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Journal ArticleDOI

Sorption of bisphenol A, 17α-ethinyl estradiol and phenanthrene on thermally and hydrothermally produced biochars

TL;DR: It is demonstrated that hydrothermal biochars could adsorb a wider spectrum of both polar and nonpolar organic contaminants than thermally produced biochar, suggesting that hydroThermal biochar derived from poultry and animal waste is a potential sorbent for agricultural and environmental applications.
About: This article is published in Bioresource Technology.The article was published on 2011-05-01. It has received 328 citations till now. The article focuses on the topics: Sorption.
Citations
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Journal ArticleDOI
TL;DR: A review of recent applications of biochars, produced from biomass pyrolysis (slow and fast), in water and wastewater treatment, and a few recommendations for further research have been made in the area of biochar development for application to water filtration.

1,738 citations


Cites background or methods from "Sorption of bisphenol A, 17α-ethiny..."

  • ...Phen adsorption on chars occurs by extensive p–p interactions (Sun et al., 2011)....

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  • ...…(T-PL) and wheat straw (T-WS) biochars, produced at 400 C over 120–420 min and hydrothermal poultry litter and swine solids chars at 250 C under autogenic pressures for 20 h were made to remove phenanthrene (Phen), bisphenol A (BPA), and 17a-ethinyl esteradiol (EE2) from water (Sun et al., 2011)....

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  • ...Thermal biochars were more hydrophobic than hydrothermal chars (Sun et al., 2011) and exhibited mostly aromatic (sp2) carbons with small amounts of alkyl (sp3) carbons....

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Journal ArticleDOI
TL;DR: In this article, the authors provide an overview on recently developed carbon material technology synthesised from the hydrothermal carbonisation (HTC) approach, with a particular focus on the carbon formation mechanism, perspectives on large scale production, nanostructuring, functionalisation and applications.
Abstract: This perspective review paper provides an overview on recently developed carbon material technology synthesised from the hydrothermal carbonisation (HTC) approach, with a particular focus on the carbon formation mechanism, perspectives on large scale production, nanostructuring, functionalisation and applications. Perceptions on how this technology will be developed especially with regard to application fields where the use of HTC-derived materials could be extended will also be introduced and discussed.

759 citations

Journal ArticleDOI
TL;DR: In this paper, the effect of H2O2 treatment on hydrothermally produced biochar (hydrochar) from peanut hull to remove aqueous heavy metals was examined.

592 citations

Journal ArticleDOI
TL;DR: In this paper, the chemical and structural properties of cellulose, lignin, d-xylose, wood meal, and phenolic hydrochars were investigated, and the carbonization mechanism was proposed, and furfural was found to be an important intermediate product during d-Xylose hydrochar production.
Abstract: Hydrothermal carbonization of cellulose, lignin, d-xylose (substitute for hemicellulose), and wood meal (WM) was experimentally conducted between 225 and 265 °C, and the chemical and structural properties of the hydrochars were investigated. The hydrochar yield is between 45 and 60%, and the yield trend of the feedstock is lignin > WM > cellulose > d-xylose. The hydrochars seem stable below 300 °C, and aromatic structure is formed in all of these hydrochars. The C content, C recovery, energy recovery, ratio of C/O, and ratio of C/H in all of these hydrochars are among 63–75%, 80–87%, 78–89%, 2.3–4.1, and 12–15, respectively. The higher heating value (HHV) of the hydrochars is among 24–30 MJ/kg, with an increase of 45–91% compared with the corresponding feedstock. The carbonization mechanism is proposed, and furfural is found to be an important intermediate product during d-xylose hydrochar production, while lignin hydrothermal carbonization products are made of polyaromatic hydrochar and phenolic hydrocha...

548 citations

Journal ArticleDOI
TL;DR: This review provides a critical review of current research updates related to the pollutants interaction with surface functional groups of biochars and the effect of the parameters variability on biochar attributes pertinent to specific pollutants removal, involved mechanisms, and competence for these removals.

497 citations


Cites background from "Sorption of bisphenol A, 17α-ethiny..."

  • ...…Teixido et al., 2011; Xu et al., 2012; Zheng et al., 2010), and a series of inorganic contaminants (e.g., heavy metals, ammonia, nitrate, phosphate, sulfide etc.) from aqueous, gaseous and/or solid phases (Ahmad et al., 2014; Sun et al., 2011; Jung et al., 2015; Xu et al., 2011; Yu et al., 2009)....

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  • ...On the contrary, removal of polar insecticide and herbicide compounds (e.g., 1-naphthol, norflurazon and fluridone) takes place due to polar specific interactions, e.g., H-bonding between pollutants and the functional groups of biochar produced at <350 o C (Chen and Chen, 2009; Sun et al., 2011)....

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References
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ReportDOI
15 Dec 2005
TL;DR: The U.S. Department of Energy and the United States Department of Agriculture have both strongly committed to expanding the role of biomass as an energy source as mentioned in this paper, and they support biomass fuels and products as a way to reduce the need for oil and gas imports; to support the growth of agriculture, forestry, and rural economies; and to foster major new domestic industries making a variety of fuels, chemicals, and other products.
Abstract: The U.S. Department of Energy (DOE) and the U.S. Department of Agriculture (USDA) are both strongly committed to expanding the role of biomass as an energy source. In particular, they support biomass fuels and products as a way to reduce the need for oil and gas imports; to support the growth of agriculture, forestry, and rural economies; and to foster major new domestic industries--biorefineries--making a variety of fuels, chemicals, and other products. As part of this effort, the Biomass R&D Technical Advisory Committee, a panel established by the Congress to guide the future direction of federally funded biomass R&D, envisioned a 30 percent replacement of the current U.S. petroleum consumption with biofuels by 2030. Biomass--all plant and plant-derived materials including animal manure, not just starch, sugar, oil crops already used for food and energy--has great potential to provide renewable energy for America's future. Biomass recently surpassed hydropower as the largest domestic source of renewable energy and currently provides over 3 percent of the total energy consumption in the United States. In addition to the many benefits common to renewable energy, biomass is particularly attractive because it is the only current renewable source of liquid transportation fuel. This, of course, makes it invaluable in reducing oil imports--one of our most pressing energy needs. A key question, however, is how large a role could biomass play in responding to the nation's energy demands. Assuming that economic and financial policies and advances in conversion technologies make biomass fuels and products more economically viable, could the biorefinery industry be large enough to have a significant impact on energy supply and oil imports? Any and all contributions are certainly needed, but would the biomass potential be sufficiently large to justify the necessary capital replacements in the fuels and automobile sectors? The purpose of this report is to determine whether the land resources of the United States are capable of producing a sustainable supply of biomass sufficient to displace 30 percent or more of the country's present petroleum consumption--the goal set by the Advisory Committee in their vision for biomass technologies. Accomplishing this goal would require approximately 1 billion dry tons of biomass feedstock per year.

2,637 citations

Journal ArticleDOI
TL;DR: The application of bio-char (charcoal or biomass-derived black carbon (C)) to soil is pro- posed as a novel approach to establish a significant, long-term, sink for atmospheric carbon dioxide in terrestrial ecosystems.
Abstract: The application of bio-char (charcoal or biomass-derived black carbon (C)) to soil is pro- posed as a novel approach to establish a significant, long-term, sink for atmospheric carbon dioxide in terrestrial ecosystems. Apart from positive effects in both reducing emissions and increasing the sequestration of greenhouse gases, the production of bio-char and its application to soil will deliver im- mediate benefits through improved soil fertility and increased crop production. Conversion of biomass C to bio-char C leads to sequestration of about 50% of the initial C compared to the low amounts retained after burning (3%) and biological decomposition (<10-20% after 5-10 years), therefore yielding more stable soil C than burning or direct land application of biomass. This efficiency of C conversion of biomass to bio-char is highly dependent on the type of feedstock, but is not significantly affected by the pyrolysis temperature (within 350-500 ◦ C common for pyrolysis). Existing slash-and- burn systems cause significant degradation of soil and release of greenhouse gases and opportunies may exist to enhance this system by conversion to slash-and-char systems. Our global analysis revealed that up to 12% of the total anthropogenic C emissions by land use change (0.21 Pg C) can be off-set annually in soil, if slash-and-burn is replaced by slash-and-char. Agricultural and forestry wastes such as forest residues, mill residues, field crop residues, or urban wastes add a conservatively estimated 0.16 Pg C yr −1 . Biofuel production using modern biomass can produce a bio-char by-product through pyrolysis which results in 30.6 kg C sequestration for each GJ of energy produced. Using published projections of the use of renewable fuels in the year 2100, bio-char sequestration could amount to 5.5-9.5 Pg C yr −1 if this demand for energy was met through pyrolysis, which would exceed current emissions from fossil fuels (5.4 Pg C yr −1 ). Bio-char soil management systems can deliver tradable C emissions reduction, and C sequestered is easily accountable, and verifiable.

2,553 citations

Journal ArticleDOI
TL;DR: In this paper, the authors reviewed the available information about the physical and chemical properties of charcoal as affected by different combustion procedures, and the effects of its application in agricultural fields on nutrient retention and crop production.
Abstract: Rapid turnover of organic matter leads to a low efficiency of organic fertilizers applied to increase and sequester C in soils of the humid tropics. Charcoal was reported to be responsible for high soil organic matter contents and soil fertility of anthropogenic soils (Terra Preta) found in central Amazonia. Therefore, we reviewed the available information about the physical and chemical properties of charcoal as affected by different combustion procedures, and the effects of its application in agricultural fields on nutrient retention and crop production. Higher nutrient retention and nutrient availability were found after charcoal additions to soil, related to higher exchange capacity, surface area and direct nutrient additions. Higher charring temperatures generally improved exchange properties and surface area of the charcoal. Additionally, charcoal is relatively recalcitrant and can therefore be used as a long-term sink for atmospheric CO2. Several aspects of a charcoal management system remain unclear, such as the role of microorganisms in oxidizing charcoal surfaces and releasing nutrients and the possibilities to improve charcoal properties during production under field conditions. Several research needs were identified, such as field testing of charcoal production in tropical agroecosystems, the investigation of surface properties of the carbonized materials in the soil environment, and the evaluation of the agronomic and economic effectiveness of soil management with charcoal.

2,514 citations


Additional excerpts

  • ...H outof-plane deformation (Haberhauer et al., 1998)....

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Journal ArticleDOI
TL;DR: A molecular-level assessment of the physical organization and chemical complexity of biomass-derived chars and, specifically, that of aromatic carbon in char structures suggests the existence of four distinct categories of char consisting of a unique mixture of chemical phases and physical states.
Abstract: Char black carbon (BC), the solid residue of incomplete combustion, is continuously being added to soils and sediments due to natural vegetation fires, anthropogenic pollution, and new strategies for carbon sequestration (“biochar”). Here we present a molecular-level assessment of the physical organization and chemical complexity of biomass-derived chars and, specifically, that of aromatic carbon in char structures. Brunauer−Emmett−Teller (BET)−N2 surface area (SA), X-ray diffraction (XRD), synchrotron-based near-edge X-ray absorption fine structure (NEXAFS), and Fourier transform infrared (FT-IR) spectroscopy are used to show how two plant materials (wood and grass) undergo analogous but quantitatively different physical−chemical transitions as charring temperature increases from 100 to 700 °C. These changes suggest the existence of four distinct categories of char consisting of a unique mixture of chemical phases and physical states: (i) in transition chars, the crystalline character of the precursor ma...

2,283 citations

Journal ArticleDOI
TL;DR: In this article, the authors investigated the source of the higher surface charge of BC compared with non-BC by mapping crosssectional areas of BC particles with diameters of 10 to 50 mm for C forms.
Abstract: Black Carbon (BC) may significantly affect nutrient retention and play a key role in a wide range of biogeochemical processes in soils, especially for nutrient cycling. Anthrosols from the Brazilian Amazon (ages between 600 and 8700 yr BP) with high contents of biomassderived BC had greater potential cation exchange capacity (CEC measured at pH 7) per unit organic C than adjacent soils with low BC contents.Synchrotron-based near edge X-ray absorption fine structure (NEXAFS) spectroscopy coupled with scanning transmission X-ray microscopy (STXM) techniques explained the source of the higher surface charge of BC compared with non-BC by mapping crosssectional areas of BC particles with diameters of 10 to 50 mm for C forms. The largest cross-sectional areas consisted of highly aromatic or only slightly oxidized organic C most likely originating from the BC itself with a characteristic peak at 286.1 eV, which could not be found in humic substance extracts, bacteria or fungi. Oxidation significantly increased from the core of BC particles to their surfaces as shown by the ratio of carboxyl-C/aromatic-C. Spotted and non-continuous distribution patterns of highly oxidized C functional groups with distinctly different chemical signatures on BC particle surfaces (peak shift at 286.1 eV to a higher energy of 286.7 eV) indicated that non-BC may be adsorbed on the surfaces of BC particles creating highly oxidized surface. As a consequence of both oxidation of the BC particles themselves and adsorption of organic matter to BC surfaces, the charge density (potential CEC per unit surface area) was greater in BC-rich Anthrosols than adjacent soils. Additionally, a high specific surface area was attributable to the presence of BC, which may contribute to the high CEC found in soils that are rich in BC.

1,932 citations