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Journal ArticleDOI

Quantum Dot Solar Cells. Semiconductor Nanocrystals as Light Harvesters

Prashant V. Kamat
- 18 Oct 2008 - 
- Vol. 112, Iss: 48, pp 18737-18753
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TLDR
In this paper, three major ways to utilize semiconductor dots in solar cell include (i) metal−semiconductor or Schottky junction photovoltaic cell, (ii) polymer−smiconductor hybrid solar cell, and (iii) quantum dot sensitized solar cell.
Abstract
The emergence of semiconductor nanocrystals as the building blocks of nanotechnology has opened up new ways to utilize them in next generation solar cells. This paper focuses on the recent developments in the utilization of semiconductor quantum dots for light energy conversion. Three major ways to utilize semiconductor dots in solar cell include (i) metal−semiconductor or Schottky junction photovoltaic cell (ii) polymer−semiconductor hybrid solar cell, and (iii) quantum dot sensitized solar cell. Modulation of band energies through size control offers new ways to control photoresponse and photoconversion efficiency of the solar cell. Various strategies to maximize photoinduced charge separation and electron transfer processes for improving the overall efficiency of light energy conversion are discussed. Capture and transport of charge carriers within the semiconductor nanocrystal network to achieve efficient charge separation at the electrode surface remains a major challenge. Directing the future resear...

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Electronics and optoelectronics of two-dimensional transition metal dichalcogenides.

TL;DR: This work reviews the historical development of Transition metal dichalcogenides, methods for preparing atomically thin layers, their electronic and optical properties, and prospects for future advances in electronics and optoelectronics.
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Dye-Sensitized Solar Cells

TL;DR: Dye-sensitized solar cells (DSCs) offer the possibilities to design solar cells with a large flexibility in shape, color, and transparency as mentioned in this paper, and many DSC research groups have been established around the world.
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Prospects of Colloidal Nanocrystals for Electronic and Optoelectronic Applications

TL;DR: Nanocrystals (NCs) discussed in this Review are tiny crystals of metals, semiconductors, and magnetic material consisting of hundreds to a few thousand atoms each that are among the hottest research topics of the last decades.
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Perovskites: The Emergence of a New Era for Low-Cost, High-Efficiency Solar Cells

TL;DR: In this paper, the authors discussed the steps that have led to this discovery, and the future of this rapidly advancing concept have been considered, and it is likely that the next few years of solar research will advance this technology to the very highest efficiencies while retaining the very lowest cost and embodied energy.
References
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Journal ArticleDOI

Hybrid solar cells with prescribed nanoscale morphologies based on hyperbranched semiconductor nanocrystals.

TL;DR: Three-dimensional hyperbranched colloidal semiconductor nanocrystals in solution-processed hybrid organic-inorganic solar cells are incorporated, yielding reproducible and controlled nanoscale morphology.
Journal ArticleDOI

Efficient, stable infrared photovoltaics based on solution-cast colloidal quantum dots.

TL;DR: Stable solution-processed photovoltaic devices having 3.6% power conversion efficiency in the infrared are reported, and diffusion of electrons and holes over hundreds of nanometers through the PbSe colloidal quantum dot solid is chiefly responsible for the high external quantum efficiencies obtained in this new class of devices.
Journal ArticleDOI

Femtosecond 1P-to-1S electron relaxation in strongly confined semiconductor nanocrystals

TL;DR: In this paper, high-sensitivity femtosecond transient absorption is applied to directly measure the population-depopulation dynamics of the lowest ( $1S$) and the first excited ( $ 1P$) electron states in CdSe nanocrystals (NC's) of different radii with energy separation up to 16 longitudinal optical phonon energies.
Journal ArticleDOI

High efficiency of CdSe quantum-dot-sensitized TiO2 inverse opal solar cells

TL;DR: In this paper, the authors demonstrated an approach to sensitized type solar cells, based on TiO2 inverse opal and the use of CdSe quantum dots (QDs) as sensitizers.
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