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Journal ArticleDOI

Spin Correlation Functions at High Temperatures

01 May 1970-Physical Review B (American Physical Society)-Vol. 1, Iss: 9, pp 3815-3830
TL;DR: In this article, a method for the self-consistent calculation of correlation functions is described and applied to the Heisenberg model at high temperatures, based on a straightforward physical picture.
Abstract: A method for the self-consistent calculation of correlation functions is described and applied to the Heisenberg model at high temperatures. The technique is based on a straightforward physical picture. It is used (i) to derive a simple analytic approximation for the autocorrelation function valid at times $t\ensuremath{\lesssim}\frac{2JS}{\ensuremath{\hbar}}$; (ii) to derive an equation given by R\'esibois and DeLeener which is shown to be valid at short times also; (iii) to derive a set of integrodifferential equations for the general correlation functions $〈{\mathrm{S}}_{\ensuremath{-}\mathrm{q}}\ifmmode\cdot\else\textperiodcentered\fi{}{\mathrm{S}}_{\mathrm{q}}(t)〉$. The latter equations are solved numerically for the case of a simple cubic lattice with nearest-neighbor interactions, and are shown to give results in excellent agreement with computer simulation calculations for the same model. A discussion is given of the physical motivation of the approximations employed and the special mathematical aspects of the problem.
Citations
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Journal ArticleDOI
TL;DR: In this paper, the present situation in theoretical and experimental studies on one-dimensional magnetic systems is fully discussed, including equal-time and dynamic properties with an emphasis on the latter.
Abstract: The present situation in theoretical and experimental studies on one-dimensional magnetic systems is fully discussed. Equal-time as well as the dynamic properties are included with an emphasis on the latter. Four model systems are examined in detail: TMMC (Heisenberg antiferromagnet), CsNiF3 (planar ferromagnet), CoCl2. 2NC5H5 (Ising ferromagnet), CuCl2. 2NC5H5 (Heisenberg antiferromagnet with S = ½). The equal-time properties are quite well understood in theory and in experiment but the dynamical properties much less so. The open questions and possible investigations for the future are discussed.

477 citations

Journal ArticleDOI
TL;DR: In this article, a brief review of the spin-iIsing model in a transverse field provides a useful description (insulating magnetic systems, order-disorder ferroelectrics, cooperative Jahn-Teller systems and other systems with 'pseudo-spin'- phonon interactions).
Abstract: A brief review is first made of systems for which the spin-iIsing model in a transverse field provides a useful description (insulating magnetic systems, order-disorder ferroelectrics, cooperative Jahn-Teller systems and other systems with 'pseudo-spin'- phonon interactions). A perturbation expansion is then developed which provides for all temperatures an approximate description of the model. The perturbation series is classified with respect to the small parameter l/z, where z is the number of spins interacting with a given spin; this generates the molecular-field approximation and the random-phase approxi- mation as the lowest-order description of the thermodynamic functions and correlation functions respectively. The leading-order approximations for the correlation functions, susceptibilities and spectral functions are discussed in detail. The formalism, which is the first application of such techniques to systems with varying magnetization direction, provides a basis for subsequent higher-order calculations of the free energy and correlation functions.

250 citations

Journal ArticleDOI
TL;DR: In this paper, the dynamic properties of paramagnets are investigated within a continued fraction representation of the relaxation shape function, and a three-pole approximation is shown on the basis of comparison with computer calculation and neutron scattering measurements on RbMnF3.
Abstract: The dynamic properties of paramagnets are investigated within a continued fraction representation of the relaxation shape function. The approach seeks to isolate the dominant frequency dependence and requires an estimation of the temperature dependence of static spin correlation functions. A three-pole approximation is shown on the basis of comparison with computer calculation and neutron scattering measurements on RbMnF3 to provide a good description of the dynamic properties of one and three dimensional paramagnets over a wide range of wavevectors and temperature.

56 citations

Journal ArticleDOI
TL;DR: In this paper, the effect of resonances and anti-resonances in electron transfer and other applications is discussed, and the condition for maximum coupling is EA=EB (resonance) and is related to a generalised reflection-inversion symmetry while the coupling minimises if VAB=0 (anti-reonance).
Abstract: Two centres A and B connected by one or more sets of bridging states (pathways) define a graph in the space of states. The Hamiltonian is decimated in this space and the problem is reduced to that of two sites with corrected energies EA and EB and an effective interaction VAB. The goal of the method is to make evident how the pathways should be modified in order to tune the resulting coupling. The condition for maximum coupling is EA=EB (resonance) and is related to a generalised reflection-inversion symmetry while the coupling minimises if VAB=0 (anti-resonance). This is a non-trivial situation allowed by the topology of the system which occurs when two or more pathways interfere destructively. The effects of resonances and anti-resonances in electron transfer and other applications are discussed.

53 citations

Journal ArticleDOI
TL;DR: In this article, a method for the approximate calculation of the time-dependent spin correlations at high temperatures is generalized to apply throughout the paramagnetic phase and yields static spin correlations in agreement with the predictions of the spherical model.
Abstract: A method previously presented for the approximate calculation of the time-dependent spin correlations at high temperatures is generalized to apply throughout the paramagnetic phase It yields static spin correlations in agreement with the predictions of the spherical model An ad hoc modification of the approximations is suggested which leads to better agreement of the static correlations with the Pade-approximant determination of the susceptibility in the critical regime The scheme has been used to calculate the inelastic neutron scattering line shapes and widths throughout the paramagnetic phase for the particular case of a simple cubic ferromagnet with nearest neighbour interactions In the critical regime it reproduces the dynamic scaling laws and allows the calculation of some of the associated universal functions The minimum line width is found to occur at a temperature above the critical temperature and the shapes and widths of the lines are found to vary rapidly near the critical point

53 citations