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Journal ArticleDOI

Recovery and pre-concentration of uranium from secondary effluent using novel resin

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TLDR
In this paper, the sorbed matrix has been eluted with different eluant concentration for further enrichment of radionuclides in the elute, and fractional elution ensures further reuse of sorbent and significant improvement in uranium enrichment.
Abstract
The act of enrichment or improving the quality of product concentration, i.e. 'pre-concentration', has been studied with respect to uranium plant effluent, which contains uranium in 10?30 ppm level intermingled with a huge number of interfering ions, such as magnesium, in percent level. The effects of different operating conditions, such as concentration of uranium in the effluent, pH, the time required for uptake of uranium and the effect of the presence of other elements in the effluent, in batch experiments have been investigated. Using this in-house novel resin for preferential uranium uptake, the sorbed matrix has been eluted with different eluant concentration for further enrichment of radionuclides in the elute. High uptake values for uranium ions prove its selectivity, and fractional elution ensures further reuse of sorbent and significant improvement in uranium enrichment.

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Book ChapterDOI

Introduction to Ion Exchange Processes

TL;DR: In this paper, the basic fundamentals and key components of ion exchange process taking into consideration the latest progress taking place in the field are reviewed and a brief encounter for the various applications utilizing ion exchange processes is also presented.
Journal ArticleDOI

Strategy of deriving 'wealth from waste' from concentrated brine of desalination plant

TL;DR: In this article, a novel polymeric chelating resin was designed and developed in Desalination Division, BARC laboratory with significant potential for this achievement, the characteristics and potential of the resin have been described for the recovery of valuable elements based on experimental findings.
Journal ArticleDOI

Studies on uranium recovery from inlet stream of Effluent Treatment Plant by novel “In-House” sorbent

TL;DR: In this article, a polyacrylhydroxamic acid (PHOA) has been synthesized and utilized targeting ground water remediation; recovery of uranium from low concentration aqueous solution.
Proceedings ArticleDOI

SEM, magnetization and Mössbauer spectroscopic characterization of Fe-U sequestration

TL;DR: The Jekyll and Hyde nature of iron and uranium loaded PAAHA has been characterized by FT-IR, SEM, Mossbauer spectroscopy, EDXRF and magnetization measurements as mentioned in this paper.
Journal ArticleDOI

Local Structure Investigations of Sequential Sorption of U and Fe on Polyacrylamide Hydroxamic Acid Resins.

TL;DR: In this article, a novel polyacrylamide hydroxamic acid (PAAHA) resin resample was applied to remove radiologically and chemically toxic uranium and iron.
References
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Journal ArticleDOI

Adsorption Efficiency of a New Adsorbent Towards Uranium and Vanadium Ions at Low Concentrations

TL;DR: In this article, a new type of fibrous adsorbent with excess amidoxime groups was synthesized by radiation-induced graft polymerization, which showed enhanced adsorption capacity for uranium and vanadium ions.
Journal ArticleDOI

The extraction of uranium from seawater by poly(amidoxime)/poly(hydroxamic acid) resins and fibre

TL;DR: Poly(amidoxime)/poly(hydroxamic acid) poly(acrylonitrile) fibres have been used to produce a chelating cloth for uranium extraction as mentioned in this paper.
Journal ArticleDOI

Composite fiber adsorbent for rapid uptake of uranyl from seawater

TL;DR: Composite fiber adsorbent was developed as a new material for the recovery of uranium from seawater as mentioned in this paper, which gave a large adsorption rate such as 200 µg of U/g of Ads by 1-day contact in a seawater batch test.
Journal ArticleDOI

Polyhydroxamic Acid Sorbents for Uranium Recovery

TL;DR: In this paper, a crosslinked polyacrylamides were synthesized by solution polymerization using benzoyl peroxide as the radical initiator, and the water-insoluble polymer obtained was functionalized by reacting with hydroxylamine to convert the amide group into hydroxamic acid group.
Journal ArticleDOI

A Superfast Sorbent Based on Textile-Grade Poly(acrylonitrile) Fiber/Fabric. Rapid Removal of Uranium from Mildly Acidic Aqueous Solutions of Low Concentration

TL;DR: In this article, the gel-coated fiber or fabric, containing 15% poly(acrylonitrile) (textile grade), used in fiber as well as fabric form, by a copper-mediated gelcoating process, exhibits an order of magnitude higher sorption capacity and 2 orders of magnitude high initial rate of sorption, as compared to conventional bead-form anionic resin Dowex 21K.
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