Journal ArticleDOI
Recent advances in the electrolytes for interfacial stability of high-voltage cathodes in lithium-ion batteries
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TLDR
In this article, the authors describe several challenges for the cathode (spinel lithium manganese oxide (LMO), lithium cobalt oxide (LCO), lithium nickel cobalt manganes oxide (NCM), spinel lithium ion ion oxide (SILO), and lithium-rich layered oxide (Li-rich cathode))-electrolyte interfaces and highlight the recent progress in the use of oxidative additives and highvoltage solvents in high-performance cells.Abstract:
Advanced electrolytes with unique functions such as in situ formation of a stable artificial solid electrolyte interphase (SEI) layer on the anode and the cathode, and the improvement in oxidation stability of the electrolyte have recently gained recognition as a promising means for highly reliable lithium-ion batteries with high energy density. In this review, we describe several challenges for the cathode (spinel lithium manganese oxide (LMO), lithium cobalt oxide (LCO), lithium nickel cobalt manganese oxide (NCM), spinel lithium manganese nickel oxide (LNMO), and lithium-rich layered oxide (Li-rich cathode))-electrolyte interfaces and highlight the recent progress in the use of oxidative additives and high-voltage solvents in high-performance cells.read more
Citations
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Journal ArticleDOI
Significantly Improved Cyclability of Conversion‐Type Transition Metal Oxyfluoride Cathodes by Homologous Passivation Layer Reconstruction
Journal ArticleDOI
Surface chemistry on LiCoPO4 electrodes in lithium cells: SEI formation and self-discharge
Jessica Manzi,Sergio Brutti +1 more
TL;DR: In this article, the surface chemistry of positive electrodes for Li-ion cell applications constituted by LiCoPO 4 (LCP) was investigated, and the authors illustrate the evolution of LCP electrodes upon charge and self-discharge.
Journal ArticleDOI
Bridging Multiscale Characterization Technologies and Digital Modeling to Evaluate Lithium Battery Full Lifecycle
Xinhua Liu,Lisheng Zhang,Hanqing Yu,Jianan Wang,Junfu Li,Kai Yang,Yunlong Zhao,Huizhi Wang,Billy Wu,Nigel P. Brandon,Shi Chun Yang +10 more
TL;DR: A seed cyber hierarchy and interactional network framework is demonstrated and digital twins techniques will be introduced enabling the real‐time monitoring and control of LIBs, autonomous computer‐assisted characterizations and intelligent manufacturing.
Journal ArticleDOI
Unanticipated Mechanism of the Trimethylsilyl Motif in Electrolyte Additives on Nickel-Rich Cathodes in Lithium-Ion Batteries.
TL;DR: It is reported that electrolyte additives with TMS moieties lead to continued capacity loss of polycrystalline (PC)-LiNi0.8Co0.1O2 (NCM811) cathodes coupled with graphite anodes compared to additives without TMS as the cycle progresses.
Journal ArticleDOI
Di(methylsulfonyl) Ethane: New Electrolyte Additive for Enhancing LiCoO2/Electrolyte Interface Stability under High Voltage
TL;DR: The outcomes indicate that the enhanced cycling performance is attributed to the involvement of DMSE in the generation of a thinner film on LiCoO2, which results in lower interfacial impedance and it protects the electrolyte from decomposition at high voltage.
References
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Journal ArticleDOI
Issues and challenges facing rechargeable lithium batteries
TL;DR: A brief historical review of the development of lithium-based rechargeable batteries is presented, ongoing research strategies are highlighted, and the challenges that remain regarding the synthesis, characterization, electrochemical performance and safety of these systems are discussed.
Journal ArticleDOI
Electrical Energy Storage for the Grid: A Battery of Choices
TL;DR: The battery systems reviewed here include sodium-sulfur batteries that are commercially available for grid applications, redox-flow batteries that offer low cost, and lithium-ion batteries whose development for commercial electronics and electric vehicles is being applied to grid storage.
Journal ArticleDOI
Li-O2 and Li-S batteries with high energy storage.
Peter G. Bruce,Stefan Freunberger,Laurence J. Hardwick,Laurence J. Hardwick,Jean-Marie Tarascon +4 more
TL;DR: The energy that can be stored in Li-air and Li-S cells is compared with Li-ion; the operation of the cells is discussed, as are the significant hurdles that will have to be overcome if such batteries are to succeed.
Journal ArticleDOI
Nonaqueous liquid electrolytes for lithium-based rechargeable batteries.
TL;DR: The phytochemical properties of Lithium Hexafluoroarsenate and its Derivatives are as follows: 2.2.1.
Journal ArticleDOI
Challenges Facing Lithium Batteries and Electrical Double‐Layer Capacitors
Nam-Soon Choi,Zonghai Chen,Stefan Freunberger,Xiulei Ji,Yang-Kook Sun,Khalil Amine,Gleb Yushin,Linda F. Nazar,Jaephil Cho,Peter G. Bruce +9 more
TL;DR: The Review will consider some of the current scientific issues underpinning lithium batteries and electric double-layer capacitors.