Reticular synthesis and the design of new materials
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...These materials are constructed by joining metal-containing units [secondary building units (SBUs)] with organic linkers, using strong bonds (reticular synthesis) to create open crystalline frameworks with permanent porosity (1)....
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...MOF-1001 [Zn4O(BPP34C10DA)3; BPP34C10DA = 4,4′-(2,5,8,11,14,16,19,22,25,28decaoxa-1,15(1,4)-dibenzenacyclooctacosaphane1(2),1(5)-diylbis(ethyne-2,1-diyl))dibenzoate] uses periodic crown ether receptors attached to the architectural framework; this endows the pore with active domains capable of molecular recognition of highly disordered guests in a stereoelectronically controlled fashion (Fig....
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...works inwhich single atomswere linked by ditopic coordinating linkers (1)....
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"Reticular synthesis and the design ..." refers background in this paper
...In many cases, such solids are interchangeably referred to as “porous” and “open-framework”, without definitive proof of porosit...
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"Reticular synthesis and the design ..." refers background in this paper
...In this context, it is worth noting that a plethora of extended structures successfully prepared by copolymerization of metal ions with organic links have been reported and reviewed under the rubric of ‘crystal engineering’, a term which has mutated somewhat over the years and which is now rather broadly define...
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