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Journal ArticleDOI

Quantum Dot Solar Cells. Semiconductor Nanocrystals as Light Harvesters

Prashant V. Kamat
- 18 Oct 2008 - 
- Vol. 112, Iss: 48, pp 18737-18753
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TLDR
In this paper, three major ways to utilize semiconductor dots in solar cell include (i) metal−semiconductor or Schottky junction photovoltaic cell, (ii) polymer−smiconductor hybrid solar cell, and (iii) quantum dot sensitized solar cell.
Abstract
The emergence of semiconductor nanocrystals as the building blocks of nanotechnology has opened up new ways to utilize them in next generation solar cells. This paper focuses on the recent developments in the utilization of semiconductor quantum dots for light energy conversion. Three major ways to utilize semiconductor dots in solar cell include (i) metal−semiconductor or Schottky junction photovoltaic cell (ii) polymer−semiconductor hybrid solar cell, and (iii) quantum dot sensitized solar cell. Modulation of band energies through size control offers new ways to control photoresponse and photoconversion efficiency of the solar cell. Various strategies to maximize photoinduced charge separation and electron transfer processes for improving the overall efficiency of light energy conversion are discussed. Capture and transport of charge carriers within the semiconductor nanocrystal network to achieve efficient charge separation at the electrode surface remains a major challenge. Directing the future resear...

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Citations
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Journal ArticleDOI

Surface-Treated TiO2 Nanoparticles for Dye-Sensitized Solar Cells with Remarkably Enhanced Performance

TL;DR: Dye-sensitized solar cells prepared by capitalizing on mesoporous P-25 TiO(2) nanoparticle film sensitized with N719 dyes exhibited a PCE as high as 8.35%, twice of untreated cells of 3.86%.
Journal ArticleDOI

Photoelectrochemical sensing of glucose based on quantum dot and enzyme nanocomposites

TL;DR: In this article, a simple procedure for constructing the photoelectrochemical biosensor based on TiO2/CdSe@CdS QD nanocomposite modified electrode was developed.
Journal ArticleDOI

Homogeneous Photosensitization of Complex TiO2 Nanostructures for Efficient Solar Energy Conversion

TL;DR: A new method based on atomic layer deposition and ion exchange reaction (ALDIER) to achieve a highly controllable and homogeneous coating of sensitizer particles on arbitrary TiO2 substrates is demonstrated.
Journal ArticleDOI

Enhanced charge transfer kinetics of CdSe quantum dot-sensitized solar cell by inorganic ligand exchange treatments.

TL;DR: An innovative route toward harvesting energy from solar light by enhancing the carrier charge transfer rate is proposed by exchanging the native, long organic chain to an atomic ligand, S(2-), with a simple solid exchange process.
Journal ArticleDOI

Multi-layered mesoporous TiO2 thin films with large pores and highly crystalline frameworks for efficient photoelectrochemical conversion

TL;DR: In this article, a ligand-assisted evaporation induced self assembly (EISA) method was used for the synthesis of highly ordered, multi-layered, continuous mesoporous TiO2 thin films with uniform large pores, crystalline walls and tunable film thickness.
References
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Journal ArticleDOI

Detailed Balance Limit of Efficiency of p‐n Junction Solar Cells

TL;DR: In this article, an upper theoretical limit for the efficiency of p−n junction solar energy converters, called the detailed balance limit of efficiency, has been calculated for an ideal case in which the only recombination mechanism of holeelectron pairs is radiative as required by the principle of detailed balance.
Journal ArticleDOI

Carbon Nanotubes--the Route Toward Applications

TL;DR: Many potential applications have been proposed for carbon nanotubes, including conductive and high-strength composites; energy storage and energy conversion devices; sensors; field emission displays and radiation sources; hydrogen storage media; and nanometer-sized semiconductor devices, probes, and interconnects.
Journal ArticleDOI

Polymer photovoltaic cells : enhanced efficiencies via a network of internal donor-acceptor heterojunctions

TL;DR: In this paper, the carrier collection efficiency and energy conversion efficiency of polymer photovoltaic cells were improved by blending of the semiconducting polymer with C60 or its functionalized derivatives.
Journal ArticleDOI

The Optical Properties of Metal Nanoparticles: The Influence of Size, Shape, and Dielectric Environment

TL;DR: In this paper, the authors describe recent progress in the theory of nanoparticle optical properties, particularly methods for solving Maxwell's equations for light scattering from particles of arbitrary shape in a complex environment.
Journal ArticleDOI

Semiconductor Nanocrystals as Fluorescent Biological Labels

TL;DR: Semiconductor nanocrystals prepared for use as fluorescent probes in biological staining and diagnostics have a narrow, tunable, symmetric emission spectrum and are photochemically stable.
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