Journal ArticleDOI
Silylmethyl radical cyclization: new stereoselective method for 1,3-diol synthesis from allylic alcohols
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La cyclisation des (alcene-2yl [bromomethyl dimethyl] silyl) ethers a l'aide du tributylstannane, suivie d'une reaction d'oxydation, conduit a des methyl-2 alcanediols-1,3Abstract:
La cyclisation des (alcene-2yl [bromomethyl dimethyl] silyl) ethers a l'aide du tributylstannane, suivie d'une reaction d'oxydation, conduit a des methyl-2 alcanediols-1,3read more
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Journal ArticleDOI
The Diels--Alder reaction in total synthesis.
TL;DR: The Diels-Alder reaction has both enabled and shaped the art and science of total synthesis over the last few decades to an extent which has yet to be eclipsed by any other transformation in the current synthetic repertoire as mentioned in this paper.
Journal ArticleDOI
Stereochemical Control in Organic-Synthesis Using Silicon-Containing Compounds
Journal ArticleDOI
Selective Preparation of Complex Polycyclic Molecules from Acyclic Precursors via Radical Mediated- or Transition Metal-Catalyzed Cascade Reactions.
Journal ArticleDOI
Die Diels‐Alder‐Reaktion in der Totalsynthese
TL;DR: In den letzten Jahrzehnten hat wohl keine andere Reaktion das Forschungsgebiet der Totalsynthese mehr gepragt als die Diels-Alder-Reaktion, oftmals als entscheidendes Element einer eleganten Kaskadenreaktion zur Herstellung komplexer Molekulstrukturen.
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