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Reliability Challenges for CMOS Technology Qualifications With Hafnium Oxide/Titanium Nitride Gate Stacks

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TLDR
In this paper, the authors summarized recent advances in the understanding of charge trapping and defect generation in HfO2/TiN gate stacks and discussed test procedures specifically tailored to quantify gate stack reliability.
Abstract
It has been demonstrated that the introduction of HfO2/ TiN gate stacks into CMOS technologies provides the means to continue with traditional device gate length scaling. However, the introduction of HfO2 as a new gate dielectric and TiN as a metallic gate electrode into the gate stack of FETs brings about new challenges for understanding reliability physics and qualification. This contribution summarizes recent advances in the understanding of charge trapping and defect generation in HfO2/ TiN gate stacks. This paper relates the electrical properties to the chemical/physical properties of the high-epsiv dielectric and discusses test procedures specifically tailored to quantify gate stack reliability of HfO2/TiN gate stacks.

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Citations
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Journal ArticleDOI

High-K materials and metal gates for CMOS applications

TL;DR: In this article, a review of the high-K gate stack is presented, including the choice of oxides, their deposition, their structural and metallurgical behaviour, atomic diffusion, interface structure, their electronic structure, band offsets, electronic defects, charge trapping and conduction mechanisms, reliability, mobility degradation and oxygen scavenging.
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Towards CMOS-compatible nanophotonics: Ultra-compact modulators using alternative plasmonic materials

TL;DR: It is shown that an extinction ratio of 46 dB/µm can be achieved, allowing for a 3-dB modulation depth in much less than one micron at the telecommunication wavelength.
Journal ArticleDOI

Ultimate Scaling of High-κ Gate Dielectrics: Higher-κ or Interfacial Layer Scavenging?

Takashi Ando
- 14 Mar 2012 - 
TL;DR: High precise IL thickness control in an ultra-thin IL regime (<0.5 nm) will be the key technology to satisfy both performance and reliability requirements for future CMOS devices.
Journal ArticleDOI

Examining nanophotonics for integrated hybrid systems: a review of plasmonic interconnects and modulators using traditional and alternative materials [Invited]

TL;DR: It is suggested that nanophotonic technologies offer key advantages for future hybrid electrophotonic devices, where the movement toward new material platforms is a precursor to high-performance, industry-ready devices.
Journal ArticleDOI

Enhancing ferroelectricity in dopant-free hafnium oxide

TL;DR: In this article, the oxidant dose was controlled to promote ferroelectricity in dopant-free ALD hafnium oxide films, and the results showed that the reduction of the dose gave a sixfold improvement in remanent polarization.
References
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Journal ArticleDOI

Band offsets of wide-band-gap oxides and implications for future electronic devices

TL;DR: In this paper, the Schottky barrier heights and band offsets for high dielectric constant oxides on Pt and Si were calculated and good agreement with experiment is found for barrier heights.
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High dielectric constant gate oxides for metal oxide Si transistors

TL;DR: In this article, a review of the development of high-k gate oxides such as hafnium oxide (HFO) and high-K oxides is presented, with the focus on the work function control in metal gate electrodes.
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Effective electron mobility in Si inversion layers in metal–oxide–semiconductor systems with a high-κ insulator: The role of remote phonon scattering

TL;DR: In this paper, the dispersion of the interfacial coupled phonon-plasmon modes, their electron-scattering strength, and their effect on the electron mobility for Si-gate structures were investigated.
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New insights in the relation between electron trap generation and the statistical properties of oxide breakdown

TL;DR: In this paper, a percolation-based model for intrinsic breakdown in thin oxide layers is proposed, which can explain the experimentally observed statistical features of the breakdown distribution, such as the increasing spread of the Q/sub BD/-distribution for ultrathin oxides.
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