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Journal ArticleDOI

Quantum Dot Solar Cells. Semiconductor Nanocrystals as Light Harvesters

Prashant V. Kamat
- 18 Oct 2008 - 
- Vol. 112, Iss: 48, pp 18737-18753
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TLDR
In this paper, three major ways to utilize semiconductor dots in solar cell include (i) metal−semiconductor or Schottky junction photovoltaic cell, (ii) polymer−smiconductor hybrid solar cell, and (iii) quantum dot sensitized solar cell.
Abstract
The emergence of semiconductor nanocrystals as the building blocks of nanotechnology has opened up new ways to utilize them in next generation solar cells. This paper focuses on the recent developments in the utilization of semiconductor quantum dots for light energy conversion. Three major ways to utilize semiconductor dots in solar cell include (i) metal−semiconductor or Schottky junction photovoltaic cell (ii) polymer−semiconductor hybrid solar cell, and (iii) quantum dot sensitized solar cell. Modulation of band energies through size control offers new ways to control photoresponse and photoconversion efficiency of the solar cell. Various strategies to maximize photoinduced charge separation and electron transfer processes for improving the overall efficiency of light energy conversion are discussed. Capture and transport of charge carriers within the semiconductor nanocrystal network to achieve efficient charge separation at the electrode surface remains a major challenge. Directing the future resear...

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Citations
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Journal ArticleDOI

Electronics and optoelectronics of two-dimensional transition metal dichalcogenides.

TL;DR: This work reviews the historical development of Transition metal dichalcogenides, methods for preparing atomically thin layers, their electronic and optical properties, and prospects for future advances in electronics and optoelectronics.
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Dye-Sensitized Solar Cells

TL;DR: Dye-sensitized solar cells (DSCs) offer the possibilities to design solar cells with a large flexibility in shape, color, and transparency as mentioned in this paper, and many DSC research groups have been established around the world.
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Prospects of Colloidal Nanocrystals for Electronic and Optoelectronic Applications

TL;DR: Nanocrystals (NCs) discussed in this Review are tiny crystals of metals, semiconductors, and magnetic material consisting of hundreds to a few thousand atoms each that are among the hottest research topics of the last decades.
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Perovskites: The Emergence of a New Era for Low-Cost, High-Efficiency Solar Cells

TL;DR: In this paper, the authors discussed the steps that have led to this discovery, and the future of this rapidly advancing concept have been considered, and it is likely that the next few years of solar research will advance this technology to the very highest efficiencies while retaining the very lowest cost and embodied energy.
References
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Journal ArticleDOI

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TL;DR: An intuition is developed for understanding and comparing nanoscale systems and why the electron and hole act as independent particles in this manifold of states, with an emphasis on exciton binding and photodissociation.
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Photoelectrochemistry of Composite Semiconductor Thin Films. Photosensitization of the SnO2/TiO2 Coupled System with a Ruthenium Polypyridyl Complex

TL;DR: In this article, the potential of a coupled electrode in bringing about an efficient charge separation in nanocrystalline DSPE cells has been highlighted, and the importance of the proper placement of the energy levels of individual semiconductor components in the coupled system for vectorial el...
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A Comparison Between the Behavior of Nanorod Array and Planar Cd(Se, Te) Photoelectrodes

TL;DR: In this paper, the authors have characterized planar and nanorod array photoelectrodes prepared by electrodeposition of Cd(Se,Te) electrodes, and compared the performance of the two types of electrodes under simulated 100 mW cm^(-2) and Air Mass 1.5 conditions.
Journal ArticleDOI

Core−Shell Quantum Dots of Lattice-Matched ZnCdSe2 Shells on InP Cores: Experiment and Theory

TL;DR: In this article, lattice-matched ZnCdSe2 concentric epilayer shells up to 50 A in thickness have been grown on InP core quantum dots (QDs) and the quality of epitaxially grown shells was monitored by absorption and emission spectra and transmission electron microscopy (TEM).
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Exciton recombination dynamics in CdSe nanowires: bimolecular to three-carrier Auger kinetics.

TL;DR: Ultrafast relaxation dynamics of charge carriers in CdSe quantum wires with diameters between 6 and 8 nm are studied as a function of carrier density to define an optimal intensity for achieving optical gain in solution-grown nanowires given the different carrier-density-dependent scaling of relaxation rates.
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