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Journal ArticleDOI

Reinforcement with graphene nanosheets in aluminum matrix composites

01 Apr 2012-Scripta Materialia (Pergamon)-Vol. 66, Iss: 8, pp 594-597
TL;DR: In this article, aluminum composites reinforced with graphene nanosheets (GNSs) were fabricated for the first time through a feasible methodology based on flake powder metallurgy.
About: This article is published in Scripta Materialia.The article was published on 2012-04-01 and is currently open access. It has received 729 citations till now. The article focuses on the topics: Ultimate tensile strength & Graphene.

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Summary

  • Graphene has a high fracture strength of 125 GPa, making it an ideal reinforcement for composite materials.
  • Aluminum composites reinforced with graphene nanosheets (GNSs) were fabricated for the first time through a feasible methodology based on flake powder metallurgy.
  • The tensile strength of 249 MPa was achieved in the Al composite reinforced with only 0.3 wt.% GNSs, which is 62% enhancement over the unreinforced Al matrix.
  • The relevant strengthening mechanisms involved in the GNS/Al composites were discussed along with experimental procedure.

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Citations
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Journal ArticleDOI
TL;DR: In this article, the authors focus on the recent development in the synthesis, property characterization and application of aluminum, magnesium, and transition metal-based composites reinforced with carbon nanotubes and graphene nanosheets.
Abstract: One-dimensional carbon nanotubes and two-dimensional graphene nanosheets with unique electrical, mechanical and thermal properties are attractive reinforcements for fabricating light weight, high strength and high performance metal-matrix composites. Rapid advances of nanotechnology in recent years enable the development of advanced metal matrix nanocomposites for structural engineering and functional device applications. This review focuses on the recent development in the synthesis, property characterization and application of aluminum, magnesium, and transition metal-based composites reinforced with carbon nanotubes and graphene nanosheets. These include processing strategies of carbonaceous nanomaterials and their composites, mechanical and tribological responses, corrosion, electrical and thermal properties as well as hydrogen storage and electrocatalytic behaviors. The effects of nanomaterial dispersion in the metal matrix and the formation of interfacial precipitates on these properties are also addressed. Particular attention is paid to the fundamentals and the structure–property relationships of such novel nanocomposites.

877 citations

Journal ArticleDOI
TL;DR: In this paper, the authors focus on the recent development in mechanical and tribological behavior of self-lubricating metallic nanocomposites reinforced by carbonous nanomaterials such as CNT and graphene.
Abstract: Rapid innovation in nanotechnology in recent years enabled development of advanced metal matrix nanocomposites for structural engineering and functional devices. Carbonous materials, such as graphite, carbon nanotubes (CNT's), and graphene possess unique electrical, mechanical, and thermal properties. Owe to their lubricious nature, these carbonous materials have attracted researchers to synthesize lightweight self-lubricating metal matrix nanocomposites with superior mechanical and tribological properties for several applications in automotive and aerospace industries. This review focuses on the recent development in mechanical and tribological behavior of self-lubricating metallic nanocomposites reinforced by carbonous nanomaterials such as CNT and graphene. The review includes development of self-lubricating nanocomposites, related issues in their processing, their characterization, and investigation of their tribological behavior. The results reveal that adding CNT and graphene to metals decreases both coefficient of friction and wear rate as well as increases the tensile strength. The mechanisms involved for the improved mechanical and tribological behavior is discussed.

673 citations


Cites background or methods from "Reinforcement with graphene nanoshe..."

  • ...pulled out from the fracture surface [31]...

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  • ...Hence, the graphene too is a good substitution for CNTs as reinforcement for metal matrix composites [31]....

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  • ...To the authors' knowledge, so far, aluminum matrix composite reinforced by graphene has successfully produced only by powder metallurgy method [31,48]....

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  • ...extrusion [31]....

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  • ...3 wt% GNS/Al composite [31]....

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Journal ArticleDOI
Jaewon Hwang1, Taeshik Yoon1, Sung Hwan Jin1, Jinsup Lee1, Taek-Soo Kim1, Soon Hyung Hong1, Seokwoo Jeon1 
TL;DR: The strengthening mechanism of the RGO is investigated by a double cantilever beam test using the graphene/Cu model structure and the yield strength of the 2.5 vol% RGO/Cu nanocomposite is 1.8 times higher than that of pure Cu.
Abstract: RGO flakes are homogeneously dispersed in a Cu matrix through a molecular-level mixing process. This novel fabrication process prevents the agglomeration of the RGO and enhances adhesion between the RGO and the Cu. The yield strength of the 2.5 vol% RGO/Cu nanocomposite is 1.8 times higher than that of pure Cu. The strengthening mechanism of the RGO is investigated by a double cantilever beam test using the graphene/Cu model structure.

577 citations

Journal ArticleDOI
TL;DR: In this article, the authors present an overview of experimental data and theoretical concepts addressing the unique combination of superior strength and enhanced ductility of metallic nanomaterials, and consider the basic approaches and methods for simultaneously optimizing their strength and ductility, employing principal deformation mechanisms, crystallographic texture, chemical composition as well as second-phase nano-precipitates, carbon nanotubes and graphene.

573 citations

Journal ArticleDOI
TL;DR: The use of graphene as reinforcement for structural materials is motivated by their exceptional mechanical/functional properties and their unique physical/chemical characteristics as discussed by the authors. But this review focuses on MMCs and CMCs because of their technological importance for structural applications and the unique challenges associated with developing high-temperature composites with nanoparticle reinforcements.
Abstract: This review critically examines the current state of graphene reinforced metal (GNP-MMC) and ceramic matrix composites (GNP-CMC) The use of graphene as reinforcement for structural materials is motivated by their exceptional mechanical/functional properties and their unique physical/chemical characteristics This review focuses on MMCs and CMCs because of their technological importance for structural applications and the unique challenges associated with developing high-temperature composites with nanoparticle reinforcements The review discusses processing techniques, effects of graphene on the mechanical behaviour of GNP-MMCs and GNP-CMCs, including early studies on the tribological performance of graphene-reinforced composites, where graphene has shown signs of serving as a protective and lubricious phase Additionally, the unique functional properties endowed by graphene to GNP-MMCs and GNP-CMCs, such as enhanced thermal/electrical conductivity, improved oxidation resistance, and excellent bi

456 citations


Cites background from "Reinforcement with graphene nanoshe..."

  • ...be more readily compacted before sintering and forming steps [40]....

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References
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Journal ArticleDOI
22 Oct 2004-Science
TL;DR: Monocrystalline graphitic films are found to be a two-dimensional semimetal with a tiny overlap between valence and conductance bands and they exhibit a strong ambipolar electric field effect.
Abstract: We describe monocrystalline graphitic films, which are a few atoms thick but are nonetheless stable under ambient conditions, metallic, and of remarkably high quality. The films are found to be a two-dimensional semimetal with a tiny overlap between valence and conductance bands, and they exhibit a strong ambipolar electric field effect such that electrons and holes in concentrations up to 10 13 per square centimeter and with room-temperature mobilities of ∼10,000 square centimeters per volt-second can be induced by applying gate voltage.

55,532 citations

Journal ArticleDOI
TL;DR: Owing to its unusual electronic spectrum, graphene has led to the emergence of a new paradigm of 'relativistic' condensed-matter physics, where quantum relativistic phenomena can now be mimicked and tested in table-top experiments.
Abstract: Graphene is a rapidly rising star on the horizon of materials science and condensed-matter physics. This strictly two-dimensional material exhibits exceptionally high crystal and electronic quality, and, despite its short history, has already revealed a cornucopia of new physics and potential applications, which are briefly discussed here. Whereas one can be certain of the realness of applications only when commercial products appear, graphene no longer requires any further proof of its importance in terms of fundamental physics. Owing to its unusual electronic spectrum, graphene has led to the emergence of a new paradigm of 'relativistic' condensed-matter physics, where quantum relativistic phenomena, some of which are unobservable in high-energy physics, can now be mimicked and tested in table-top experiments. More generally, graphene represents a conceptually new class of materials that are only one atom thick, and, on this basis, offers new inroads into low-dimensional physics that has never ceased to surprise and continues to provide a fertile ground for applications.

35,293 citations

Journal ArticleDOI
Changgu Lee1, Xiaoding Wei1, Jeffrey W. Kysar1, James Hone1, James Hone2 
18 Jul 2008-Science
TL;DR: Graphene is established as the strongest material ever measured, and atomically perfect nanoscale materials can be mechanically tested to deformations well beyond the linear regime.
Abstract: We measured the elastic properties and intrinsic breaking strength of free-standing monolayer graphene membranes by nanoindentation in an atomic force microscope. The force-displacement behavior is interpreted within a framework of nonlinear elastic stress-strain response, and yields second- and third-order elastic stiffnesses of 340 newtons per meter (N m(-1)) and -690 Nm(-1), respectively. The breaking strength is 42 N m(-1) and represents the intrinsic strength of a defect-free sheet. These quantities correspond to a Young's modulus of E = 1.0 terapascals, third-order elastic stiffness of D = -2.0 terapascals, and intrinsic strength of sigma(int) = 130 gigapascals for bulk graphite. These experiments establish graphene as the strongest material ever measured, and show that atomically perfect nanoscale materials can be mechanically tested to deformations well beyond the linear regime.

18,008 citations

Journal ArticleDOI
TL;DR: The extremely high value of the thermal conductivity suggests that graphene can outperform carbon nanotubes in heat conduction and establishes graphene as an excellent material for thermal management.
Abstract: We report the measurement of the thermal conductivity of a suspended single-layer graphene. The room temperature values of the thermal conductivity in the range ∼(4.84 ± 0.44) × 103 to (5.30 ± 0.48) × 103 W/mK were extracted for a single-layer graphene from the dependence of the Raman G peak frequency on the excitation laser power and independently measured G peak temperature coefficient. The extremely high value of the thermal conductivity suggests that graphene can outperform carbon nanotubes in heat conduction. The superb thermal conduction property of graphene is beneficial for the proposed electronic applications and establishes graphene as an excellent material for thermal management.

11,878 citations

Journal ArticleDOI
TL;DR: In this paper, a single layer graphene was suspended ∼150nm above a Si/SiO2 gate electrode and electrical contacts to the graphene was achieved by a combination of electron beam lithography and etching.

7,276 citations

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Q1. What have the authors contributed in "Reinforcement with graphene nanosheets in aluminum matrix composites" ?

In this paper, aluminum composites reinforced with graphene nanosheets ( GNSs ) were fabricated for the first time through a feasible methodology based on flake powder metallurgy.