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Journal ArticleDOI

Role of Amino-Acid Adsorption on Silica and Silicon Nitride Surfaces during STI CMP

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TLDR
In this article, the role of adsorption of the amino acids L-proline and L-arginine on silicon dioxide and silicon nitride surfaces was characterized as a function of pH and concentration using thermogravimetric analysis.
Abstract
Selectivity (oxide/nitride polish rate) is a critical factor during chemical mechanical polishing (CMP) of shallow trench isolation (STI) structure, and it can be modified by adding amino acids to the slurry. The role of adsorption of the amino acids L-proline and L-arginine, on silicon dioxide and silicon nitride surfaces was characterized as a function of pH and concentration using thermogravimetric analysis. The results suggest that the adsorption behavior does not correlate with the polishing behavior of STI CMP and hence it may not play a key role in changing the selectivity.

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Citations
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Journal ArticleDOI

Chemical mechanical planarization: slurry chemistry, materials, and mechanisms.

TL;DR: This work focuses on the application of CMP to FEOL and MOL systems, which combines low-k and Ultralow-k materials, and the challenges faced by these systems in the aftermath of the Chernobyl disaster.
Journal ArticleDOI

Shallow Trench Isolation Chemical Mechanical Planarization: A Review

TL;DR: In this paper, a review of high selectivity shallow trench isolation (STI) CMP slurries is presented along with the characteristics of the colloidal dispersions like the abrasives, additives, the interactions between them and with the films being planarized and the associated pH range in which the high selectivities are observed.
Journal ArticleDOI

Role of Different Additives on Silicon Dioxide Film Removal Rate during Chemical Mechanical Polishing Using Ceria-Based Dispersions

TL;DR: In this paper, the role of several additives used with ceria-based dispersions to polish silicon dioxide films and investigate their interaction with both the abrasives and silicon dioxide film using several techniques.
Journal ArticleDOI

The effect of hydrogen peroxide on polishing removal rate in CMP with various abrasives

TL;DR: The effect of hydrogen peroxide in chemical planarization slurries for shallow trench isolation was investigated in this article, where various abrasives used in this study were ceria, silica, alumina, zirconia, titania, silicon carbide, and silicon nitride.
Patent

Aqueous polishing composition and process for chemically mechanically polishing substrates containing silicon oxide dielectric and polysilicon films

TL;DR: In this article, an aqueous polishing composition has been found, the composition comprising at least one type of abrasive particles which are positively charged when dispersed in an anionic phosphate dispersing agent; and a process for polishing substrate materials for electrical, mechanical and optical devices.
References
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Journal ArticleDOI

Chemical processes in glass polishing

TL;DR: In this article, a detailed mechanico-chemical model for the glass polishing process is proposed, and the central chemical process which occurs is the interaction of both the glass surface and the polishing particle with water.
Book

Chemical Mechanical Planarization of Microelectronic Materials

TL;DR: In this article, historical perspective CMP: variables and manipulations electrochemical and mechanical concepts for CMP processes copper CMP CMP of other materials post CMP cleaning, and a discussion of the relationship between CMP and manipulation.
Journal ArticleDOI

Chemical mechanical planarization for microelectronics applications

TL;DR: An overview of the CMP process in general, the science and mechanism of polishing, different metal and dielectric CMP processes as well as the future trends are discussed in this paper.
Journal ArticleDOI

Mechanism of polishing of SiO2 films by CeO2 particles

TL;DR: In this paper, the authors examined the polishing mechanism in chemical mechanical polishing of a thermally grown SiO 2 film by CeO 2 particles, and the surface structure of the film and the waste were investigated by various analytical means.
BookDOI

Chemical-mechanical planarization of semiconductor materials

TL;DR: In this paper, the authors present a detailed overview of CMP technology and its application in metal CMP processes, as well as equipment used in CMP process and tools used to clean CMP slurry.
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