Open AccessDOI
Ruthenium(III) catalyzed oxidation of 1-phenylethanol and substituted 1-phenylethanols by phenyliodosoacetate
K. Vijayasri,J. Rajaram,J. C. Kuriacose +2 more
- Vol. 95, Iss: 5, pp 573-578
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TLDR
In this paper, the formation of a complex of Ru(III) and (pia) which reacts with the substrate, S, in a slow step is presented. But this complex is not a π-complex.Abstract:
Ruthenium(III) catalysed oxidation of 1-phenylethanol and substituted 1-phenylethanols by phenyliodosoacetate (pia) in acetic acid is studied and a probable mechanism suggested. The proposed mechanism involves the formation of a complex of Ru(III) and (pia) which reacts with the substrate, S, in a slow step. Spectrophotometric evidence for this complex is presented. Studies on the effect of substituents suggest a transition state involving a π-complex.read more
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Journal ArticleDOI
Kinetics and Mechanism of Ruthenium(III) Catalyzed Oxidation of LProline by Hexacyanoferrate(III) in Aqueous Alkali
TL;DR: In this article, the rate law of ruthenium(III) catalyzed oxidation of L-proline by hexacyanoferrate (III) in alkali was studied spectrophotometrically.
Journal ArticleDOI
Os (VIII) Catalyzed Oxidative Cleavage of Pyrrolidine Ring in L-Proline by Sodium Periodate (NaIO4) in Alkaline Medium
TL;DR: In this paper, a kinetic and mechanistic investigation of catalyzed oxidation of proline by sodium periodate (NaIO4) in alkaline medium in temperature range 30 0 C to 45 0 C was conducted.
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