Solid state reactions in the potassium iodate and molybdenum(VI) oxide system
TL;DR: In this paper, the reaction between potassium iodate and molybdenum(VI) oxide in mixtures of different mole ratios has been investigated employing TG and DTA techniques in static air atmosphere.
Abstract: The reaction between potassium iodate and molybdenum(VI) oxide in mixtures of different mole ratios has been investigated employing TG and DTA techniques in static air atmosphere. The products are characterised by infrared spectroscopy, chemical analysis and X-ray diffraction studies. The studies indicate the formation of mono-, di-, tri- and tetramolybdates of potassium from mixtures with 2∶1, 1∶1, 2∶3 and 1∶2 mole ratios of KlO3∶MoO3. The kinetics of the reaction was followed and the energy of activation values were computed.
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Citations
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Cites background or methods from "Solid state reactions in the potass..."
...Suba and Udupa [32] studied the reaction between potassium iodate and molybdenum (VI) oxide in mixtures of different mole ratios employing TG, derivative thermogravimetry (DTG) and DTA techniques in static air atmosphere; followed the kinetics of the reaction and computed the values of E....
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...Even though a vast number of publications are available in the literature on KIO3 [21–36], studies on the thermal decomposition and kinetics are not available....
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24 citations
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Cites background from "Solid state reactions in the potass..."
...The rate constant k(T) and the activation energy (E) are related by Arrhenius equation [28]....
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References
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