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Journal ArticleDOI

Reevaluating carbon fluxes in subduction zones, what goes down, mostly comes up.

TL;DR: Carbon fluxes in subduction zones can be better constrained by including new estimates of carbon concentration in subducting mantle peridotites, consideration of carbonate solubility in aqueous fluid along subduction geotherms, and diapirism of carbon-bearing metasediments.
Abstract: Carbon fluxes in subduction zones can be better constrained by including new estimates of carbon concentration in subducting mantle peridotites, consideration of carbonate solubility in aqueous fluid along subduction geotherms, and diapirism of carbon-bearing metasediments. Whereas previous studies concluded that about half the subducting carbon is returned to the convecting mantle, we find that relatively little carbon may be recycled. If so, input from subduction zones into the overlying plate is larger than output from arc volcanoes plus diffuse venting, and substantial quantities of carbon are stored in the mantle lithosphere and crust. Also, if the subduction zone carbon cycle is nearly closed on time scales of 5–10 Ma, then the carbon content of the mantle lithosphere + crust + ocean + atmosphere must be increasing. Such an increase is consistent with inferences from noble gas data. Carbon in diamonds, which may have been recycled into the convecting mantle, is a small fraction of the global carbon inventory.

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Citations
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01 Dec 2002
TL;DR: In this paper, the authors estimate that half to two thirds of subducted crustal water is later refluxed at the prism toe; most of the remaining water escapes at subarc depths, triggering partial melting.
Abstract: [1] The alteration of upper oceanic crust entails growth of hydrous minerals and loss of macroporosity, with associated large-scale fluxes of H2O, CO2, Cl−, and K2O between seawater and crust. This age-dependent alteration can be quantified by combining a conceptual alteration model with observed age-dependent changes in crustal geophysical properties at DSDP/ODP sites, permitting estimation of crustal concentrations of H2O, CO2, Cl−, and K2O, given crustal age. Surprisingly, low-temperature alteration causes no net change in total water; pore water loss is nearly identical to bound water gain. Net change in total crustal K2O is also smaller than expected; the obvious low-temperature enrichment is partly offset by earlier high-temperature depletion, and most crustal K2O is primary rather than secondary. I calculate crustal concentrations of H2O, CO2, Cl−, and K2O for 41 modern subduction zones, thereby determining their modern mass fluxes both for individual subduction zones and globally. This data set is complemented by published flux determinations for subducting sediments at 26 of these subduction zones. Global mass fluxes among oceans, oceanic crust, continental crust, and mantle are calculated for H2O, Cl−, and K2O. Except for the present major imbalance between sedimentation and sediment subduction, most fluxes appear to be at or near steady state. I estimate that half to two thirds of subducted crustal water is later refluxed at the prism toe; most of the remaining water escapes at subarc depths, triggering partial melting. The flux of subducted volatiles, however, does not appear to correlate with either rate of arc magma generation or magnitude of interplate earthquakes.

251 citations

Book
08 Apr 2019
TL;DR: In this paper, negative emissions technologies (NETs) that remove and sequester carbon dioxide from the air will need to play a significant role in mitigating climate change, and the benefits, risks, and sustainable scale potential for NETs and sequestration are assessed.
Abstract: To achieve goals for climate and economic growth, “negative emissions technologies” (NETs) that remove and sequester carbon dioxide from the air will need to play a significant role in mitigating climate change. Unlike carbon capture and storage technologies that remove carbon dioxide emissions directly from large point sources such as coal power plants, NETs remove carbon dioxide directly from the atmosphere or enhance natural carbon sinks. Storing the carbon dioxide from NETs has the same impact on the atmosphere and climate as simultaneously preventing an equal amount of carbon dioxide from being emitted. Recent analyses found that deploying NETs may be less expensive and less disruptive than reducing some emissions, such as a substantial portion of agricultural and land-use emissions and some transportation emissions. In 2015, the National Academies published Climate Intervention: Carbon Dioxide Removal and Reliable Sequestration, which described and initially assessed NETs and sequestration technologies. This report acknowledged the relative paucity of research on NETs and recommended development of a research agenda that covers all aspects of NETs from fundamental science to full-scale deployment. To address this need, Negative Emissions Technologies and Reliable Sequestration: A Research Agenda assesses the benefits, risks, and “sustainable scale potential” for NETs and sequestration. This report also defines the essential components of a research and development program, including its estimated costs and potential impact.

220 citations


Cites methods from "Reevaluating carbon fluxes in subdu..."

  • ...Third, as reviewed by Kelemen et al., 2011 and Kelemen and Manning, 2015, carbonate veins are abundant in outcrops of mantle peridotite (Figure 6.11)....

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Journal ArticleDOI
TL;DR: In this article, a large-scale mantle low δ26Mg anomaly in eastern China has been delineated, suggesting the contribution of sedimentary carbonates recycled into the upper mantle, but limited into the lower mantle.
Abstract: Although deep carbon recycling plays an important role in the atmospheric CO2 budget and climate changes through geological time, the precise mechanisms remain poorly understood. Since recycled sedimentary carbonate through plate subduction is the main light-δ26Mg reservoir within deep-Earth, Mg isotope variation in mantle-derived melts provides a novel perspective when investigating deep carbon cycling. Here, we show that the Late Cretaceous and Cenozoic continental basalts from 13 regions covering the whole of eastern China have low δ26Mg isotopic compositions, while the Early Cretaceous basalts from the same area and the island arc basalts from circum-Pacific subduction zones have mantle-like or heavy Mg isotopic characteristics. Thus, a large-scale mantle low δ26Mg anomaly in eastern China has been delineated, suggesting the contribution of sedimentary carbonates recycled into the upper mantle, but limited into the lower mantle. This large-scale spatial and temporal variation of Mg isotopes in the mantle places severe constraints on deep carbon recycling via oceanic subduction.

220 citations

Journal ArticleDOI
TL;DR: In this article, the authors compare the maximum pressure P-T conditions of exhumed subduction-related metamorphic rocks with those predicted by computational thermal models of subduction systems.

217 citations


Cites background from "Reevaluating carbon fluxes in subdu..."

  • ...Therefore decarbonation and garnet growth should be faster and occur at shallower levels than currently modeled (Ague and Nico- lescu, 2014; Baxter and Caddick, 2013; Kelemen and Manning, 2015)....

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Journal ArticleDOI
01 Jan 2016-Lithos
TL;DR: In this article, the authors consider records of fluid and mass transfer at localities representing various depths and structural expressions of evolving paleo-interfaces, ranging widely in structural character, the rock types involved, and the rheology of these rocks.

182 citations

References
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Journal ArticleDOI
TL;DR: A global plate motion model, named NUVEL-1, which describes current plate motions between 12 rigid plates is described, with special attention given to the method, data, and assumptions used as discussed by the authors.
Abstract: A global plate motion model, named NUVEL-1, which describes current plate motions between 12 rigid plates is described, with special attention given to the method, data, and assumptions used Tectonic implications of the patterns that emerged from the results are discussed It is shown that wide plate boundary zones can form not only within the continental lithosphere but also within the oceanic lithosphere; eg, between the Indian and Australian plates and between the North American and South American plates Results of the model also suggest small but significant diffuse deformation of the oceanic lithosphere, which may be confined to small awkwardly shaped salients of major plates

3,409 citations

01 Jan 1988
TL;DR: In this paper, a new global model (NUVEL-1) was proposed to describe the geologically current motion between 12 assumed-rigid plates by inverting plate motion data.
Abstract: SUMMARY We determine best-fitting Euler vectors, closure-fitting Euler vectors, and a new global model (NUVEL-1) describing the geologically current motion between 12 assumed-rigid plates by inverting plate motion data we have compiled, critically analysed, and tested for self-consistency. We treat Arabia, India and Australia, and North America and South America as distinct plates, but combine Nubia and Somalia into a single African plate because motion between them could not be reliably resolved. The 1122 data from 22 plate boundaries inverted to obtain NUVEL-1 consist of 277 spreading rates, 121 transform fault azimuths, and 724 earthquake slip vectors. We determined all rates over a uniform time interval of 3.0m.y., corresponding to the centre of the anomaly 2A sequence, by comparing synthetic magnetic anomalies with observed profiles. The model fits the data well. Unlike prior global plate motion models, which systematically misfit some spreading rates in the Indian Ocean by 8–12mm yr−1, the systematic misfits by NUVEL-1 nowhere exceed ∼3 mm yr−1. The model differs significantly from prior global plate motion models. For the 30 pairs of plates sharing a common boundary, 29 of 30 P071, and 25 of 30 RM2 Euler vectors lie outside the 99 per cent confidence limits of NUVEL-1. Differences are large in the Indian Ocean where NUVEL-1 plate motion data and plate geometry differ from those used in prior studies and in the Pacific Ocean where NUVEL-1 rates are systematically 5–20 mm yr−1 slower than those of prior models. The strikes of transform faults mapped with GLORIA and Seabeam along the Mid-Atlantic Ridge greatly improve the accuracy of estimates of the direction of plate motion. These data give Euler vectors differing significantly from those of prior studies, show that motion about the Azores triple junction is consistent with plate circuit closure, and better resolve motion between North America and South America. Motion of the Caribbean plate relative to North or South America is about 7 mm yr−1 slower than in prior global models. Trench slip vectors tend to be systematically misfit wherever convergence is oblique, and best-fitting poles determined only from trench slip vectors differ significantly from their corresponding closure-fitting Euler vectors. The direction of slip in trench earthquakes tends to be between the direction of plate motion and the normal to the trench strike. Part of this bias may be due to the neglect of lateral heterogeneities of seismic velocities caused by cold subducting slabs, but the larger part is likely caused by independent motion of fore-arc crust and lithosphere relative to the overriding plate.

3,328 citations

Journal ArticleDOI
TL;DR: This article evaluated subducting sediments on a global basis in order to better define their chemical systematics and to determine both regional and global average compositions, and then used these compositions to assess the importance of sediments to arc volcanism and crust-mantle recycling, and to re-evaluate the chemical composition of the continental crust.

2,973 citations


"Reevaluating carbon fluxes in subdu..." refers methods in this paper

  • ...Plank T, Langmuir CH (1998) The chemical composition of subducting sediment and its consequences for the crust and mantle....

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  • ...[C] in oceanic sediments was reviewed by Rea and Ruff (23), Plank and Langmuir (24), and Plank (25)....

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  • ...Subduction of Carbon-Bearing Sediments: 13–23 Mt C/y [C] in oceanic sediments was reviewed by Rea and Ruff (23), Plank and Langmuir (24), and Plank (25)....

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Journal ArticleDOI
TL;DR: In this paper, a global set of present plate boundaries on the Earth is presented in digital form, taking into account relative plate velocities from magnetic anomalies, moment tensor solutions, and geodesy.
Abstract: [1] A global set of present plate boundaries on the Earth is presented in digital form. Most come from sources in the literature. A few boundaries are newly interpreted from topography, volcanism, and/or seismicity, taking into account relative plate velocities from magnetic anomalies, moment tensor solutions, and/or geodesy. In addition to the 14 large plates whose motion was described by the NUVEL-1A poles (Africa, Antarctica, Arabia, Australia, Caribbean, Cocos, Eurasia, India, Juan de Fuca, Nazca, North America, Pacific, Philippine Sea, South America), model PB2002 includes 38 small plates (Okhotsk, Amur, Yangtze, Okinawa, Sunda, Burma, Molucca Sea, Banda Sea, Timor, Birds Head, Maoke, Caroline, Mariana, North Bismarck, Manus, South Bismarck, Solomon Sea, Woodlark, New Hebrides, Conway Reef, Balmoral Reef, Futuna, Niuafo'ou, Tonga, Kermadec, Rivera, Galapagos, Easter, Juan Fernandez, Panama, North Andes, Altiplano, Shetland, Scotia, Sandwich, Aegean Sea, Anatolia, Somalia), for a total of 52 plates. No attempt is made to divide the Alps-Persia-Tibet mountain belt, the Philippine Islands, the Peruvian Andes, the Sierras Pampeanas, or the California-Nevada zone of dextral transtension into plates; instead, they are designated as “orogens” in which this plate model is not expected to be accurate. The cumulative-number/area distribution for this model follows a power law for plates with areas between 0.002 and 1 steradian. Departure from this scaling at the small-plate end suggests that future work is very likely to define more very small plates within the orogens. The model is presented in four digital files: a set of plate boundary segments; a set of plate outlines; a set of outlines of the orogens; and a table of characteristics of each digitization step along plate boundaries, including estimated relative velocity vector and classification into one of 7 types (continental convergence zone, continental transform fault, continental rift, oceanic spreading ridge, oceanic transform fault, oceanic convergent boundary, subduction zone). Total length, mean velocity, and total rate of area production/destruction are computed for each class; the global rate of area production and destruction is 0.108 m2/s, which is higher than in previous models because of the incorporation of back-arc spreading.

1,853 citations


"Reevaluating carbon fluxes in subdu..." refers background in this paper

  • ...Because slow- and ultraslow-spreading crust is formed at ∼30% of midocean ridges (18, 19), crust composed of altered peridotite is 1–4% of the total, and not a significant part of the global carbon budget....

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Journal ArticleDOI
16 Jul 2004-Science
TL;DR: The geological, geochemical, and biological processes that contributed to the rise of the dinoflagellates, coccolithophores, and diatoms all contain plastids derived from an ancestral red alga by secondary symbiosis are examined.
Abstract: The community structure and ecological function of contemporary marine ecosystems are critically dependent on eukaryotic phytoplankton. Although numerically inferior to cyanobacteria, these organisms are responsible for the majority of the flux of organic matter to higher trophic levels and the ocean interior. Photosynthetic eukaryotes evolved more than 1.5 billion years ago in the Proterozoic oceans. However, it was not until the Mesozoic Era (251 to 65 million years ago) that the three principal phytoplankton clades that would come to dominate the modern seas rose to ecological prominence. In contrast to their pioneering predecessors, the dinoflagellates, coccolithophores, and diatoms all contain plastids derived from an ancestral red alga by secondary symbiosis. Here we examine the geological, geochemical, and biological processes that contributed to the rise of these three, distantly related, phytoplankton groups.

1,348 citations