Journal ArticleDOI
Recent advances in metal free- and late transition metal-catalysed hydroamination of unactivated alkenes
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TLDR
In this paper, some of the recent advancements completed in the development of (chiral) metal-free and late-transition metal catalysts for the inter-and intramolecular hydroamination of unactivated alkenes, including allenes, 1,3-dienes, and strained alkens, are discussed.About:
This article is published in Catalysis Science & Technology.The article was published on 2015-03-24. It has received 138 citations till now. The article focuses on the topics: Hydroamination.read more
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Electrochemical strategies for C-H functionalization and C-N bond formation.
TL;DR: This review provides an overview on the use of anodic electrochemical methods for expediting the development of carbon-hydrogen functionalization and carbon-nitrogen bond formation strategies and aims to provide inspiration for future synthetic applications in the field of electrosynthesis.
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Copper Hydride Catalyzed Hydroamination of Alkenes and Alkynes
TL;DR: The background, advances, and mechanistic investigations in CuH-catalyzed hydroamination are detailed.
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Photochemical Generation of Nitrogen-Centered Amidyl, Hydrazonyl, and Imidyl Radicals: Methodology Developments and Catalytic Applications
TL;DR: This Perspective highlights the recent advances in visible light-mediated generation of amidyl, hydrazonyl, and imidyl radicals from a variety of precursors.
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Recent Advances in Hydrometallation of Alkenes and Alkynes via the First Row Transition Metal Catalysis
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Electrocatalytic Generation of Amidyl Radicals for Olefin Hydroamidation: Use of Solvent Effects to Enable Anilide Oxidation
TL;DR: The first electrocatalytic method that employs ferrocene (Fc), a cheap organometallic reagent, as the redox catalyst to produce amidyl radicals from N-aryl amides is reported, and an efficient intramolecular olefin hydroamidation reaction has been developed.
References
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Journal ArticleDOI
Hydroamination: direct addition of amines to alkenes and alkynes.
TL;DR: Hydroamination of Alkenes and Alkynes under Microwave Irradiation and Nitromercuration Reactions 3878 9.8.4.5.
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A powerful chiral counterion strategy for asymmetric transition metal catalysis.
TL;DR: It is shown that the chiral counterion can be combined additively with chiral ligands to enable an asymmetric transformation that cannot be achieved by either method alone.
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"Designer acids": combined acid catalysis for asymmetric synthesis.
TL;DR: Combining Lewis and Brønsted acids will bring out their inherent reactivity by associative interaction, and also provide more-organized structures that allow an effective asymmetric environment.
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Recent developments in enantioselective gold(I) catalysis.
TL;DR: An overview of enantioselective gold(I) catalysis since 2005 suggests that new approaches and strategies have emerged over the past two years, leading to the development of a number of effective gold( I)-catalyzed enantioseslective transformations, most notably the enantiOSElective hydrofunctionalization of allenes.
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Gold-Catalyzed Hydroamination of C–C Multiple Bonds
Ross A. Widenhoefer,Xiaoqing Han +1 more
TL;DR: A brief overview of the gold-catalyzed hydroamination of C-C multiple bonds can be found in this paper, where gold catalysts have been applied as catalysts for a number of selective organic transformations including unactivated alkenes, alkynes, allenes and 1, 3-dienes.