RuCl2(PPh3)3-catalyzed transfer hydrogenation of d-glucose
TL;DR: In this paper, a mixed solvent system such as dimethylacetamide-water and dioxane-water is used for the transfer hydrogenation of glucose to a mixture of mixed solvent systems.
About: This article is published in Journal of Molecular Catalysis.The article was published on 1992-09-15. It has received 16 citations till now. The article focuses on the topics: Benzyl alcohol & Cyclohexanol.
Citations
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TL;DR: In this paper, water-soluble homogeneous catalysts used for hydrogenation of aldehydes and aldoses are reviewed. Butler et al. focus on the mechanistic aspects of their activity and modes of their deactivation.
Abstract: Homogeneous catalysts used in hydrogenation of aldehydes and aldoses, mechanistic aspects of their activity, and modes of their deactivation are reviewed. Particular attention is paid to water soluble homogenous catalysts used for hydrogenation of sugars.
12 citations
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TL;DR: In this article, Ru(II and Ni(II) complexes of aminomethylphosphine ligands supported on Fe3O4@SiO2 (core@shell) surface have been synthesized with Schlenk technique and characterized with Scanning Electron Microscopy (SEM), Energy-Dispersive X-Ray Spectroscopy (EDX), Transmission Electromechanical Imaging (TEM), XRD, Fourier Transform Infrared Spectrograph (FT-IR), Ultraviolet-Vis, Thermogravimetric
5 citations
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TL;DR: An iron-catalysed transfer hydrogenation methodology was developed to oxidise aldo-hexoses and -pentoses into sugar lactones using different acceptors using differentacceptors.
1 citations
References
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TL;DR: In this article, the interaction of triphenylphosphine, -arsine and -stibine with hydrated ruthenium trichloride in methanol leads to a variety of complexes such as [RuCl2(PPh3)4], [RuCL2(SbPh3]3], RuCl3(Pph3)2CH3OH, [RuC2(CPh3As, Ph3Sb, pyridine etc., with a carbonyl-containing solution] and the corresponding brom
697 citations
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TL;DR: In this paper, the authors present an overview of the potential applications of structural selectivity in the field of Synthetic Synthetic Applications (Synthetic Applications IV. Mechanism V. Summary and Prospects V I, References
Abstract: 1. Olefins 2. Acetylenes 3. Carbonyl Compounds 4. Nitriles 5. Imines, Hydroxylamines, Hydrazones 6. Azo Compounds 7. Nitro Compounds B. Hydrogenolysis 1 , Nitriles 2. Halides 3. Allylic and Benzylic Functional Groups 4. Amines C. Structural Selectivity D. Special Synthetic Applications IV. Mechanism V . Summary and Prospects V I , References 567 568 568 569 569 570 570 570 570 570 570 571 571 571 571 571 571 571 571 571 573 574 575 576 580 580
627 citations
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TL;DR: In this paper, a review deals with the new rapidly developing field of homogeneous catalysis and coordination chemistry, namely with reactions involving hydrogen transfer from organic compounds to transition metal complexes accompanied by the dissociation of a C-H bond and the formation of a metal-hydrogen bond.
Abstract: The review deals with the new rapidly developing field of homogeneous catalysis and coordination chemistry, namely with reactions involving hydrogen transfer from organic compounds to transition metal complexes accompanied by the dissociation of a C–H bond and the formation of a metal–hydrogen bond. Particular attention has been devoted to catalytic reactions in which transition metal compounds serve as catalysts of hydrogen transfer and of the reduction of organic compounds by the C–H bonds of other organic molecules. The bibliography includes 177 references.
36 citations
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TL;DR: La decarbonylation de C n aldoses non proteges par un complexe du rhodium donne les correspondants C n -1 alditols as mentioned in this paper.
Abstract: La decarbonylation de C n aldoses non proteges par un complexe du rhodium donne les correspondants C n -1 alditols
26 citations