Journal ArticleDOI
Selective oxidation of alcohols and aldehydes over supported metal nanoparticles
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In this article, the authors examined the literature on supported metal catalysts for the oxidation of molecules of interest in biomass conversion (primary alcohols, polyols, 5-hydroxymethylfurfural, and various sugars).About:
This article is published in Green Chemistry.The article was published on 2013-01-01. It has received 622 citations till now. The article focuses on the topics: Alcohol oxidation & Catalysis.read more
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Metal Catalysts for Heterogeneous Catalysis: From Single Atoms to Nanoclusters and Nanoparticles.
Lichen Liu,Avelino Corma +1 more
TL;DR: This Review will compare the results obtained from different systems and try to give a picture on how different types of metal species work in different reactions and give perspectives on the future directions toward better understanding of the catalytic behavior of different metal entities in a unifying manner.
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Conversion of Biomass into Chemicals over Metal Catalysts
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Control of metal-support interactions in heterogeneous catalysts to enhance activity and selectivity
TL;DR: In this paper, a review of metal-support interaction tuning strategies to enhance catalytic performance for various reactions is presented, showing that up to fifteen-fold productivity enhancement has been achieved, and that metal support interaction is most impactful for metal nanoparticles smaller than four nanometres.
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Layer-by-layer Nanoarchitectonics: Invention, Innovation, and Evolution
Katsuhiko Ariga,Yusuke Yamauchi,Gaulthier Rydzek,Qingmin Ji,Yusuke Yonamine,Kevin C.-W. Wu,Jonathan P. Hill +6 more
TL;DR: In this article, a bottom-up-type self-assembly method is used for materials fabrication with nanoscale structural precision based on bottom-down selfassembly, which has become more important in various current disciplines in chemistry including materials chemistry, materials engineering, and biology.
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Recent advances in heterogeneous selective oxidation catalysis for sustainable chemistry
TL;DR: Recent advances in the development of new catalytic materials or novel catalytic systems for challenging oxidation reactions, which are important from the viewpoint of green and sustainable chemistry and still remain challenging, are summarized.
References
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Journal ArticleDOI
Technology development for the production of biobased products from biorefinery carbohydrates—the US Department of Energy’s “Top 10” revisited
TL;DR: An updated evaluation of potential target structures using similar selection methodology, and an overview of the technology developments that led to the inclusion of a given compound are presented.
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Liquid-phase catalytic processing of biomass-derived oxygenated hydrocarbons to fuels and chemicals.
TL;DR: An overview of chemical catalytic transformations of biomass-derived oxygenated feedstocks in the liquid phase to value-added chemicals and fuels is presented, with specific examples emphasizing the development of catalytic processes based on an understanding of the fundamental reaction chemistry.
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Solvent-Free Oxidation of Primary Alcohols to Aldehydes Using Au-Pd/TiO2 Catalysts
Dan I. Enache,Jennifer K. Edwards,Philip Landon,Benjamin Solsona-Espriu,Albert Frederick Carley,Andrew A. Herzing,Masashi Watanabe,Christopher J. Kiely,David W. Knight,Graham J. Hutchings +9 more
TL;DR: It is shown that Au/Pd-TiO2 catalysts give very high turnover frequencies (up to 270,000 turnovers per hour) for the oxidation of alcohols, including primary alkyl alcohols and the addition of Au to Pd nanocrystals improved the overall selectivity.
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A collaborative effect between gold and a support induces the selective oxidation of alcohols.
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Hydroxyapatite-Supported Palladium Nanoclusters: A Highly Active Heterogeneous Catalyst for Selective Oxidation of Alcohols by Use of Molecular Oxygen
TL;DR: The present Pd catalyst does not require additives to complete the catalytic cycle, and the diameters of the generated Pd nanoclusters can be controlled upon acting on the alcohol substrates used.