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Journal ArticleDOI

Quantum Dot Solar Cells. Semiconductor Nanocrystals as Light Harvesters

Prashant V. Kamat
- 18 Oct 2008 - 
- Vol. 112, Iss: 48, pp 18737-18753
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TLDR
In this paper, three major ways to utilize semiconductor dots in solar cell include (i) metal−semiconductor or Schottky junction photovoltaic cell, (ii) polymer−smiconductor hybrid solar cell, and (iii) quantum dot sensitized solar cell.
Abstract
The emergence of semiconductor nanocrystals as the building blocks of nanotechnology has opened up new ways to utilize them in next generation solar cells. This paper focuses on the recent developments in the utilization of semiconductor quantum dots for light energy conversion. Three major ways to utilize semiconductor dots in solar cell include (i) metal−semiconductor or Schottky junction photovoltaic cell (ii) polymer−semiconductor hybrid solar cell, and (iii) quantum dot sensitized solar cell. Modulation of band energies through size control offers new ways to control photoresponse and photoconversion efficiency of the solar cell. Various strategies to maximize photoinduced charge separation and electron transfer processes for improving the overall efficiency of light energy conversion are discussed. Capture and transport of charge carriers within the semiconductor nanocrystal network to achieve efficient charge separation at the electrode surface remains a major challenge. Directing the future resear...

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Citations
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Journal ArticleDOI

Controlled synthesis of CuInS2, Cu2SnS3 and Cu2ZnSnS4 nano-structures: insight into the universal phase-selectivity mechanism

TL;DR: In this paper, the coordination strength between solvent and metal precursors is controlled by coordination strength of the phase structure of a mixture of copper iodide, indium acetate and 1-dodecanethiol to obtain a well-shaped CuInS2 nanopyramids and nanodisks.
Journal ArticleDOI

A review on solar cells from Si-single crystals to porous materials and quantum dots.

TL;DR: In this paper, the development of the different generations of solar cells is reviewed, and an advanced photovoltaic cell, originally developed for satellites with solar conversion efficiency of 37.3%, based on concentration of the solar spectrum up to 400 suns was developed.
Journal ArticleDOI

Synthesis and characterization of wurtzite-phase copper tin selenide nanocrystals.

TL;DR: The wurtzite CTSe nanocrystals possess an optical and electrochemical band gap of 1.7 eV and display an electrochemical photoresponse indicative of a p-type semiconductor.
Journal ArticleDOI

Heterojunction Engineering of CdTe and CdSe Quantum Dots on TiO2 Nanotube Arrays: Intricate Effects of Size-Dependency and Interfacial Contact on Photoconversion Efficiencies

TL;DR: In this paper, the quality of heterojunctions at the QD-TiO2 nanotube interface has important implications on the efficiencies of photoelectrochemical solar cells.
Journal ArticleDOI

Transient optical studies of interfacial charge transfer at nanostructured metal oxide/PbS quantum dot/organic hole conductor heterojunctions.

TL;DR: It is shown that yields of charge separation are significantly higher at PbS/SnO(2) interfaces relative to P bS/TiO( 2) interfaces, and it is concluded that this behavior is a result of the ca. 300-500 meV lower conduction band edge in SnO(3) as compared to TiO(1) and the driving force for electron injection is increased.
References
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Journal ArticleDOI

Detailed Balance Limit of Efficiency of p‐n Junction Solar Cells

TL;DR: In this article, an upper theoretical limit for the efficiency of p−n junction solar energy converters, called the detailed balance limit of efficiency, has been calculated for an ideal case in which the only recombination mechanism of holeelectron pairs is radiative as required by the principle of detailed balance.
Journal ArticleDOI

Carbon Nanotubes--the Route Toward Applications

TL;DR: Many potential applications have been proposed for carbon nanotubes, including conductive and high-strength composites; energy storage and energy conversion devices; sensors; field emission displays and radiation sources; hydrogen storage media; and nanometer-sized semiconductor devices, probes, and interconnects.
Journal ArticleDOI

Polymer photovoltaic cells : enhanced efficiencies via a network of internal donor-acceptor heterojunctions

TL;DR: In this paper, the carrier collection efficiency and energy conversion efficiency of polymer photovoltaic cells were improved by blending of the semiconducting polymer with C60 or its functionalized derivatives.
Journal ArticleDOI

The Optical Properties of Metal Nanoparticles: The Influence of Size, Shape, and Dielectric Environment

TL;DR: In this paper, the authors describe recent progress in the theory of nanoparticle optical properties, particularly methods for solving Maxwell's equations for light scattering from particles of arbitrary shape in a complex environment.
Journal ArticleDOI

Semiconductor Nanocrystals as Fluorescent Biological Labels

TL;DR: Semiconductor nanocrystals prepared for use as fluorescent probes in biological staining and diagnostics have a narrow, tunable, symmetric emission spectrum and are photochemically stable.
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