Journal ArticleDOI
Rigid Pillars and Double Walls in a Porous Metal-Organic Framework: Single-Crystal to Single-Crystal, Controlled Uptake and Release of Iodine and Electrical Conductivity
Ming-Hua Zeng,Qiang-Xin Wang,Yan-Xi Tan,Sheng Hu,Hai-Xia Zhao,La-Sheng Long,Mohamedally Kurmoo +6 more
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TLDR
A highly stable pillared and double-walled zinc(II) metal-organic framework with regular nanochannels displays single-crystal to single-Crystal transformation upon desolvation and a large quantity of iodine uptake, controlled release, and electrical conductivity elevation due to synergy between the iodine guests and the host framework.Abstract:
A highly stable pillared and double-walled zinc(II) metal-organic framework with regular nanochannels displays single-crystal to single-crystal transformation upon desolvation and a large quantity of iodine uptake, controlled release, and electrical conductivity elevation due to synergy between the iodine guests and the host framework.read more
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Metal‐Organic Frameworks: A Rapidly Growing Class of Versatile Nanoporous Materials
TL;DR: This review covers advances in the MOF field from the past three years, focusing on applications, including gas separation, catalysis, drug delivery, optical and electronic applications, and sensing.
Journal ArticleDOI
Electrically Conductive Metal-Organic Frameworks.
TL;DR: This Review discusses the efforts undertaken so far to achieve efficient charge transport in MOFs and focuses on four common strategies that have been harnessed toward high conductivities.
Journal ArticleDOI
Role of solvents in coordination supramolecular systems
Cheng-Peng Li,Miao Du +1 more
TL;DR: This feature article aims to demonstrate the solvent effect on regulating such diversiform metallosupramolecular solids, incorporating their crystal growth/assembly, structural modulation, dynamic transformations, and potential applications, which may provide new insights into the rational design and construction of such advanced crystalline materials.
Journal ArticleDOI
Capture of Volatile Iodine, a Gaseous Fission Product, by Zeolitic Imidazolate Framework-8
Dorina F. Sava,Mark A. Rodriguez,Karena W. Chapman,Peter J. Chupas,Jeffery A. Greathouse,Paul Stewart Crozier,Tina M. Nenoff +6 more
TL;DR: Detailed structural evidence is presented of captured molecular iodine (I(2), a volatile gaseous fission product, within the metal-organic framework ZIF-8 [zeolitic imidazolate framework-8 or Zn(2-methylimidazolated)(2)] to understand the capture of I(2) via bonding with the framework.
Journal ArticleDOI
New Porous Crystals of Extended Metal-Catecholates
Mohamad Hmadeh,Zheng Lu,Zheng Liu,Felipe Gándara,Hiroyasu Furukawa,Shun Wan,Veronica Augustyn,Rui Chang,Lei Liao,Fei Zhou,Emilie Perre,Vidvuds Ozolins,Kazu Suenaga,Xiangfeng Duan,Bruce Dunn,Yasuaki Yamamto,Osamu Terasaki,Omar M. Yaghi +17 more
TL;DR: Mohamad Hmadeh et al. as discussed by the authors have proposed a method to improve the performance of nanotube research through mentoring, which has been shown to yield promising results in the field of Reticular Chemistry.
References
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Journal ArticleDOI
Selective gas adsorption and separation in metal–organic frameworks
TL;DR: This critical review starts with a brief introduction to gas separation and purification based on selective adsorption, followed by a review of gas selective adsorbents in rigid and flexible MOFs, and primary relationships between adsorptive properties and framework features are analyzed.
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A route to high surface area, porosity and inclusion of large molecules in crystals
Hee K. Chae,Diana Y. Siberio-Pérez,Jaheon Kim,Yong Bok Go,Mohamed Eddaoudi,Adam J. Matzger,Michael O'Keeffe,Omar M. Yaghi +7 more
TL;DR: The design, synthesis and properties of crystalline Zn4O(1,3,5-benzenetribenzoate)2 are reported, a new metal-organic framework with a surface area estimated at 4,500 m2 g-1 that combines this exceptional level of surface area with an ordered structure that has extra-large pores capable of binding polycyclic organic guest molecules.
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Magnetic metal-organic frameworks.
TL;DR: The diversity of magnetic exchange interactions between nearest-neighbour moment carriers is examined, covering from dimers to oligomers and their implications in infinite chains, layers and networks, having a variety of topologies.
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Secondary building units, nets and bonding in the chemistry of metal–organic frameworks
TL;DR: The geometries of 131 SBUs, their connectivity and composition of transition-metal carboxylate clusters which may serve as secondary building units (SBUs) towards construction and synthesis of metal-organic frameworks (MOFs).
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Storage of Hydrogen, Methane, and Carbon Dioxide in Highly Porous Covalent Organic Frameworks for Clean Energy Applications
Hiroyasu Furukawa,Omar M. Yaghi +1 more
TL;DR: Findings place COFs among the most porous and the best adsorbents for hydrogen, methane, and carbon dioxide.