Journal ArticleDOI
RuCl2(PPh3)3-catalyzed transfer hydrogenation of d-glucose
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TLDR
In this paper, a mixed solvent system such as dimethylacetamide-water and dioxane-water is used for the transfer hydrogenation of glucose to a mixture of mixed solvent systems.About:
This article is published in Journal of Molecular Catalysis.The article was published on 1992-09-15. It has received 16 citations till now. The article focuses on the topics: Benzyl alcohol & Cyclohexanol.read more
Citations
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Chemical conversion pathways for carbohydrates
TL;DR: A review of the recent developments in liquid phase chemical conversions of monosaccharides, disaccharide, and polysaccharides can be found in this paper, followed by a process-driven approach where the existing carbohydrate conversion pathways are classified according to the types of chemical processes involved.
Journal ArticleDOI
Homogeneous catalysis for the conversion of biomass and biomass-derived platform chemicals
TL;DR: In this article, the authors provide an overview of the most important recent developments in homogeneous catalysis towards the production and transformation of biomass and biomass related model compounds, including the chemical valorisation of the main components of lignocellulosic biomass.
Journal ArticleDOI
Combined Homogeneous and Heterogeneous Catalysts. Rhodium and Platinum Isocyanide Complexes Tethered on Silica-Supported Metal Heterogeneous Catalysts: Arene and Cyclohexanone Hydrogenation †
Hanrong Gao,Robert J. Angelici +1 more
TL;DR: In this paper, the TCSM (tethered complex on supported metal) catalysts were used to catalyze the hydrogenation of arenes (Rh−CNR2/Pd−SiO2 and rhCl[CN(CH2)3Si(OC2H5)3]2) under mild conditions of 40 °C and 1 atm.
Journal ArticleDOI
A highly productive, whole-cell DERA chemoenzymatic process for production of key lactonized side-chain intermediates in statin synthesis.
TL;DR: To the authors' knowledge, this is the first asymmetric aldol condensation process achieved with whole-cell DERA catalysis and it simplifies and extends previously developed DERA-catalyzed approaches based on the isolated enzyme.
Journal ArticleDOI
A new and direct access to glycono-1,4-lactones from glycopyranoses by regioselective oxidation and subsequent ring restriction
TL;DR: In this article, the authors show that the treatment of partially protected or unprotected carbohydrates with the RhH(PPh 3 ) 4 -benzalacetone system leads exclusively to glycono-1,4-lactones by regioselective oxidation and subsequent ring restriction.
References
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Journal ArticleDOI
New complexes of ruthenium (II) and (III) with triphenylphosphine, triphenylarsine, trichlorostannate, pyridine and other ligands
T.A. Stephenson,G. Wilkinson +1 more
TL;DR: In this article, the interaction of triphenylphosphine, -arsine and -stibine with hydrated ruthenium trichloride in methanol leads to a variety of complexes such as [RuCl2(PPh3)4], [RuCL2(SbPh3]3], RuCl3(Pph3)2CH3OH, [RuC2(CPh3As, Ph3Sb, pyridine etc., with a carbonyl-containing solution] and the corresponding brom
Journal ArticleDOI
Catalytic Transfer Hydrogenation
TL;DR: In this paper, the authors present an overview of the potential applications of structural selectivity in the field of Synthetic Synthetic Applications (Synthetic Applications IV. Mechanism V. Summary and Prospects V I, References
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Detailed tautomeric equilibrium of aqueous D-glucose. Observation of six tautomers by ultrahigh resolution carbon-13 NMR
Steven R. Maple,Adam Allerhand +1 more
Journal ArticleDOI
Hydrogen Transfer from Organic Compounds Catalysed by Transition Metal Complexes
TL;DR: In this paper, a review deals with the new rapidly developing field of homogeneous catalysis and coordination chemistry, namely with reactions involving hydrogen transfer from organic compounds to transition metal complexes accompanied by the dissociation of a C-H bond and the formation of a metal-hydrogen bond.
Journal ArticleDOI
Decarbonylation of unprotected aldose sugars by chlorotris(triphenylphosphine)rhodium(I). A new descent of series approach to alditols, deoxyalditols, and glycosylalditols
TL;DR: La decarbonylation de C n aldoses non proteges par un complexe du rhodium donne les correspondants C n -1 alditols as mentioned in this paper.
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