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Journal ArticleDOI

Quantum Dot Solar Cells. Semiconductor Nanocrystals as Light Harvesters

Prashant V. Kamat
- 18 Oct 2008 - 
- Vol. 112, Iss: 48, pp 18737-18753
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TLDR
In this paper, three major ways to utilize semiconductor dots in solar cell include (i) metal−semiconductor or Schottky junction photovoltaic cell, (ii) polymer−smiconductor hybrid solar cell, and (iii) quantum dot sensitized solar cell.
Abstract
The emergence of semiconductor nanocrystals as the building blocks of nanotechnology has opened up new ways to utilize them in next generation solar cells. This paper focuses on the recent developments in the utilization of semiconductor quantum dots for light energy conversion. Three major ways to utilize semiconductor dots in solar cell include (i) metal−semiconductor or Schottky junction photovoltaic cell (ii) polymer−semiconductor hybrid solar cell, and (iii) quantum dot sensitized solar cell. Modulation of band energies through size control offers new ways to control photoresponse and photoconversion efficiency of the solar cell. Various strategies to maximize photoinduced charge separation and electron transfer processes for improving the overall efficiency of light energy conversion are discussed. Capture and transport of charge carriers within the semiconductor nanocrystal network to achieve efficient charge separation at the electrode surface remains a major challenge. Directing the future resear...

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Citations
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Journal ArticleDOI

Surface engineering of PbS quantum dot sensitized solar cells with a conversion efficiency exceeding 7

TL;DR: In this article, PbS/CdS QDs with a core/shell structure, which were used as the photosensitizer to fabricate sensitized solar cells, were prepared through the ion exchange method.
Journal ArticleDOI

Metal chalcogenides as counter electrode materials in quantum dot sensitized solar cells: a perspective

TL;DR: In this article, a panorama of both conventional noble metals and carbon CE materials and newly emerged metal chalcogenide CE materials for QDSSCs is presented, while the influence of CE materials on the overall device performance is stressed in detail.
Journal ArticleDOI

Donor−Acceptor Nanoarchitecture on Semiconducting Electrodes for Solar Energy Conversion

TL;DR: In this paper, donor-nanocarbons (i.e., fullerenes and carbon nanotubes) have been successfully deposited electrophoretically or spincoated onto nanostructured SnO2 and TiO2 electrodes that exhibit efficient photocurrent generation.
Journal ArticleDOI

Optimization of TiO2 photoanode films for highly efficient quantum dot-sensitized solar cells

TL;DR: In this paper, the preparation and optimization of films have been systematically studied, including the TiCl4 treatment technique, transparent layer and light-scattering layer thickness and composition, and the results show that the sole treatment on fluorine doped SnO2 (FTO) glass is sufficient for achieving a high efficiency in the resultant cell devices when compared with the simultaneous treatment on both FTO glass and TiO2 mesoporous films.
Journal ArticleDOI

The importance of the TiO2/quantum dots interface in the recombination processes of quantum dot sensitized solar cells

TL;DR: It is shown that the recombination of electrons at the TiO(2)/QDs interface is as important as the recombinated from TiO (2) and QDs to the electrolyte in the development of quantum dot sensitized solar cells.
References
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Journal ArticleDOI

Detailed Balance Limit of Efficiency of p‐n Junction Solar Cells

TL;DR: In this article, an upper theoretical limit for the efficiency of p−n junction solar energy converters, called the detailed balance limit of efficiency, has been calculated for an ideal case in which the only recombination mechanism of holeelectron pairs is radiative as required by the principle of detailed balance.
Journal ArticleDOI

Carbon Nanotubes--the Route Toward Applications

TL;DR: Many potential applications have been proposed for carbon nanotubes, including conductive and high-strength composites; energy storage and energy conversion devices; sensors; field emission displays and radiation sources; hydrogen storage media; and nanometer-sized semiconductor devices, probes, and interconnects.
Journal ArticleDOI

Polymer photovoltaic cells : enhanced efficiencies via a network of internal donor-acceptor heterojunctions

TL;DR: In this paper, the carrier collection efficiency and energy conversion efficiency of polymer photovoltaic cells were improved by blending of the semiconducting polymer with C60 or its functionalized derivatives.
Journal ArticleDOI

The Optical Properties of Metal Nanoparticles: The Influence of Size, Shape, and Dielectric Environment

TL;DR: In this paper, the authors describe recent progress in the theory of nanoparticle optical properties, particularly methods for solving Maxwell's equations for light scattering from particles of arbitrary shape in a complex environment.
Journal ArticleDOI

Semiconductor Nanocrystals as Fluorescent Biological Labels

TL;DR: Semiconductor nanocrystals prepared for use as fluorescent probes in biological staining and diagnostics have a narrow, tunable, symmetric emission spectrum and are photochemically stable.
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