Journal ArticleDOI
Separation of hydrocarbons with a microporous metal-organic framework
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This article is published in Angewandte Chemie.The article was published on 2006-01-16. It has received 712 citations till now. The article focuses on the topics: Microporous material & Metal-organic framework.read more
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Selective gas adsorption and separation in metal–organic frameworks
TL;DR: This critical review starts with a brief introduction to gas separation and purification based on selective adsorption, followed by a review of gas selective adsorbents in rigid and flexible MOFs, and primary relationships between adsorptive properties and framework features are analyzed.
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Metal–Organic Frameworks for Separations
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Hybrid porous solids: past, present, future
TL;DR: The state-of-the-art on hybrid porous solids, their advantages, their new routes of synthesis, the structural concepts useful for their 'design', aiming at reaching very large pores are presented.
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Industrial applications of metal–organic frameworks
TL;DR: An overview of the potential applications of MOFs in the chemical industry is presented and the synthesis and characterization of the materials are briefly discussed from the industrial perspective.
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Metal-organic framework as a template for porous carbon synthesis
TL;DR: Porous carbon was synthesized by heating the precursor FA within the pores of MOF-5 to display a high specific surface area and important hydrogen uptake and excellent electrochemical properties as an electrode material for electrochemical double-layered capacitor (EDLC).
References
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Journal ArticleDOI
Functional porous coordination polymers.
TL;DR: The aim is to present the state of the art chemistry and physics of and in the micropores of porous coordination polymers, and the next generation of porous functions based on dynamic crystal transformations caused by guest molecules or physical stimuli.
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Hydrogen Storage in Microporous Metal-Organic Frameworks
Nathaniel L. Rosi,Juergen Eckert,Mohamed Eddaoudi,David T. Vodak,Jaheon Kim,Michael O'Keeffe,Omar M. Yaghi +6 more
TL;DR: Inelastic neutron scattering spectroscopy of the rotational transitions of the adsorbed hydrogen molecules indicates the presence of two well-defined binding sites (termed I and II), which are associated with hydrogen binding to zinc and the BDC linker, respectively.
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Interpenetrating Nets: Ordered, Periodic Entanglement.
TL;DR: A detailed and systematic examination of many interpenetrating nets of this kind is made, and implications for crystal engineering are discussed.
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Strategies for hydrogen storage in metal--organic frameworks.
TL;DR: A discussion of several strategies aimed at improving hydrogen uptake in metal-organic frameworks, including the optimization of pore size and adsorption energy by linker modification, impregnation, catenation, and the inclusion of open metal sites and lighter metals.
Journal ArticleDOI
Highly controlled acetylene accommodation in a metal–organic microporous material
Ryotaro Matsuda,Ryo Kitaura,Ryo Kitaura,Susumu Kitagawa,Yoshiki Kubota,Rodion V. Belosludov,Tatsuo C. Kobayashi,Hirotoshi Sakamoto,Takashi Chiba,Masaki Takata,Yoshiyuki Kawazoe,Yoshimi Mita +11 more
TL;DR: High levels of selective sorption of acetylene molecules as compared to a very similar molecule, carbon dioxide, onto the functionalized surface of a MOM are reported.