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Review on microencapsulated phase change materials (MEPCMs): Fabrication, characterization and applications

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TLDR
In this paper, a comprehensive review has been carried out for microencapsulated phase change materials (MEPCMs), which is one of the most efficient ways of storing thermal energy and it has received a growing attention in the past decade.
Abstract
The use of latent heat storage, microencapsulated phase change materials (MEPCMs), is one of the most efficient ways of storing thermal energy and it has received a growing attention in the past decade. However, there is no complete overview of its utilization in thermal energy storage systems, and the information is widely spread in the literature. In this paper, a comprehensive review has been carried out for MEPCMs. Four aspects have been the focus of this review: fabrication and characterization of MEPCMs, applications of MEPCMs to the textile and building, fundamental properties of microencapsulated phase change material slurry (MPCS) and application of MPCS to the thermal energy storage system. Over 140 recent publications are referenced in this paper.

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Journal ArticleDOI

A review of microencapsulation methods of phase change materials (PCMs) as a thermal energy storage (TES) medium

TL;DR: In this article, the most common methods described in the literature for the production of microencapsulated phase change materials (MEPCMs) are interfacial polymerization, suspension polymerization and spray drying.
Journal ArticleDOI

Review of solid–liquid phase change materials and their encapsulation technologies

TL;DR: In this article, a review of solid-liquid phase change materials (PCMs) for thermal energy storage applications is presented, where the morphology of particles is identified as a key influencing factor on the thermal and chemical stability and the mechanical strength of encapsulated PCMs.
Journal ArticleDOI

Thermal energy storage: Recent developments and practical aspects

TL;DR: In this article, a review of thermal energy storage using phase change materials (PCMs), mainly using liquid-solid transition to store latent heat, allows a more compact, efficient and therefore economical system to operate.
Journal ArticleDOI

Organic phase change materials and their textile applications: An overview

TL;DR: In this paper, the potential industrial applications of PCMs in textiles and clothing systems, the methods of PCM integration into textiles, and the method of evaluating their thermal properties are also presented.
Journal ArticleDOI

A review of performance enhancement of PCM based latent heat storage system within the context of materials, thermal stability and compatibility

TL;DR: In this article, the authors focused on the classification of various paraffins and salt hydrates, and provided an understanding on how to maximize thermal utilization of PCM and how to improve the phase transition rate, thermal conductivity, latent heat storage capacity and thermo-physical stability.
References
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Journal ArticleDOI

Review on thermal energy storage with phase change materials and applications

TL;DR: The use of a latent heat storage system using phase change materials (PCMs) is an effective way of storing thermal energy and has the advantages of high energy storage density and the isothermal nature of the storage process.
Journal ArticleDOI

Review on thermal energy storage with phase change: materials, heat transfer analysis and applications

TL;DR: In this paper, a review of the history of thermal energy storage with solid-liquid phase change has been carried out and three aspects have been the focus of this review: materials, heat transfer and applications.
Journal ArticleDOI

Applications of spray-drying in microencapsulation of food ingredients: An overview

TL;DR: In this article, the main process engineering information that are considered useful to the success of a microencapsulation operation by spray-drying is reported, and a summary of the most commonly used wall materials and the main encapsulated food compounds are presented.
Journal ArticleDOI

Encapsulation in the food industry: a review

TL;DR: Most recent developments include the encapsulation of foods in the areas of controlled release, carrier materials, preparation methods and sweetener immobilization.
Journal ArticleDOI

Transport characteristics of suspension: VIII. A note on the viscosity of Newtonian suspensions of uniform spherical particles

TL;DR: In this article, a critical analysis of the extensive experimental data on the relative viscosity of suspensions of uniform spherical particles was made, and the coefficients of different power series relating relative visco-solutions and volume fraction solids were determined using a nonlinear least squares procedure.
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Copyright and reuse: The Warwick Research Archive Portal ( WRAP ) makes the work of researchers of the University of Warwick available open access under the following conditions. Copyright © and all moral rights to the version of the paper presented here belong to the individual author ( s ) and/or other copyright owners. 

Coolant flow rate and temperature, heat exchanger design factors, and the MPCS flow rate were important factors in thermal performance of such a loop system. 

Two enhancement ratios, the traditional enhancement ratio and a modified enhancement ratio, were used to quantify the enhanced heat transfer characteristics of the microencapsulated phase change suspension for six major parameters. 

Physical methods are mainly spray drying or centrifugal and fluidized bed processes, which are inherently not capable of producing microcapsules smaller than 100 µm. 

The chemical processes include the interfacial polymerization, in situ polymerization, the sample or complex coacervation, phase separation, suspension-like polymerization and other fabrication methods. 

The results also indicated that “Rayleigh number”, “Prandtl number” and aspect ratio could be the main parameters for evaluating a natural convection in enclosures for most of Newtonian and nonNewtonian fluids. 

Heat transfer enhancement were influenced by various sets of the relevant dimensionless parameters, including the particle volume concentration, the modified “Stefan number”, the “Peclet number” of MPCS, the wall thickness ratio, and the wall to fluid thermal conductivity ratio. 

They demonstrated that microcapsules contained more core material by either increasing the ratio of styrene to maleic anhydride groups in the copolymer, or by incorporating t-butyl styrene instead of styrene into the copolymer. 

The treated fabrics were quite promising in terms of its thermal storage/release, durability, and temperature sensing properties. 

Applications of MEPCM in the textile and building were presented; the results concluded that MEPCM had good potential for thermal energy storage purposes and it could be used for solar space heating as well. 

The results showed that when particle volume fractions increased the slurry flow structure changed from turbulent to laminar, and the pressure-drop reduction of the slurry flow relative to a single phase water flow was under the same flow rate conditions. 

The presence of a crosslinked affects the morphology of the external microcapsule surface; the microcapsule external surface appeared smooth with a crosslinked. 

Zhang et al. [28] demonstrated that the degree of super-cooling of microencapsulated n-octadecane is decreased by adding 10.0 wt. % of 1-octadecanol as a nucleating agent. 

The heat transfer coefficient of MPCS was increased by both effects of latent heat in phase change process and convection around particles with different diameters. 

The stirring rate, emulsifier content and cyclohexane content have effects on the diameters and morphology of the microencapsulated n-octadecane, as shown in Fig. 4 [22]. 

They concluded that the microencapsulation efficiency (%) was about 87 % and the loading amount of Migrin oil in the microcapsules was about 53 wt.