Journal ArticleDOI
RuCl2(PPh3)3-catalyzed transfer hydrogenation of d-glucose
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TLDR
In this paper, a mixed solvent system such as dimethylacetamide-water and dioxane-water is used for the transfer hydrogenation of glucose to a mixture of mixed solvent systems.About:
This article is published in Journal of Molecular Catalysis.The article was published on 1992-09-15. It has received 16 citations till now. The article focuses on the topics: Benzyl alcohol & Cyclohexanol.read more
Citations
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Continuous Transfer Hydrogenation of Sugars to Alditols with Bioderived Donors over Cu–Ni–Al Catalysts
TL;DR: In this paper, the authors used hydrotalcite-derived Cu6−xNixAl2 catalysts for the transfer of sugars to alditols with biobased alcohol donors.
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Comparative study of homogeneous hydrogenation of d-glucose and d-mannose catalyzed by water soluble [Ru(tri(m-sulfophenyl) phosphine)] complex
Snježana Kolarić,Vitomir Šunjić +1 more
TL;DR: In this paper, homogeneous hydrogenation of two epimeric aldoses, d -glucose (d -Glc) and d -mannose ( d -Man) was performed in water, with molecular hydrogen and by transfer hydrogenation catalyzed by [Ru-TPPTS] complex (TPPTS = trisodium salt of tri(m -sulfophenyl)phosphine).
Journal ArticleDOI
Engineered, highly productive biosynthesis of artificial, lactonized statin side-chain building blocks: The hidden potential of Escherichia coli unleashed
TL;DR: The combined overexpression of the endogenous DERA and the membrane-bound, PQQ-dependent glucose dehydrogenase, the latter being coupled to the respiratory chain, allows direct biosynthesis of 6-substituted lactones in a highly productive, high-yield, cost-effective and industrially scalable process.
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Transformation of Glucose into Sorbitol on Raney Nickel Catalysts in the Absence of Molecular Hydrogen: Sugar Disproportionation vs Catalytic Hydrogen Transfer
TL;DR: In this article, Raney nickel catalysts have been tested in the transformation of glucose into sorbitol through a hydrogen transfer pathway in the presence of short chain alcohols and showed that catalytic hydrogen transfer was only possible from ethanol under the tested neutral conditions.
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Hydrogenation and transfer hydrogenation of d-fructose catalyzed by dichlorotris (triphenylphosphine) ruthenium (II)
TL;DR: In this article, RuCl 2 (PPh 3 ) 3 was used as a catalyst for the transfer hydrogenation of fructose to mannitol and glucitol in an inert atmosphere.
References
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Journal ArticleDOI
New complexes of ruthenium (II) and (III) with triphenylphosphine, triphenylarsine, trichlorostannate, pyridine and other ligands
T.A. Stephenson,G. Wilkinson +1 more
TL;DR: In this article, the interaction of triphenylphosphine, -arsine and -stibine with hydrated ruthenium trichloride in methanol leads to a variety of complexes such as [RuCl2(PPh3)4], [RuCL2(SbPh3]3], RuCl3(Pph3)2CH3OH, [RuC2(CPh3As, Ph3Sb, pyridine etc., with a carbonyl-containing solution] and the corresponding brom
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Catalytic Transfer Hydrogenation
TL;DR: In this paper, the authors present an overview of the potential applications of structural selectivity in the field of Synthetic Synthetic Applications (Synthetic Applications IV. Mechanism V. Summary and Prospects V I, References
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Detailed tautomeric equilibrium of aqueous D-glucose. Observation of six tautomers by ultrahigh resolution carbon-13 NMR
Steven R. Maple,Adam Allerhand +1 more
Journal ArticleDOI
Hydrogen Transfer from Organic Compounds Catalysed by Transition Metal Complexes
TL;DR: In this paper, a review deals with the new rapidly developing field of homogeneous catalysis and coordination chemistry, namely with reactions involving hydrogen transfer from organic compounds to transition metal complexes accompanied by the dissociation of a C-H bond and the formation of a metal-hydrogen bond.
Journal ArticleDOI
Decarbonylation of unprotected aldose sugars by chlorotris(triphenylphosphine)rhodium(I). A new descent of series approach to alditols, deoxyalditols, and glycosylalditols
TL;DR: La decarbonylation de C n aldoses non proteges par un complexe du rhodium donne les correspondants C n -1 alditols as mentioned in this paper.
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