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Journal ArticleDOI

Rare earth elements and the island arc tholeiitic series

01 Aug 1970-Earth and Planetary Science Letters (Elsevier)-Vol. 9, Iss: 1, pp 17-28
TL;DR: The island arc tholeiitic series as mentioned in this paper is the most dominant in many western Pacific and Atlantic Island arcs and represents the earliest stages in arc evolution. But it is chemically inappropriate to call many of the rocks in island arcs calc-alkaline and they suggest they be known as the "island arc thoeitic series" and they differ from normal thoeiitic features by having a higher percentage of intermediate and acid members and too little normative olivine, for example, to have been in equilibrium with peridotite.
About: This article is published in Earth and Planetary Science Letters.The article was published on 1970-08-01. It has received 455 citations till now. The article focuses on the topics: Island arc & Peridotite.
Citations
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Journal ArticleDOI
TL;DR: In this paper, the Pontic eocene volcanic rocks cropping out in the Kastamonu area, Pontic chain of Northern Turkey were analyzed and the SiO2% versus K2O% relationship showed that the analyzed samples belong to two major groups: the basaltic andesitic and the andesite ones.
Abstract: Analytical data for Sr, Rb, Cs, Ba, Pb, rare earth elements, Y, Th, U, Zr, Hf, Sn, Nb, Mo, Ni, Co, V, Cr, Sc, Cu and major elements are reported for eocene volcanic rocks cropping out in the Kastamonu area, Pontic chain of Northern Turkey. SiO2% versus K2O% relationship shows that the analyzed samples belong to two major groups: the basaltic andesitic and the andesitic ones. High-K basaltic andesites and low-K andesites occur too. Although emplaced on continental type basement (the North Anatolian Crystalline Swell), the Pontic eocene volcanics show elemental abundances closely comparable with typical island arc calc-alkaline suites, e.g. low SiO2% range, low to moderate K2O% and large cations (Cs, Rb, Sr, Ba, Pb) contents and REE patterns with fractionated light and almost flat heavy REE patterns. ΣREE and highly charged cations (Th, U, Hf, Sn, Zr) are slightly higher than typical calc-alkaline values. Ferromagnesian elements show variable values. Within the basaltic andesite group the increase of K%, large cations, ΣREE, La/Yb ratio and high valency cations and the decrease of ferromagnesian element abundances with increasing SiO2% content indicate that the rock types making up this group developed by crystalliquid fractionation of olivine and clinopyroxene from a basic parent magma. Trace element concentration suggest that the andesite group was not derived by crystal-liquid fractionation processes from the basaltic andesites, but could represent a distinct group of rocks derived from a different parent magma.

4,477 citations

Journal ArticleDOI
TL;DR: In this paper, the results of analyses for Ti, Zr, Y, Nb and Sr in over 200 basaltic rocks from different tectonic settings have been used to construct diagrams in which these settings can usually be identified.

3,403 citations

Journal ArticleDOI
01 Apr 1989-Lithos
TL;DR: In this paper, the authors used petrologic diagrams applied to analyses of volcanic rocks for construction of discriminant lines between rock series and provided coordinates for sufficient points to enable accurate plotting of the boundary lines within seven diagrams, viz.

1,150 citations

Journal ArticleDOI
TL;DR: In this paper, five minor and trace elements have been variously combined to produce a set of binary diagrams in addition to total alkali-SiO2 diagrams, that discriminate between fresh tholeiitic and alkali basalts.

744 citations

Journal ArticleDOI
TL;DR: The solidus of a model pyrolite composition is sensitively dependent on water content and has been determined experimentally up to 40 kb, for water-saturated (6% H2O) and water-underwater (0.2%) conditions.

681 citations

References
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Journal ArticleDOI
TL;DR: A table of abundances of the elements in the various major units of the Earth's lithic crust with a documentation of the sources and a discussion of the choice of units and data is presented in this article.
Abstract: This paper presents a table of abundances of the elements in the various major units of the Earth's lithic crust with a documentation of the sources and a discussion of the choice of units and data.

4,619 citations

Journal ArticleDOI
TL;DR: In this paper, the results of a detailed experimental investigation of fractionation of natural basaltic compositions under conditions of high pressure and high temperature were reported, where a single stage, pistoncylinder apparatus has been used in the pressure range up to 27 kb and at temperatures up to 1500° C to study the melting behaviour of several basaltics compositions.
Abstract: This paper reports the results of a detailed experimental investigation of fractionation of natural basaltic compositions under conditions of high pressure and high temperature. A single stage, piston-cylinder apparatus has been used in the pressure range up to 27 kb and at temperatures up to 1500° C to study the melting behaviour of several basaltic compositions. The compositions chosen are olivine-rich (20% or more normative olivine) and include olivine tholeiite (12% normative hypersthene), olivine basalt (1% normative hypersthene) alkali olivine basalt (2% normative nepheline) and picrite (3% normative hypersthene). The liquidus phases of the olivine tholeiite and olivine basalt are olivine at 1 Atmosphere, 4.5 kb and 9 kb, orthopyroxene at 13.5 and 18 kb, clinopyroxene at 22.5 kb and garnet at 27 kb. In the alkali olivine basalt composition, the liquidus phases are olivine at 1 Atmosphere and 9 kb, orthopyroxene with clinopyroxene at 13.5 kb, clinopyroxene at 18 kb and garnet at 27 kb. The sequence of appearance of phases below the liquidus has also been studied in detail. The electron probe micro-analyser has been used to make partial quantitative analyses of olivines, orthopyroxenes, clinopyroxenes and garnets which have crystallized at high pressure.

1,246 citations

Journal ArticleDOI
P.W. Gast1
TL;DR: In this article, it was shown that the abundance of large ion elements in alkaline basalts cannot be consistently explained by fractional crystallization processes and that these characteristics are produced by previous partial melting episodes.

1,035 citations

Journal ArticleDOI
TL;DR: In this article, it was shown that oceanic tholeiites are either complete melts of the upper mantle or are generated from a mix of this tholeite and a magnesium-rich peridotite or dunite in proportions up to perhaps 1:4.
Abstract: Tholeiitic basalts (oceanic tholeiites) that form most of the deeply submerged volcanic features in the oceans are characterized by extremely low amounts of Ba, K, P, Pb, Sr, Th, U, and Zr as well as Fe 2 O 3 /FeO 10 in unaltered samples. Oceanic tholeiites also have rare earth abundance-distribution patterns and ratios of K/Rb (1300) and Sr 87 /Sr 86 (0.702) similar to or overlapping those of calcium-rich (basaltic) achondritic meteorites. The close compositional similarities between the oceanic tholeiites and calcium-rich achondrites indicates the relatively primitive nature of the oceanic tholeiites. In contrast, the alkali-rich basalts that cap submarine and island volcanoes are relatively enriched in Ba, K, La, Nb, P, Pb, Pb 206 , Rb, Fe 2 O 3 , Sr, Sr 87 , Ti, Th, U, and Zr; i.e . in the same elements and isotopes that are concentrated in the sialic continental crusts by factors of 5 to 1000 more than the amounts readily inferred in the upper mantle. These analytical data coupled with the field relationships indicate that the alkali-rich basalts are derivative rocks, fractionated from the oceanic tholeiites by processes of magmatic differentiation, and that the oceanic tholeiites are the principal or only primary magma generated in the upper mantle under the oceans. Studies of the abundances and compositions of continental basalts show that essentially identical tholeiitic lavas, contaminated with Si, K, and the chemically coherent trace elements and radiogenic isotopes from the sial, also have been the predominant or only magma generated in the mantle under the continents. The chemical properties of oceanic tholeiites suggest that the upper mantle probably contains less than (in parts per million): Ba, 10; K, 1000; Pb, 0.4; Rb, 10; Th, 0.2; and U, 0.1. The Sr 87 /Sr 86 must be less than 0.7015; Th/U about 2; K/Rb about 1500–2000; and Fe 2 O 3 /FeO less than 0.1. The integration of field and petrochemical data with seismic, density, and shock-wave studies suggests that the oceanic tholeiites are either complete melts of the upper mantle or are generated from a mix of this tholeiite and a magnesium-rich peridotite or dunite in proportions up to perhaps 1:4. The Mohorovicic discontinuity under the oceans appears to mark the transition downward from a largely tholeiitic oceanic crust to either tholeiite reconstituted to blueschist or greenschist or to the ultramafic residue left after expulsion of oceanic tholeiite.

698 citations

Journal ArticleDOI
TL;DR: Oceanic ridge volcanic rocks alkali metal, alkaline earth, rare earth, nickel and major element content, observing partial melting as mentioned in this paper. But this is not the case for all volcanic rocks.
Abstract: Oceanic ridge volcanic rocks alkali metal, alkaline earth, rare earth, nickel and major element content, observing partial melting

581 citations