Journal ArticleDOI
SO2F2-mediated oxidation of primary and tertiary amines with 30% aqueous H2O2 solution
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TLDR
In this article, a highly efficient and selective oxidation of primary and tertiary amines employing SO2F2/H2O2/base system was described, where primary benzylamines were transformed into nitriles and secondary benzyamines were rearranged to amides.About:
This article is published in Tetrahedron Letters.The article was published on 2021-11-09. It has received 3 citations till now. The article focuses on the topics: Tertiary amine.read more
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Copper nanoparticles on graphene support: An efficient photocatalyst for coupling of nitroaromatics in visible light
TL;DR: In this article, an efficient photocatalysts of copper nanoparticles on graphene support are successfully developed for controllably catalyzing the coupling reactions of aromatic nitro compounds to the corresponding azoxy or azo compounds under visible-light irradiation.
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Selective Deuteration of Heterocycle N -Oxides via Iridium-Catalysed Hydrogen Isotope Exchange
TL;DR: In this article , an iridium(I) N-heterocyclic carbene/phosphine complex has been applied to the C-H activation and hydrogen isotope exchange of quinoline N-oxides.
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Oxidation of Sulfides with SO2F2/H2O2/Base
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Nitrile-Containing Pharmaceuticals: Efficacious Roles of the Nitrile Pharmacophore
TL;DR: This research presents a novel, scalable, and scalable approaches that can be applied to the rapidly changing and rapidly changing environment of drug discovery and development.
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5-Substituted-1H-tetrazoles as carboxylic acid isosteres: medicinal chemistry and synthetic methods
TL;DR: A survey of representative literature procedures for the preparation of 5-substituted-1H-tetrazoles, focusing on preparations from aryl and alkyl nitriles, is presented in sections by generalized synthetic methods.
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Sulfur(VI) Fluoride Exchange (SuFEx): Another Good Reaction for Click Chemistry
TL;DR: It is shown that proton or silicon centers can activate the exchange of S�F bonds for SO bonds to make functional products, and that the sulfate connector is surprisingly stable toward hydrolysis.
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Designer magnets containing cyanides and nitriles.
Joel S. Miller,Jamie L. Manson +1 more
TL;DR: Three-dimensional network solids exhibiting magnetic ordering have been made from several first-row metal ions and bridging unsaturated cyanide, tricyanomethanide, and/or dicyanamide ligands, which possess several different structural motifs, and the shorter the bridge, the stronger the interaction.