Sensitivity enhancement by using few-layer black phosphorus-graphene/TMDCs heterostructure in surface plasmon resonance biochemical sensor
TL;DR: In this paper, a surface plasmon resonance (SPR) biochemical sensor based on the different heterostructures of few-layer black phosphorus (BP) and graphene/transition metal dichalcogenides (TMDCs) was proposed.
Abstract: The heterostructure of two-dimensional (2D) materials are promising and useful in the field of surface plasmon resonance (SPR) biochemical sensors. To enhance the sensitivity, we design a novel SPR biochemical sensor by using heterostructures of few-layer black phosphorus (BP) and graphene/transition metal dichalcogenides (TMDCs). The SPR biochemical sensor based on the different heterostructures of BP and graphene/TMDCs are analyzed, and the highest sensitivity with 279°/RIU for the heterostructure of BP and bilayer WSe2 is obtained. Moreover, the proposed biochemical sensor can be used to detect the analyte with different refractive index. The most prominent advantage of the proposed structure is its high sensitivity. The maximum sensitivity of our proposed SPR biochemical sensor is about 2.4 times of the conventional biochemical sensor. We believe that this biochemical sensor could find potential applications in chemical examination, medical diagnosis and biological detection.
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TL;DR: A surface plasmon resonance sensor based on two-dimensional nanomaterial of antimonene for the specific label-free detection of clinically relevant biomarkers such as miRNA-21 and mi RNA-155 and provides a promising avenue for the early diagnosis, staging, and monitoring of cancer.
Abstract: MicroRNA exhibits differential expression levels in cancer and can affect cellular transformation, carcinogenesis and metastasis. Although fluorescence techniques using dye molecule labels have been studied, label-free molecular-level quantification of miRNA is extremely challenging. We developed a surface plasmon resonance sensor based on two-dimensional nanomaterial of antimonene for the specific label-free detection of clinically relevant biomarkers such as miRNA-21 and miRNA-155. First-principles energetic calculations reveal that antimonene has substantially stronger interaction with ssDNA than the graphene that has been previously used in DNA molecule sensing, due to thanking for more delocalized 5s/5p orbitals in antimonene. The detection limit can reach 10 aM, which is 2.3-10,000 times higher than those of existing miRNA sensors. The combination of not-attempted-before exotic sensing material and SPR architecture represents an approach to unlocking the ultrasensitive detection of miRNA and DNA and provides a promising avenue for the early diagnosis, staging, and monitoring of cancer.
432 citations
TL;DR: In this paper, the authors focus on optical refractive index (RI) sensors with no fluorescent labeling required, and utilize two parameters to characterize and compare the performance of optical RI sensors: sensitivity to RI change (denoted by symbol SRI) and figure of merit (in short, FoM).
Abstract: DOI: 10.1002/adom.201801433 Scientific American selects plasmonic sensing as the top 10 emerging technologies of 2018.[15] Almost every single new plasmonic or photonic structure would be explored to test its sensing ability.[16–29] These works tend to report the sensing performance of their own structure. Some declare that their sensitivity breaks the world record. However, there is still a missing literature on what the world record really is, the gap between the experiments and the theoretical limit, as well as the differences between metal-based plasmonic sensors and dielectric-based photonic sensors. To push plasmonic and photonic sensors into industrial applications, an optical sensing technology map is absolutely necessary. This review aims to cover a wide range of most representative plasmonic and photonic sensors, and place them into a single map. The sensor performances of different structures will be distinctly illustrated. Future researchers could plot the sensing ability of their new sensors into this technology map and gauge their performances in this field. In this review, we focus on optical refractive index (RI) sensors with no fluorescent labeling required. We will utilize two parameters to characterize and compare the performance of optical RI sensors: sensitivity to RI change (denoted by symbol SRI) and figure of merit (in short, FoM). For simplicity, we restrict our discussions to bulk RI change, where the change in RI occurs within the whole sample. There is another case where the RI variation occurs only within a very small volume close to the sensor surface. This surface RI sensitivity is proportional to the bulk RI sensitivity, the ratio of the thickness of the layer within which the surface RI variation occurs, and the penetration depth of the optical mode.[6] The bulk RI sensitivity defines the ratio of the change in sensor output (e.g., resonance angle, intensity, or resonant wavelength) to the bulk RI variations. Here, we limit our discussions to the spectral interrogations and the bulk RI sensitivity SRI is given by[3,5–7,30]
259 citations
TL;DR: This article, which focuses on BP and BP-analogue materials, will present their crystal structure, properties, synthesis methods and applications and the future opportunities and challenges of the materials are included.
Abstract: Black phosphorus (BP), a novel two-dimensional (2D) layered semiconductor material, has attracted tremendous attention since 2014 due to its prominent carrier mobility, thickness-dependent direct bandgap and in-plane anisotropic physical properties. BP has been considered as a promising material for many applications, such as in transistors, photonics, optoelectronics, sensors, batteries and catalysis. However, the development of BP was hampered by its instability under ambient conditions, as well as by the lack of methods to synthesize large-area and high quality 2D nanofilms. Recently, some BP-analogue materials such as binary phosphides (MPx), transition metal phosphorus trichalcogenides (MPX3), and 2D group V (pnictogens) and 2D group VI materials have attracted increasing interest for their unique and stable structures, and excellent physical and chemical properties. This article, which focuses on BP and BP-analogue materials, will present their crystal structure, properties, synthesis methods and applications. Also the similarity and difference between BP and BP-analogue materials will be discussed, and the presentation of the future opportunities and challenges of the materials are included at the end.
220 citations
TL;DR: The mechanism and application of BP in Li-/Na-ion battery anodes, oxygen evolution reaction/hydrogen evolution reaction catalysis, photocatalytic hydrogen production, and selective sensors are summarized.
Abstract: As a new type of 2D semiconductor, black phosphorus (BP) possesses high charge-carrier mobility and theoretical capacity, thickness-dependent bandgap, and anisotropic structure, which has attracted tremendous attention since early 2014. To explore its full application in all aspects, studies based on BP nanostructures are swiftly expanding from the electronic field to energy storage and even biochemistry. The mechanism and application of BP in Li-/Na-ion battery anodes, oxygen evolution reaction/hydrogen evolution reaction catalysis, photocatalytic hydrogen production, and selective sensors are summarized. Based on the solid research on this topic, feasible improvements and constructive suggestions regarding these four fields are put forward.
213 citations
TL;DR: A nonlinear photonic diode that breaks time-reversal symmetry is demonstrated to realize the unidirectional excitation of Kerr nonlinearity, which can be regarded as a significant demonstration of a graphdiyne-based prototypical application in non linear photonics and might suggest an important step toward versatile graphdiyah-based advanced passive photonics devices in the future.
Abstract: Graphdiyne is a new carbon allotrope comprising sp- and sp2 -hybridized carbon atoms arranged in a 2D layered structure. In this contribution, 2D graphdiyne is demonstrated to exhibit a strong light-matter interaction with high stability to achieve a broadband Kerr nonlinear optical response, which is useful for nonreciprocal light propagation in passive photonic diodes. Furthermore, advantage of the unique Kerr nonlinearity of 2D graphdiyne is taken and a nonreciprocal light propagation device is proposed based on the novel similarity comparison method. Graphdiyne has demonstrated a large nonlinear refractive index in the order of ≈10-5 cm2 W-1 , comparing favorably to that of graphene. Based on the strong Kerr nonlinearity of 2D graphdiyne, a nonlinear photonic diode that breaks time-reversal symmetry is demonstrated to realize the unidirectional excitation of Kerr nonlinearity, which can be regarded as a significant demonstration of a graphdiyne-based prototypical application in nonlinear photonics and might suggest an important step toward versatile graphdiyne-based advanced passive photonics devices in the future.
194 citations
References
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TL;DR: In this article, a few-layer black phosphorus crystals with thickness down to a few nanometres are used to construct field effect transistors for nanoelectronic devices. But the performance of these materials is limited.
Abstract: Two-dimensional crystals have emerged as a class of materials that may impact future electronic technologies. Experimentally identifying and characterizing new functional two-dimensional materials is challenging, but also potentially rewarding. Here, we fabricate field-effect transistors based on few-layer black phosphorus crystals with thickness down to a few nanometres. Reliable transistor performance is achieved at room temperature in samples thinner than 7.5 nm, with drain current modulation on the order of 10(5) and well-developed current saturation in the I-V characteristics. The charge-carrier mobility is found to be thickness-dependent, with the highest values up to ∼ 1,000 cm(2) V(-1) s(-1) obtained for a thickness of ∼ 10 nm. Our results demonstrate the potential of black phosphorus thin crystals as a new two-dimensional material for applications in nanoelectronic devices.
6,924 citations
TL;DR: A detailed theoretical investigation of the atomic and electronic structure of few-layer black phosphorus (BP) is presented to predict its electrical and optical properties, finding that the mobilities are hole-dominated, rather high and highly anisotropic.
Abstract: Two-dimensional crystals are emerging materials for nanoelectronics. Development of the field requires candidate systems with both a high carrier mobility and, in contrast to graphene, a sufficiently large electronic bandgap. Here we present a detailed theoretical investigation of the atomic and electronic structure of few-layer black phosphorus (BP) to predict its electrical and optical properties. This system has a direct bandgap, tunable from 1.51 eV for a monolayer to 0.59 eV for a five-layer sample. We predict that the mobilities are hole-dominated, rather high and highly anisotropic. The monolayer is exceptional in having an extremely high hole mobility (of order 10,000 cm(2) V(-1) s(-1)) and anomalous elastic properties which reverse the anisotropy. Light absorption spectra indicate linear dichroism between perpendicular in-plane directions, which allows optical determination of the crystalline orientation and optical activation of the anisotropic transport properties. These results make few-layer BP a promising candidate for future electronics.
3,622 citations
TL;DR: Fundamentals of SPR affinity biosensors are reviewed and recent advances in development and applications of SPR biosensor are discussed.
Abstract: Surface plasmon resonance (SPR) biosensors are optical sensors exploiting special electromagnetic waves—surface plasmon-polaritons—to probe interactions between an analyte in solution and a biomolecular recognition element immobilized on the SPR sensor surface. Major application areas include detection of biological analytes and analysis of biomolecular interactions where SPR biosensors provide benefits of label-free real-time analytical technology. This paper reviews fundamentals of SPR affinity biosensors and discusses recent advances in development and applications of SPR biosensors.
2,123 citations
TL;DR: From numerical calculations and arguments based on the crystal structure of the material, it is shown that the deformation in the direction normal to the plane can be used to change the gap size and induce a semiconductor-metal transition.
Abstract: The band structure of single-layer black phosphorus and the effect of strain are predicted using density functional theory and tight-binding models. Having determined the localized orbital composition of the individual bands from first principles, we use the system symmetry to write down the effective low-energy Hamiltonian at the Γ point. From numerical calculations and arguments based on the crystal structure of the material, we show that the deformation in the direction normal to the plane can be used to change the gap size and induce a semiconductor-metal transition.
1,307 citations
TL;DR: The experimental observation of highly anisotropic, bright excitons with large binding energy in monolayer black phosphorus opens avenues for the future explorations of many-electron physics in this unusual two-dimensional material, but also suggests its promising future in optoelectronic devices.
Abstract: Polarization-resolved photoluminescence measurements reveal the anisotropic character of excitons in monolayer black phosphorus, which are found to have a large binding energy.
1,169 citations