Journal ArticleDOI
Recent advances in dysprosium-based single molecule magnets: Structural overview and synthetic strategies
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In this paper, the authors demonstrate the research developed in the few years in the fascinating and challenging field of Dy-based SMMs with particular focus on how recent studies tend to address the issue of relaxation dynamics in these systems from synthetic point of view.About:
This article is published in Coordination Chemistry Reviews.The article was published on 2013-06-01. It has received 800 citations till now.read more
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Symmetry strategies for high performance lanthanide-based single-molecule magnets
TL;DR: In this review, crystal-field theory is employed to demonstrate the electronic structures according to the semiquantitative electrostatic model and specific symmetry elements are analysed for the elimination of transverse crystal fields and quantum tunnelling of magnetization (QTM).
A Polynuclear Lanthanide Single-Molecule Magnet with a Record
Po-Heng Lin,Tara J. Burchell,Liviu Ungur,Liviu F. Chibotaru,Wolfgang Wernsdorfer,Muralee Murugesu +5 more
TL;DR: The magnet-like behavior can be observed by slow relaxation of the magnetization below the blocking temperature as mentioned in this paper, and this assumption has formed the basis for the understanding of the origin of the anisotropic barrier.
Journal ArticleDOI
Equatorially Coordinated Lanthanide Single Ion Magnets
TL;DR: The three-coordinate Er-based complex is the first equatorially coordinated mononuclear Er- based single-molecule magnet (SMM) corroborating that simple models can effectively direct the design of target SMMs incorporating 4f-elements.
Journal ArticleDOI
Radical ligand-containing single-molecule magnets
TL;DR: A survey of radical ligand-containing single-molecule magnets can be found in this article, with a brief overview of other classes of metal-ligand radical complexes that could be exploited in the design of new single molecule magnet.
Journal ArticleDOI
Toward heterometallic single-molecule magnets: Synthetic strategy, structures and properties of 3d–4f discrete complexes
Ke Liu,Wei Shi,Peng Cheng +2 more
TL;DR: In this paper, a review of 3d-4f heterometallic discrete complexes is presented, focusing on the examples showing dynamics of the magnetization, as well as the synthetic strategy, structures and magnetic properties.
References
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Journal ArticleDOI
Magnetic bistability in a metal-ion cluster
TL;DR: In this article, it was shown that the magnetization of the Mn12 cluster is highly anisotropic and the magnetisation relaxation time becomes very long below a temperature of 4 K, giving rise to pronounced hysteresis.
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Time‐Dependent Statistics of the Ising Model
TL;DR: In this paper, the effect of a uniform, time-varying magnetic field upon the Ising model is discussed, and the frequency-dependent magnetic susceptibility is found in the weak-field limit.
Journal ArticleDOI
Molecular spintronics using single-molecule magnets
Lapo Bogani,Wolfgang Wernsdorfer +1 more
TL;DR: This work reviews the first progress in the resulting field, molecular spintronics, which will enable the manipulation of spin and charges in electronic devices containing one or more molecules, and discusses the advantages over more conventional materials, and the potential applications in information storage and processing.
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Quantum Tunneling of Magnetization and Related Phenomena in Molecular Materials
Dante Gatteschi,Roberta Sessoli +1 more
TL;DR: The fundamental concepts needed to understand quantum size effects in molecular magnets are reviewed and critically report what has been done in the field to date are critically reported.
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Lanthanide Double-Decker Complexes Functioning as Magnets at the Single-Molecular Level
TL;DR: Double-decker phthalocyanine complexes with Tb3+ or Dy3+ showed slow magnetization relaxation as a single-molecular property and a significant temperature rise results from a mechanism in the relaxation process different from that in the transition-metal-cluster SMMs.