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Size dependence of Young's modulus in ZnO nanowires.

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TLDR
A core-shell composite NW model in terms of the surface stiffening effect correlated with significant bond length contractions occurred near the {1010} free surfaces is proposed to explore the origin of the size dependence, and it is possible to estimate the size-related elastic properties of GaN nanotubes and relative nanostructures by using this model.
Abstract
We report a size dependence of Young's modulus in [0001] oriented ZnO nanowires (NWs) with diameters ranging from 17 to 550 nm for the first time. The measured modulus for NWs with diameters smaller than about 120 nm is increasing dramatically with the decreasing diameters, and is significantly higher than that of the larger ones whose modulus tends to that of bulk ZnO. A core-shell composite NW model in terms of the surface stiffening effect correlated with significant bond length contractions occurred near the {1010} free surfaces (which extend several layers deep into the bulk and fade off slowly) is proposed to explore the origin of the size dependence, and present experimental result is well explained. Furthermore, it is possible to estimate the size-related elastic properties of GaN nanotubes and relative nanostructures by using this model.

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Citations
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Growth of nanowires

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Electrostatic potential in a bent piezoelectric nanowire. The fundamental theory of nanogenerator and nanopiezotronics

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Surface Effect on the Elastic Behavior of Static Bending Nanowires

TL;DR: In this paper, the dependence of the surface effect on the overall Young's modulus of nanowires for three different boundary conditions: cantilever, simply supported, and fixed-fixed.
References
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Journal ArticleDOI

Nanobeam mechanics: Elasticity, strength, and toughness of nanorods and nanotubes

TL;DR: In this paper, the Young's modulus, strength, and toughness of nanostructures are evaluated using an atomic force microscopy (AFM) approach. And the results showed that the strength of the SiC NRs were substantially greater than those found previously for larger SiC structures, and they approach theoretical values.
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Electrostatic deflections and electromechanical resonances of carbon nanotubes

TL;DR: The methods developed here have been applied to a nanobalance for nanoscopic particles and also to a Kelvin probe based on nanotubes, which indicates a crossover from a uniform elastic mode to an elastic mode that involves wavelike distortions in the nanotube.
Journal ArticleDOI

Size-dependent elastic properties of nanosized structural elements

TL;DR: In this article, a simple model is constructed to predict the size dependence of the effective stiffness of the structural element, and the important length scale in the problem is identified to be the ratio of the surface elastic modulus to the elastic modulation of the bulk.
Journal ArticleDOI

Mechanical properties of ultrahigh-strength gold nanowires

TL;DR: It is found that for Au nanowires, Young's modulus is essentially independent of diameter, whereas the yield strength is largest for the smallest diameter wires, with strengths up to 100 times that of bulk materials, and substantially larger than that reported for bulk nanocrystalline metals.
Journal ArticleDOI

Surface tension effect on the mechanical properties of nanomaterials measured by atomic force microscopy

TL;DR: In this paper, the effect of reduced size on the elastic properties measured on silver and lead nanowires and on polypyrrole nanotubes with an outer diameter ranging between 30 and 250 nm is discussed.
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