containing equimolar ammoniated CdSO 4 and Na 2 SeSO 3 as the starting materials without any capping agents, using gamma and electron beam irradiation under a reducing condition.
References
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Journal ArticleDOI

Detailed Balance Limit of Efficiency of p‐n Junction Solar Cells

TL;DR: In this article, an upper theoretical limit for the efficiency of p−n junction solar energy converters, called the detailed balance limit of efficiency, has been calculated for an ideal case in which the only recombination mechanism of holeelectron pairs is radiative as required by the principle of detailed balance.
Journal ArticleDOI

Carbon Nanotubes--the Route Toward Applications

TL;DR: Many potential applications have been proposed for carbon nanotubes, including conductive and high-strength composites; energy storage and energy conversion devices; sensors; field emission displays and radiation sources; hydrogen storage media; and nanometer-sized semiconductor devices, probes, and interconnects.
Journal ArticleDOI

Polymer photovoltaic cells : enhanced efficiencies via a network of internal donor-acceptor heterojunctions

TL;DR: In this paper, the carrier collection efficiency and energy conversion efficiency of polymer photovoltaic cells were improved by blending of the semiconducting polymer with C60 or its functionalized derivatives.
Journal ArticleDOI

The Optical Properties of Metal Nanoparticles: The Influence of Size, Shape, and Dielectric Environment

TL;DR: In this paper, the authors describe recent progress in the theory of nanoparticle optical properties, particularly methods for solving Maxwell's equations for light scattering from particles of arbitrary shape in a complex environment.
Journal ArticleDOI

Semiconductor Nanocrystals as Fluorescent Biological Labels

TL;DR: Semiconductor nanocrystals prepared for use as fluorescent probes in biological staining and diagnostics have a narrow, tunable, symmetric emission spectrum and are photochemically stable.
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