Journal ArticleDOI
Raman spectrum of liquid water and Luck's two state model
M. C. Shivaglal,Surjit Singh +1 more
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TLDR
In this paper, it was suggested that the Raman spectrum for water can be explained on the basis of the presence of free and hydrogen-bonded OH bonds.About:
This article is published in Journal of Molecular Liquids.The article was published on 1990-10-01. It has received 2 citations till now. The article focuses on the topics: Raman spectroscopy & Overtone.read more
Citations
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Journal ArticleDOI
The weakening of the intramolecular hydrogen bond NH⋯O in complexes of ortho-substituted anilines with proton acceptors
Gleb S. Denisov,L. A. Kuzina +1 more
TL;DR: In this paper, a method of estimating the intramolecular hydrogen-bond enthalpy in ortho-substituted anilines has been proposed, based on the assumption of the equality of two hydrogen-body enthalpies in the complex with the symmetrically perturbed amino group.
Journal ArticleDOI
Electrostatic model of cooperative effects in hydrogen-bonded systems: cooperative effect of base and cation on the AH stretching1 vibrational frequency
TL;DR: In this paper, the potential energy surface (PES) of the intermolecular interaction is approximated by the sum of the coulombic interaction energies of the atomic effective (residual) charges, allowing for the inductive action on the neighbouring bonds and the exchange repulsion of nearest atoms.
References
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Journal ArticleDOI
Raman Spectral Studies of the Effects of Temperature on Water Structure
TL;DR: In this paper, the integrated Raman intensities of the spectral contour arising from the intermolecular librational motions of pure water have been obtained in the temperature range of ∼10°-95°C.
Journal ArticleDOI
Raman isosbestic points from liquid water
TL;DR: Isosbestic points from two different measurements calculated by the relations, X(ZZ)Y‐(4/3)X(ZX)Y and X(Z,X+Z)Y•(7/6)X[Y,X + Z]Y agree exactly for 45α2, 3370 cm−1 as discussed by the authors.
Journal ArticleDOI
Raman spectra and an assignment of the vibrational stretching region of water
W. F. Murphy,H. J. Bernstein +1 more
Journal ArticleDOI
Raman Spectral Studies of HDO in H2O
TL;DR: In this article, a 6.2M solution of D2O in H2O was analyzed by means of a specialpurpose analog computer, and two Gaussian components near 2510−2540 and 2630−2660 cm−1 were found to provide adequate fits of the contours in the temperature range involved, although some indication of a third weak Gaussian Raman component was found.
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