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Journal ArticleDOI

Sensor and Numerical Simulator Evaluation for Porous Medium Desiccation and Rewetting at the Intermediate Laboratory Scale

TL;DR: In this article, an intermediate-scale experiment was conducted to test the response of a series of instruments to desiccation and subsequent rewetting of porous media, including thermistors, thermocouple psychrometers, dual-probe heat pulse sensors, heat dissipation units, and humidity probes.
Abstract: Soil desiccation, in conjunction with surface infiltration control, is considered at the Hanford Site as a potential technology to limit the flux of technetium and other contaminants in the vadose zone to the groundwater. An intermediate-scale experiment was conducted to test the response of a series of instruments to desiccation and subsequent rewetting of porous media. The instruments include thermistors, thermocouple psychrometers, dual-probe heat pulse sensors, heat dissipation units, and humidity probes. The experiment was simulated with the multifluid flow simulator STOMP, using independently obtained hydraulic and thermal porous medium properties. All instrument types used for this experiment were able to indicate when the desiccation front passed a certain location. In most cases the changes were sharp, indicating rapid changes in moisture content, water potential, or humidity. However, a response to the changing conditions was recorded only when the drying front was very close to a sensor. Of the tested instruments, only the heat dissipation unit and humidity probes were able to detect rewetting. The numerical simulation results reasonably match the experimental data, indicating that the simulator captures the pertinent gas flow and transport processes related to desiccation and rewetting and may be useful in the design and analysis of field tests.
Citations
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Journal ArticleDOI
TL;DR: In this paper, Neutron moisture logging, electrical resistivity tomography, and cross-hole ground-penetrating radar approaches were evaluated with respect to their ability to provide effective spatial and temporal monitoring of desiccation during a treatability study conducted in the vadose zone of the USDOE Hanford site in the state of Washington.
Abstract: Soil desiccation was recently field tested as a potential vadose zone remediation technology. Desiccation removes water from the vadose zone and significantly decreases the aqueous-phase permeability of the desiccated zone, thereby decreasing movement of moisture and contaminants. The two- and three-dimensional distribution of moisture content reduction with time provides valuable information for desiccation operations and for determining when treatment goals have been reached. This type of information can be obtained through the use of geophysical methods. Neutron moisture logging, cross-hole electrical resistivity tomography, and cross-hole ground-penetrating radar approaches were evaluated with respect to their ability to provide effective spatial and temporal monitoring of desiccation during a treatability study conducted in the vadose zone of the USDOE Hanford site in the state of Washington.

29 citations


Additional excerpts

  • ...Soil desiccation was investigated as a potential vadose zone remediation technology, including laboratory studies (Ward et al., 2008; Oostrom et al., 2009, 2012a, 2012b; Truex et al., 2011), modeling studies (Ward et al., 2008; Truex et al., 2011), and i eld testing (Truex et al., 2012a, 2012b)…...

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Journal ArticleDOI
TL;DR: In this paper, a vertical coordinate transform was developed to enable a computational domain regular in the vertical direction, enabling the solution of the Richards equation with efficient computations and simpler coding.

24 citations

Journal ArticleDOI
TL;DR: In this paper, desiccation of the vadose zone has the potential to reduce the flux of contaminants to underlying groundwater by removing moisture and decreasing the aqueous-phase permeability of the desiccated zone.
Abstract: Desiccation of the vadose zone has the potential to reduce the flux of contaminants to underlying groundwater by removing moisture and decreasing the aqueous-phase permeability of the desiccated zone. However, data to evaluate implementation of desiccation are needed to enable consideration of desiccation as a potential remedy. Implementation of desiccation was field tested by injecting dry nitrogen gas to a target treatment zone and monitoring the spatial and temporal progress of the drying process. Aqueous waste discharges to disposal cribs approximately 50 years ago distributed water and contaminants, including primarily technetium-99 and nitrate, within the 100-m deep vadose zone at the test site. A field test location was selected adjacent to one of the former disposal cribs. The test was conducted in a contaminated portion of the vadose zone dominated by fine sands with lenses of silt material. Desiccation reduced volumetric moisture content to as low as 0.01. The lateral and vertical distribution of drying from the injection well was influenced by the subsurface heterogeneity. However, over time, desiccation occurred in the initially wetter, lower permeability lenses.

22 citations


Cites background or methods from "Sensor and Numerical Simulator Eval..."

  • ...Hydraulic properties of Hanford lysimeter and 100-mesh sand (at er Oostrom et al. 2012a)....

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  • ...…transport dominates, have been discussed by, e.g., Fayer and Simmons (1995), Morel-Seytoux and Nimmo (1999), and Webb (2000). h e relatively simple extension theory by Webb (2000) has been used successfully by Oostrom et al. (2012a, 2012b) to simulate desiccation in intermediate-scale l ow cells....

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  • ...Evaporation can remove pore water and may result in very low moisture contents and decreased water relative permeability in the desiccated zone (Ward et al., 2008; Oostrom et al., 2009, 2012a,2012b; Truex et al., 2011)....

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  • ...Laboratory and modeling studies (Ward et al., 2008; Oostrom et al., 2009, 2012a,2012b; Truex et al., 2011) suggest that the overall performance of desiccation in limiting water and contaminant l ux to the groundwater is a function of the i nal moisture content, contaminant concentration, sediment…...

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  • ...Because the transport of dry gas is directly related to the permeability of the porous medium, higher permeability zones in soil columns and l ow cells packed with heterogeneous media dried more quickly than lower permeability zones (Oostrom et al., 2009, 2012a,2012b)....

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Journal ArticleDOI
TL;DR: In this paper, a multi-year test of the Prototype Hanford Barrier (PHB) has yielded in situ soil water content and pressure data for a nine-year period.
Abstract: Engineered surface barriers are used to isolate underlying contaminants from water, plants, animals, and humans. To understand the flow processes within a barrier and the barrier’s ability to store and release water, the field hydraulic properties of the barrier need to be known. In situ measurement of soil hydraulic properties and their variation over time is challenging because most measurement methods are destructive. A multiyear test of the Prototype Hanford Barrier (PHB) has yielded in situ soil water content and pressure data for a nine-year period. The upper 2 m layer of the PHB is a silt loam. Within this layer, water content and water pressure were monitored at multiple depths at 12 water balance stations using a neutron probe and heat dissipation units. Valid monitoring data from 1995 to 2003 for 4 depths at 12 monitoring stations were used to determine the field water retention of the silt loam layer. The data covered a wide range of wetness, from near saturation to the permanent wilt point, and each retention curve contained 51 to 96 data points. The data were described well with the commonly used van Genuchten water retention model. It was found that the spatial variation of themore » saturated and residual water content and the pore size distribution parameter were relatively small, while that of the van Genuchten alpha was relatively large. The effects of spatial variability of the retention properties appeared to be larger than the combined effects of added 15% w/w pea gravel and plant roots on the properties. Neither of the primary hydrological processes nor time had a detectible effect on the water retention of the silt loam barrier.« less

12 citations


Cites background from "Sensor and Numerical Simulator Eval..."

  • ...Oostrom et al. (2012) measured h as low as about −900 m in a laboratory experiment....

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Journal ArticleDOI
TL;DR: In this paper, a series of four intermediate-scale flow cell experiments was conducted in homogeneous and simple layered heterogeneous porous medium systems to investigate the effects of heterogeneity on desiccation of unsaturated porous media.
Abstract: Soil desiccation (drying), involving water evaporation induced by dry gas injection, is a potentially robust vadose zone remediation process to limit contaminant transport through the vadose zone. A series of four intermediate-scale flow cell experiments was conducted in homogeneous and simple layered heterogeneous porous medium systems to investigate the effects of heterogeneity on desiccation of unsaturated porous media. The permeability ratios of porous medium layers ranged from about five to almost two orders of magnitude. The insulated flow cell was equipped with twenty humidity and temperature sensors and a dual-energy gamma system was used to determine water saturations at various times. The multiphase code STOMP was used to simulate the desiccation process. Results show that injected dry gas flowed predominantly in the higher permeability layer and delayed water removal from the lower permeability material. For the configurations tested, water vapor diffusion from the lower to the higher permeability zone was considerable over the duration of the experiments, resulting in much larger relative humidity values of the outgoing air than based on permeability ratios alone. Acceptable numerical matches with the experimental data were obtained when an extension of the saturation-capillary pressure relation below the residual water saturation was used. The agreementsmore » between numerical and experimental results suggest that the correct physics are implemented in the simulator and that the thermal and hydraulic properties of the porous media, flow cell wall and insulation materials were properly represented.« less

9 citations


Cites background or methods or result from "Sensor and Numerical Simulator Eval..."

  • ...…sand and only a small fraction of the total water l ux is advectively transported through this sand. h e internal temperature and relative humidity responses during desiccation are consistent with observations by Oostrom et al. (2009, 2012) in other intermediate-scale l ow cell experiments....

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  • ...As also shown by Oostrom et al. (2012) for desiccation of a heterogeneous system in a larger Fig....

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  • ...…equal to the irreducible water saturations obtained by Schroth et al. (1996; Table 2) to minimize water movement due to redistribution for the duration of the desiccation experiments (30 d). h e validity of this assumption has been demonstrated using 1-m-long columns by Oostrom et al. (2012)....

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  • ...A main advantage of this method is that it does not require rei tting of the capillary pressure–saturation experimental data obtained for saturations larger than irreducible. h e method has been applied successfully to simulate l ow cell experiments by Oostrom et al. (2012)....

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  • ...10. h e temperature minima for the reported experiments are larger than observed in Oostrom et al. (2009, 2012) due to use of smaller gas injection rates....

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References
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Journal ArticleDOI
TL;DR: In this article, the authors describe the construction and performance of a device for measuring specific heat using the line source method, which was constructed from two hypodermic needles, 0.813 mm in diam and 28 mm long, and spaced 6 mm apart.
Abstract: Temperature rise, measured a short distance from a line heat source, can be used to determine the volumetric specific heat of soil and other materials. Volumetric specific heat is linearly related to the inverse of the temperature rise. The purpose of this note is to describe the construction and performance of a device for measuring specific heat using the line source method. The device was constructed from two hypodermic needles, 0.813 mm in diam. and 28 mm long, and spaced 6 mm apart. One needle contained a heater and the other a thermocouple. The temperature rise from heat pulses given to the heater were measured with the thermocouple. The coefficientof variation (CV) of specific heat on replicate samples was around 1%. Since water is the main variable component of the specific heat in nonswelling soil, changes in water content might be resolved to 0.01 or better in nonswelling soils

414 citations


"Sensor and Numerical Simulator Eval..." refers methods in this paper

  • ...Dual-Probe Heat Pulse Sensors DPHP Specii c Heat Sensors (East 30 Sensors, Pullman, WA) were used to measure water content. h e sensor type, described in detail by Campbell et al. (1991), consists of two parallel hypodermic needles separated by a i xed distance....

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Journal ArticleDOI
TL;DR: In this article, the authors present a comprehensive set of hydrologically relevant properties for a unique set of commercially available silica sands, including high sphericity, high batch-to-batch consistency, Miller-similarity, and availability in large quantities.
Abstract: The use of well-characterized porous media can simplify and improve the efficiency of laboratory subsurface flow and transport experiments. The objective of this study was to present a comprehensive set of hydrologically relevant properties for a unique set of commercially available silica sands. Features of sands selected for characterization included high sphericity, high batch-to-batch consistency, Miller-similarity, and availability in large quantities. Samples of four different sand grades (12/20, 20/30, 30/40, and 40/50 sieve sizes) were characterized for physical properties, chemical composition, water retention, three-phase air-non-aqueous-phase liquid (NAPL)-water saturation-pressure relationships for water and a model NAPL, Soltrol 220, and saturated and unsaturated hydraulic conductivity. Properties common to all sand grades included high chemical purity and low organic matter content. Water retention curves featured well-defined air entry pressures and the Miller-similarity of the media was demonstrated for both static and dynamic properties. During water retention measurements, we determined that the common assumption of a uniform vertical water content distribution in retention cells can result in significant errors in uniform porous media. A numerical correction procedure was developed and successfully applied to correct fitted water retention curve parameters, illustrating that potential errors of up to 70% in volumetric water content are made without proper analysis. The characterization data for the four sand grades presented here should facilitate their use in a wide range of laboratory flow and transport studies.

287 citations


"Sensor and Numerical Simulator Eval..." refers methods in this paper

  • ...…Devices, Inc., Pullman, WA). h e thermal properties of the polycarbonate were provided by the manufacturer (McMaster-Carr, Robbinsville, NJ). h e hydraulic properties of the sands and the Hanford sediment were obtained using methods described by Wietsma et al. (2009) and Schroth et al. (1996)....

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ReportDOI
09 Jun 2006
TL;DR: This guide describes the general use, input file formatting, compilation and execution of the STOMP (Subsurface Transport Over Multiple Phases) simulator, a scientific tool for analyzing single and multiple phase subsurface flow and transport.
Abstract: This guide describes the general use, input file formatting, compilation and execution of the STOMP (Subsurface Transport Over Multiple Phases) simulator, a scientific tool for analyzing single and multiple phase subsurface flow and transport. A description of the simulator’s governing equations, constitutive functions and numerical solution algorithms are provided in a companion theory guide. In writing these guides for the STOMP simulator, the authors have assumed that the reader comprehends concepts and theories associated with multiple-phase hydrology, heat transfer, thermodynamics, radioactive chain decay, and relative permeability-saturation-capillary pressure constitutive relations. The authors further assume that the reader is familiar with the computing environment on which they plan to compile and execute the STOMP simulator. Source codes for the sequential versions of the simulator are available in pure FORTRAN 77 or mixed FORTRAN 77/90 forms. The pure FORTRAN 77 source code form requires a parameters file to define the memory requirements for the array elements. The mixed FORTRAN 77/90 form of the source code uses dynamic memory allocation to define memory requirements, based on a FORTRAN 90 preprocessor STEP, that reads the input files. The simulator utilizes a variable source code configuration, which allows the execution memory and speed to be tailored to the problem specifics, and essentially requires that the source code be assembled and compiled through a software maintenance utility. The memory requirements for executing the simulator are dependent on the complexity of physical system to be modeled and the size and dimensionality of the computational domain. Likewise execution speed depends on the problem complexity, size and dimensionality of the computational domain, and computer performance. Selected operational modes of the STOMP simulator are available for scalable execution on multiple processor (i.e., parallel) computers. These versions of the simulator are written in pure FORTRAN 90 with imbedded directives that are interpreted by a FORTRAN preprocessor. Without the preprocessor, the scalable version of the simulator can be executed sequentially on a single processor computer. The scalable versions of the STOMP modes carry the “-Sc” designator on the operational mode name. For example, STOMP-WCS-Sc is the scalable version of the STOMP-WCS (Water-CO2-Salt) mode. A separate mode containing an evaporation model as a boundary condition on the upper surface of the computation domain has also been included. This mode, STOMP-WAE-B (Water-Air-Energy-Barriers) can be viewed as an extension of the STOMP-WAE (Water-Air-Energy) mode. Details of this particular mode are outlined by Ward et al. (2005)(a). STOMP V4.0 includes the reactive transport module ECKEChem (Equilibrium-Conservation-Kinetic Equation Chemistry) for the STOMP-W (Water) and STOMP-WCS (Water-CO2-Salt) modes. For this particular module, the “-R” designator is included in the operational mode name (e.g., STOMP-W-R, STOMP-WCS-R-Sc). This mode is described in detail by White and McGrail (2005)(b). For all operational modes and processor implementations, the memory requirements for executing the simulator are dependent on the complexity of physical system to be modeled and the size and dimensionality of the computational domain. Likewise execution speed depends on the problem complexity, size and dimensionality of the computational domain, and computer performance. Additional information about the simulator can be found on the STOMP webpage: http://stomp.pnl.gov. The website includes an introductory short course with problems ranging from simple one-dimensional saturated flow to complex multiphase system computations.

229 citations


"Sensor and Numerical Simulator Eval..." refers background or methods in this paper

  • ...…objectives were to (i) evaluate the utility of candidate sensors to monitor during the desiccation and rewetting processes and (ii) test and verify the Water-Air-Energy mode of the STOMP (White and Oostrom, 2006) simulator using mostly independently obtained l uid and hydraulic property values....

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  • ...h e physical experiment was simulated with the water–air–energy mode of the STOMP simulator (Ward et al., 2005; White and Oostrom, 2006; Oostrom et al., 2009), solving the water and air mass balance equations and the energy conservation equation. h e partial dif erential equations for l ow and…...

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  • ...h e physical experiment was simulated with the water–air–energy mode of the STOMP simulator (Ward et al., 2005; White and Oostrom, 2006; Oostrom et al., 2009), solving the water and air mass balance equations and the energy conservation equation. h e partial dif erential equations for l ow and transport are discretized following the integrated-volume i nite dif erence method by integrating over a control volume. h e inclusion of the wall in the model and the coni guration of the heterogeneous experiments required the use of a three-dimensional model....

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  • ...This paper shows which sensors successfully measured drying and we ng responses, and reports on the STOMP performance....

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  • ...So far, only a few laboratory or i eld An intermediate-scale experiment involving desicca on and rewe ng of a porous medium was conducted to evaluate the response of several soil moisture sensors and the per- formance of the multiphase flow simulator STOMP....

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01 Oct 1997
TL;DR: STOMP as mentioned in this paper is a computer model designed to be a general purpose tool for simulating subsurface flow and transport, that complements other analytical capabilities developed by Pacific Northwest National Laboratory`s Hydrology Group.
Abstract: STOMP is a computer model designed to be a general purpose tool for simulating subsurface flow and transport, that complements other analytical capabilities developed by Pacific Northwest National Laboratory`s Hydrology Group. The simulator was specifically designed to provide scientists and engineers from various disciplines with multidimensional analysis capabilities for modeling subsurface flow and transport phenomena. STOMP`s target capabilities were guided by proposed or applied remediation activities at sites contaminated with volatile organic compounds and/or radioactive material. Developed with the support of the U.S. Department of Energy, Office of Environmental Restoration and Waste Management, the simulator`s modeling capabilities address a variety of subsurface environments, including nonisothermal conditions, fractured media, multiple-phase systems, non-wetting fluid entrapment, soil freezing conditions, nonaqueous phase liquids, first-order chemical reactions, radioactive decay, solute transport, dense brines, nonequilibrium dissolution, and surfactant enhanced dissolution and mobilization of organics.

212 citations


"Sensor and Numerical Simulator Eval..." refers methods in this paper

  • ...h e physical experiment was simulated with the water–air–energy mode of the STOMP simulator (Ward et al., 2005; White and Oostrom, 2006; Oostrom et al., 2009), solving the water and air mass balance equations and the energy conservation equation. h e partial dif erential equations for l ow and…...

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  • ...Numerical Simula ons h e physical experiment was simulated with the water–air–energy mode of the STOMP simulator (Ward et al., 2005; White and Oostrom, 2006; Oostrom et al., 2009), solving the water and air mass balance equations and the energy conservation equation....

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Journal ArticleDOI

144 citations


"Sensor and Numerical Simulator Eval..." refers methods in this paper

  • ...Because of the swelling properties of bentonite, its hydraulic properties were not directly measured except for the air permeability of the dry material. h e laboratory method used was based on designs by Corey (1957) and Springer et al. (1998)....

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  • ...h e laboratory method used was based on designs by Corey (1957) and Springer et al. (1998)....

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  • ...h e laboratory method used was based on designs by Corey (1957) and Springer et al....

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