Recent Advances in Nanomaterials for Wastewater Treatment
01 Jan 2019-pp 21-58
TL;DR: In this paper, the use of semiconducting nanoparticles for wastewater treatment is discussed, and the role of nanomaterials in adsorption techniques (specifically, carbon-based nanoadsorbents) is discussed in detail.
Abstract: Developing an efficient wastewater treatment technique is one of the major necessities of the twenty-first century, owing to the scarcity of water resources. Besides, it is of paramount important to find appropriate methodologies to economically treat wastewater. Recent advances in nanotechnology have attracted the attention of many researchers for wastewater treatment. The major advantages of such nanomaterial-based systems are that they can be reused and have been found to be very effective. Though many research works have been reported in this regard, there is very limited collective information. Hence, the major objective of this work is to describe recent achievements in nanomaterial-based systems for wastewater treatment. This chapter critically reviews and lists the uses of nanomaterials in wastewater treatment. This comprises the utilization of semiconducting nanoparticles either alone or combined with ozonation, the Fenton process, or sonolysis for effective degradation/removal of organic pollutants. Furthermore, the effectiveness of nanotechnology in antimicrobial activity to produce pure water via an eco-friendly route is discussed. Similarly, the role of nanomaterials in adsorption techniques (specifically, carbon-based nanoadsorbents) to remove heavy metal contamination from industrial wastewater is also discussed in detail.
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TL;DR: In this article, a review emphasises advances in nanotechnology and their respective kinetics, different reaction-based models for wastewater treatment, and discusses several nano-material based approaches employed in wastewater treatment deliberated in this manuscript.
17 citations
TL;DR: In this article , a review summarizes recent advances in the synthesis, reporting techniques, and applications of functionalized nanomaterials (FNMs) in adsorptive and photocatalytic removal of pollutants from wastewater.
Abstract: Abstract Nanotechnology has emerged as an extraordinary and rapidly developing discipline of science. It has remolded the fate of the whole world by providing diverse horizons in different fields. Nanomaterials are appealing because of their incredibly small size and large surface area. Apart from the naturally occurring nanomaterials, synthetic nanomaterials are being prepared on large scales with different sizes and properties. Such nanomaterials are being utilized as an innovative and green approach in multiple fields. To expand the applications and enhance the properties of the nanomaterials, their functionalization and engineering are being performed on a massive scale. The functionalization helps to add to the existing useful properties of the nanomaterials, hence broadening the scope of their utilization. A large class of covalent and non-covalent functionalized nanomaterials (FNMs) including carbons, metal oxides, quantum dots, and composites of these materials with other organic or inorganic materials are being synthesized and used for environmental remediation applications including wastewater treatment. This review summarizes recent advances in the synthesis, reporting techniques, and applications of FNMs in adsorptive and photocatalytic removal of pollutants from wastewater. Future prospects are also examined, along with suggestions for attaining massive benefits in the areas of FNMs.
6 citations
TL;DR: In this paper , a simple hydrothermal method was used to synthesize the SrTiO3/rGO@Ag composites, followed by decorating the surface with Ag particles by using the photodeposition process.
Abstract: Understanding the graphene/semiconductor/metal interactions is crucial to design innovative photocatalytic materials with efficient photocatalytic activity for environmental cleanup applications. SrTiO3 on reduced graphene oxide (rGO) with various graphene contents was successfully synthesized in this study utilizing a simple hydrothermal method, followed by decorating the surface with Ag particles by using the photodeposition process. Under UV-visible light irradiation, the resulting composites were tested for their improved photocatalytic activity to decompose methylene blue (MB). The prepared photocatalysts were characterized by XRD, SEM, EDX, DLS, FT-IR, Raman spectroscopy, and DRS. First-principle density functional theory calculations (DFT) were also carried out by using the generalized gradient approximation (GGA) and PBE functional with the addition of on-site Coulomb correction (GGA + U). The obtained SrTiO3/rGO@Ag composites showed great improvement in the photocatalytic performances over pristine SrTiO3. For the degradation reaction of MB, SrTiO3/rGO20%@Ag4% composites yielded the best photocatalytic activity with efficacy reach 94%, which was also shown that it could be recycled up to four times with nearly unchanged photocatalytic activity.
4 citations
01 Jan 2021
TL;DR: In this paper, the authors discuss the latest technologies which are available right now using the chalcogenides nanomaterials, as catalysts, remediation of various environmental contaminants, and their role in treating contaminated water including organic contaminants degradation alongside bacterial disinfection.
Abstract: Nowadays pollution is a major concern for human mankind. As the generations are passing by, the more the worse it is getting to protect the environment. Every part of the environment is being contaminated due and in reverse, the humans and the other living being getting affected due to the consequences done by humans. Even though there are several technologies available to protect the environment still we find some voids to fill in and in this process, new technology evolves in. Water pollution is also considered to be one of the most ghastly situations, where economic development, rapid industrialization and even the population overgrowth is playing a key role. Due to rapid growth the release of several organic as well as inorganic substances into the environment, this is further leading to environmental pollution as well as the contamination of water. Because of this, combining nanotechnology in wastewater treatment will improve the quality of water. The major advantage of using the nanoparticles is they possess unique characteristics and have a high surface area where the unwanted particles get absorbed in these nanoparticles and get removed from them because of their high surface area. It can also be used for removing toxic substances. In this chapter, we discuss the latest technologies, which are available right now using the chalcogenides nanomaterials. Like, to disinfect the bacterial communities in wastewater, aspects of chalcogenide nanomaterials, as catalysts, remediation of various environmental contaminants, and their role in treating the contaminated water including organic contaminants degradation alongside bacterial disinfection.
3 citations
References
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TL;DR: In this paper, the degradation of chlorophenols (CPs) by means of advanced oxidation processes (AOPs) was evaluated during the period 1995-2002 and different mechanistic degradation pathways were taken into account.
Abstract: Advanced oxidation processes (AOPs) constitute a promising technology for the treatment of wastewaters containing non-easily removable organic compounds. Chlorophenols (CPs) are a group of special interest due to their high toxicity and low biodegradability. Data concerning the degradation of CPs by means of AOPs reported during the period 1995–2002 are evaluated in this work. Among the AOPs, the following techniques are studied: processes based on hydrogen peroxide (H2O2+UV, Fenton, photo-Fenton and Fenton-like processes), photolysis, photocatalysis and processes based on ozone (O3, O3+UV and O3+catalyst). Half-life times and kinetic constants for CP degradation are reviewed and the different mechanistic degradation pathways are taken into account.
2,024 citations
TL;DR: It is highlighted that both adults and children consuming food crops grown in wastewater-irrigated soils ingest significant amount of the metals studied, however, health risk index values of less than 1 indicate a relative absence of health risks associated with the ingestion of contaminated vegetables.
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TL;DR: The concept of photochemical sterilization was introduced in this article, where microorganisms were killed photoelectrochemically with semiconductor powder (platinum-loaded titanium oxide, TiO2/Pt).
Abstract: We report the novel concept of photochemical sterilization. Microbial cells were killed photoelectrochemically with semiconductor powder (platinum-loaded titanium oxide, TiO2/Pt). Coenzyme A, (CoA) in the whole cells was photo-electrochemically oxidized and, as a result, the respiration of cells was inhibited. Inhibition of respiratory activity caused death of the cells. Lactobacillus acidophilus, Saccharomyces cerevisiae and Escherichia coli (103 cells/ml respectively) were completely sterilized when they were incubated with TiO2/Pt particles under metal halide lamp irradiation for 60–120 min.
1,317 citations
1,258 citations
TL;DR: In this paper, an overview of the use of nanomaterials in water purification can be found, highlighting recent advances on the development of novel nanoscale materials and processes for treatment of surface water, groundwater and industrial wastewater contaminated by toxic metal ions, radionuclides, organic and inorganic solutes, bacteria and viruses.
Abstract: Advances in nanoscale science and engineering suggest that many of the current problems involving water quality could be resolved or greatly ameliorated using nanosorbents, nanocatalysts, bioactive nanoparticles, nanostructured catalytic membranes and nanoparticle enhanced filtration among other products and processes resulting from the development of nanotechnology. Innovations in the development of novel technologies to desalinate water are among the most exciting and promising. Additionally, nanotechnology-derived products that reduce the concentrations of toxic compounds to sub-ppb levels can assist in the attainment of water quality standards and health advisories. This article gives an overview of the use of nanomaterials in water purification. We highlight recent advances on the development of novel nanoscale materials and processes for treatment of surface water, groundwater and industrial wastewater contaminated by toxic metal ions, radionuclides, organic and inorganic solutes, bacteria and viruses. In addition, we discuss some challenges associated with the development of cost effective and environmentally acceptable functional nanomaterials for water purification.
1,099 citations