Solar Synthesis: Prospects in Visible Light Photocatalysis
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"Solar Synthesis: Prospects in Visib..." refers background in this paper
...This development has been inspired in large part by the recognition that the same transition metal complexes that have been so productively used to convert sunlight to electrochemical potential can also be used to catalyze useful and unique organic reactions that are initiated by visible light irradiation (8, 9)....
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...Several recent reviews have described both mechanisms in detail; however, in either scenario, the amines have generally been sacrificial or catalytic co-reductants in photoredox processes that are not themselves incorporated into the synthetic target (8, 35)....
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"Solar Synthesis: Prospects in Visib..." refers background in this paper
...This complex exhibits a strong, broad absorbance in the visible range that results in the production of a long-lived excited state (12, 13)....
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...(A) Ruthenium and iridium complexes, such as 1 to 3, readily absorb visible light and can mediate numerous photochemical transformations (12, 13)....
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...(A) Visible light– induced energy-transfer sensitization involves coupling the generation of an electronically excited organic substrate to the relaxation of a photoexcited transition metal chromophore (12)....
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