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Journal ArticleDOI

Quantum Dot Solar Cells. Semiconductor Nanocrystals as Light Harvesters

Prashant V. Kamat
- 18 Oct 2008 - 
- Vol. 112, Iss: 48, pp 18737-18753
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TLDR
In this paper, three major ways to utilize semiconductor dots in solar cell include (i) metal−semiconductor or Schottky junction photovoltaic cell, (ii) polymer−smiconductor hybrid solar cell, and (iii) quantum dot sensitized solar cell.
Abstract
The emergence of semiconductor nanocrystals as the building blocks of nanotechnology has opened up new ways to utilize them in next generation solar cells. This paper focuses on the recent developments in the utilization of semiconductor quantum dots for light energy conversion. Three major ways to utilize semiconductor dots in solar cell include (i) metal−semiconductor or Schottky junction photovoltaic cell (ii) polymer−semiconductor hybrid solar cell, and (iii) quantum dot sensitized solar cell. Modulation of band energies through size control offers new ways to control photoresponse and photoconversion efficiency of the solar cell. Various strategies to maximize photoinduced charge separation and electron transfer processes for improving the overall efficiency of light energy conversion are discussed. Capture and transport of charge carriers within the semiconductor nanocrystal network to achieve efficient charge separation at the electrode surface remains a major challenge. Directing the future resear...

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Citations
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Journal ArticleDOI

Electrolyte for quantum dot-sensitized solar cells assessed with cyclic voltammetry

TL;DR: In this paper, the performance of various electrolytes for quantum dot-sensitized solar cells (QDSSCs) was evaluated using cyclic voltammetry (CV) measurements.
Journal ArticleDOI

Enhanced photovoltaic performance utilizing effective charge transfers and light scattering effects by the combination of mesoporous, hollow 3D-ZnO along with 1D-ZnO in CdS quantum dot sensitized solar cells.

TL;DR: The enhanced photovoltaic performance of the solar cell is attributed to the high Brunauer-Emmett-Teller (BET) surface area, efficient light-scattering effects and facilitated diffusion of the electrolyte for better functioning of the redox couple (S( 2-)/Sn(2-)) in the hybrid photoanode.
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Comparative experiments of graphene covalently and physically binding CdSe quantum dots to enhance the electron transport in flexible photovoltaic devices

TL;DR: The results indicated that the carrier transport of the QD-graphene system is not related to the additive effect from the CdSe and graphene components but rather is a result of the unique interactions between the graphene and QDs.
Journal ArticleDOI

Controlled microwave-assisted growth of silica nanoparticles under acid catalysis.

TL;DR: These microwave methods have utility for mass production of silica nanoparticles or other nanoparticles by flow-through microwave synthetic methods for industrial applications, as well as a facile method for encapsulating or embedding materials with silica for improved functionality and stability.
Journal ArticleDOI

Novel carbon sphere@Bi2MoO6 core–shell structure for efficient visible light photocatalysis

TL;DR: In this article, a carbon sphere (CS)@Bi2MoO6 core-shell structure (CS@BMO) composites were successfully synthesized via a solvothermal reaction of CSs and Bi2MO6 precursors in the mixed solution of ethylene glycol and ethanol.
References
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Journal ArticleDOI

Detailed Balance Limit of Efficiency of p‐n Junction Solar Cells

TL;DR: In this article, an upper theoretical limit for the efficiency of p−n junction solar energy converters, called the detailed balance limit of efficiency, has been calculated for an ideal case in which the only recombination mechanism of holeelectron pairs is radiative as required by the principle of detailed balance.
Journal ArticleDOI

Carbon Nanotubes--the Route Toward Applications

TL;DR: Many potential applications have been proposed for carbon nanotubes, including conductive and high-strength composites; energy storage and energy conversion devices; sensors; field emission displays and radiation sources; hydrogen storage media; and nanometer-sized semiconductor devices, probes, and interconnects.
Journal ArticleDOI

Polymer photovoltaic cells : enhanced efficiencies via a network of internal donor-acceptor heterojunctions

TL;DR: In this paper, the carrier collection efficiency and energy conversion efficiency of polymer photovoltaic cells were improved by blending of the semiconducting polymer with C60 or its functionalized derivatives.
Journal ArticleDOI

The Optical Properties of Metal Nanoparticles: The Influence of Size, Shape, and Dielectric Environment

TL;DR: In this paper, the authors describe recent progress in the theory of nanoparticle optical properties, particularly methods for solving Maxwell's equations for light scattering from particles of arbitrary shape in a complex environment.
Journal ArticleDOI

Semiconductor Nanocrystals as Fluorescent Biological Labels

TL;DR: Semiconductor nanocrystals prepared for use as fluorescent probes in biological staining and diagnostics have a narrow, tunable, symmetric emission spectrum and are photochemically stable.
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