Journal ArticleDOI
Quasi-ideal strontium titanate crystal surfaces through formation of stontium hydroxide
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TLDR
In this article, the topmost oxide layer was observed to hydroxylate after immersion in water, which was used to enhance the etch-selectivity of SrO relative to TiO2 in a buffered HF solution.Abstract:
In recent years, well-defined and nearly perfect single crystal surfaces of oxide perovskites have become increasingly important. A single terminated surface is a prerequisite for reproducible thin film growth and fundamental growth studies. In this work, atomic and lateral force microscopy have been used to display different terminations of SrTiO3. We observe hydroxylation of the topmost SrO layer after immersion of SrTiO3 in water, which is used to enhance the etch-selectivity of SrO relative to TiO2 in a buffered HF solution. We reproducibly obtain perfect and single terminated surfaces, irrespective of the initial state of polished surfaces and the pH value of the HF solution. This approach to the problem might be used for a variety of multi-component oxide single crystals. True two-dimensional reflection high-energy electron diffraction intensity oscillations are observed during homo epitaxial growth using pulsed laser deposition on these surfaces.read more
Citations
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Journal ArticleDOI
A highly active and stable IrOx/SrIrO3 catalyst for the oxygen evolution reaction
Linsey C. Seitz,Colin F. Dickens,Colin F. Dickens,Kazunori Nishio,Kazunori Nishio,Yasuyuki Hikita,Joseph Montoya,Andrew D. Doyle,Charlotte Kirk,Aleksandra Vojvodic,Harold Y. Hwang,Harold Y. Hwang,Jens K. Nørskov,Jens K. Nørskov,Thomas F. Jaramillo,Thomas F. Jaramillo +15 more
TL;DR: The IrOx/SrIrO3 catalyst outperforms known IrOx and ruthenium oxide (RuOx) systems, the only other OER catalysts that have reasonable activity in acidic electrolyte.
Journal ArticleDOI
Magnetic effects at the interface between non-magnetic oxides
Alexander Brinkman,Mark Huijben,Mark Huijben,M. van Zalk,J. Huijben,Uli Zeitler,Jan C. Maan,W.G. van der Wiel,Guus Rijnders,David H.A. Blank,Hans Hilgenkamp +10 more
TL;DR: In this article, the authors show how magnetism can be induced at the interface between the otherwise non-magnetic insulating perovskites SrTiO3 and LaAlO3.
Journal Article
Magnetic effects at the interface between nonmagnetic oxides
TL;DR: The conducting oxide interface now provides a versatile system to induce and manipulate magnetic moments in otherwise non-magnetic materials.
Journal ArticleDOI
Strain Tuning of Ferroelectric Thin Films
Darrell G. Schlom,Long Qing Chen,Chang-Beom Eom,Karin M. Rabe,Stephen K. Streiffer,Jean-Marc Triscone +5 more
TL;DR: In this paper, the effect of biaxial strain on the properties of epitaxial ferroelectric thin films and superlattices is discussed. But the results for single-layer thin films are not discussed.
Journal ArticleDOI
Ferroelectricity at the Nanoscale: Local Polarization in Oxide Thin Films and Heterostructures
Chong H. Ahn,Chong H. Ahn,Chong H. Ahn,Karin M. Rabe,Karin M. Rabe,Karin M. Rabe,Jean-Marc Triscone,Jean-Marc Triscone,Jean-Marc Triscone +8 more
TL;DR: Not only can the necessary high-quality ferroelectric films now be grown for new device capabilities, but ferroelectrics can be combined with other functional oxides, such as high-temperature superconductors and magnetic oxide, to create multifunctional materials and devices.
References
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Book
The surface science of metal oxides
TL;DR: In this paper, the electronic structure of transition metal-oxide surfaces is described. But the electronic structures of non-transition metaloxide surfaces have not been discussed, and they are not considered in this paper.
Journal ArticleDOI
Atomic Control of the SrTiO3 Crystal Surface
Masashi Kawasaki,Kazuhiro Takahashi,Tatsuro Maeda,Ryuta Tsuchiya,Makoto Shinohara,Osamu Ishiyama,Takuzo Yonezawa,Mamoru Yoshimoto,Hideomi Koinuma +8 more
TL;DR: The atomically smooth SrTiO3 (100) with steps one unit cell in height was obtained by treating the crystal surface with a pH-controlled NH4F-HF solution, providing a well-defined substrate surface for atomically regulated epitaxial growth of such perovskite oxide films as YBa2Cu3O7-δ.
Journal ArticleDOI
Functional Group Imaging by Chemical Force Microscopy
TL;DR: By monitoring the friction between a specifically functionalized tip and sample, one can produce friction images that display predictable contrast and correspond to the spatial distribution of functional groups on the sample surface.
BookDOI
Reflection High-Energy Electron Diffraction and Reflection Electron Imaging of Surfaces
P. K. Larsen,P. J. Dobson +1 more
TL;DR: The main topics of the workshop, Reflection High Energy Electron Diffraction (RHEED) and Reflection Electron Microscopy (REM), have a common basis in the diffraction processes which high energy electrons undergo when they interact with solid surfaces at grazing angles as discussed by the authors.
Journal ArticleDOI
In-situ monitoring during pulsed laser deposition of complex oxides using reflection high energy electron diffraction under high oxygen pressure
TL;DR: In this paper, reflection high energy electron diffraction (RHEED) was used for growth monitoring during the deposition of complex oxides at standard PLD conditions, and the results showed that the RHEED patterns are observable at these high pressures.