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Journal ArticleDOI

Stable isotopes in precipitation

01 Nov 1964-Tellus A (Wiley/Blackwell (10.1111))-Vol. 16, Iss: 4, pp 436-468
TL;DR: In this paper, the isotopic fractionation of water in simple condensation-evaporation processes is considered quantitatively on the basis of the fractionation factors given in section 1.2.
Abstract: In chapter 2 the isotopic fractionation of water in some simple condensation-evaporation processes are considered quantitatively on the basis of the fractionation factors given in section 1.2. The condensation temperature is an important parameter, which has got some glaciological applications. The temperature effect (the δ's decreasing with temperature) together with varying evaporation and exchange appear in the “amount effect” as high δ's in sparse rain. The relative deuterium-oxygen-18 fractionation is not quite simple. If the relative deviations from the standard water (S.M.O.W.) are called δ D and δ 18 , the best linear approximation is δ D = 8 δ 18 . Chapter 3 gives some qualitative considerations on non-equilibrium (fast) processes. Kinetic effects have heavy bearings upon the effective fractionation factors. Such effects have only been demonstrated clearly in evaporation processes, but may also influence condensation processes. The quantity d = δ D −8 δ 18 is used as an index for non-equilibrium conditions. The stable isotope data from the world wide I.A.E.A.-W.M.O. precipitation survey are discussed in chapter 4. The unweighted mean annual composition of rain at tropical island stations fits the line δ D = 4.6 δ 18 indicating a first stage equilibrium condensation from vapour evaporated in a non-equilibrium process. Regional characteristics appear in the weighted means. The Northern hemisphere continental stations, except African and Near East, fit the line δ D = 8.0 δ 18 + 10 as far as the weighted means are concerned (δ D = 8.1 δ 18 + 11 for the unweighted) corresponding to an equilibrium Rayleigh condensation from vapour, evaporated in a non-equilibrium process from S.M.O.W. The departure from equilibrium vapour seems even higher in the rest of the investigated part of the world. At most stations the δ D and varies linearily with δ 18 with a slope close to 8, only at two stations higher than 8, at several lower than 8 (mainly connected with relatively dry climates). Considerable variations in the isotopic composition of monthly precipitation occur at most stations. At low latitudes the amount effect accounts for the variations, whereas seasonal variation at high latitudes is ascribed to the temperature effect. Tokyo is an example of a mid latitude station influenced by both effects. Some possible hydrological applications are outlined in chapter 5. DOI: 10.1111/j.2153-3490.1964.tb00181.x
Citations
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Journal ArticleDOI
TL;DR: Rooting patterns for terrestrial biomes are analyzed and distributions for various plant functional groups are compared and the merits and possible shortcomings of the analysis are discussed in the context of root biomass and root functioning.
Abstract: Understanding and predicting ecosystem functioning (e.g., carbon and water fluxes) and the role of soils in carbon storage requires an accurate assessment of plant rooting distributions. Here, in a comprehensive literature synthesis, we analyze rooting patterns for terrestrial biomes and compare distributions for various plant functional groups. We compiled a database of 250 root studies, subdividing suitable results into 11 biomes, and fitted the depth coefficient β to the data for each biome (Gale and Grigal 1987). β is a simple numerical index of rooting distribution based on the asymptotic equation Y=1-βd, where d = depth and Y = the proportion of roots from the surface to depth d. High values of β correspond to a greater proportion of roots with depth. Tundra, boreal forest, and temperate grasslands showed the shallowest rooting profiles (β=0.913, 0.943, and 0.943, respectively), with 80-90% of roots in the top 30 cm of soil; deserts and temperate coniferous forests showed the deepest profiles (β=0.975 and 0.976, respectively) and had only 50% of their roots in the upper 30 cm. Standing root biomass varied by over an order of magnitude across biomes, from approximately 0.2 to 5 kg m-2. Tropical evergreen forests had the highest root biomass (5 kg m-2), but other forest biomes and sclerophyllous shrublands were of similar magnitude. Root biomass for croplands, deserts, tundra and grasslands was below 1.5 kg m-2. Root/shoot (R/S) ratios were highest for tundra, grasslands, and cold deserts (ranging from 4 to 7); forest ecosystems and croplands had the lowest R/S ratios (approximately 0.1 to 0.5). Comparing data across biomes for plant functional groups, grasses had 44% of their roots in the top 10 cm of soil. (β=0.952), while shrubs had only 21% in the same depth increment (β=0.978). The rooting distribution of all temperate and tropical trees was β=0.970 with 26% of roots in the top 10 cm and 60% in the top 30 cm. Overall, the globally averaged root distribution for all ecosystems was β=0.966 (r 2=0.89) with approximately 30%, 50%, and 75% of roots in the top 10 cm, 20 cm, and 40 cm, respectively. We discuss the merits and possible shortcomings of our analysis in the context of root biomass and root functioning.

2,554 citations

Book ChapterDOI
02 Apr 2013
TL;DR: The International Atomic Energy Agency (IAEA), in cooperation with the World Meteorological Organization (WMO), has been conducting a world-wide survey of hydrogen (H/'H) and oxygen (O/O) isotope composition of monthly precipitation since 1961.
Abstract: The International Atomic Energy Agency (IAEA), in cooperation with the World Meteorological Organization (WMO), has been conducting a world-wide survey of hydrogen (H/'H) and oxygen (O/O) isotope composition of monthly precipitation since 1961 At present, 72 IAEA/WMO network stations are in operation Another 82 stations belonging to national organizations continue to send their results to the IAEA for publication The paper focuses on basic features of spatial and temporal distribution of deuterium and O in global precipitation, as derived from the IAEA/WMO isotope database The internal structure and basic characteristics of this database are discussed in some detail The existing phenomenological relationships between observed stable isotope composition of precipitation and various climate-related parameters such as local surface air temperature and amount of precipitation are reviewed and critically assessed Attempts are presented towards revealing interannual fluctuations in the accumulated isotope records and relating them to changes of precipitation amount and the surface air temperature over the past 30 years

2,229 citations

Journal ArticleDOI
TL;DR: In this article, the isotope fractionations that accompany the evaporation from the ocean and other surface waters and the reverse process of rain formation account for the most notable changes.
Abstract: Changes of the isotopic composition of water within the water cycle provide a recognizable signature, relating such water to the different phases of the cycle. The isotope fractionations that accompany the evaporation from the ocean and other surface waters and the reverse process of rain formation account for the most notable changes. As a result, meteoric waters are depleted in the heavy isotopic species of H and O relative to ocean waters, whereas waters in evaporative systems such as lakes, plants, and soilwaters are relatively enriched. During the passage through the aquifers, the isotope composition of water is essentially a conservative property at ambient temperatures, but at elevated temperatures, interaction with the rock matrix may perturb the isotope composition. These changes of the isotope composition in atmospheric waters, surface water, soil, and groundwaters, as well as in the biosphere, are applied in the characterization of hydrological system as well as indicators of paleo-climatological conditions in proxy materials in climatic archives, such as ice, lake sediments, or organic materials.

2,010 citations


Cites background or methods from "Stable isotopes in precipitation"

  • ...These are the lines inδ-space whose formula isδ(D) = 8δ(18O)+ d, where d has been named the “deuterium excess” parameter by Dansgaard (1964); obviously the GMWL (Craig 1961b) is one such meteoric water line with d= 10‰....

    [...]

  • ...Since these usually constitute the isotopically most enriched part of the rain [corresponding to the amount effect of Dansgaard (1964)], this selection process introduces a negative bias that cancels the signature of the evaporation process....

    [...]

  • ...On the other hand, as shown in Figure 8, the evaporated moisture’s isotope composition is characterized by larger d-excess value, so that the precipitation derived from an air mass into which the reevaporated moisture is admixed is also characterized by a large d-excess (Dansgaard 1964)....

    [...]

  • ...Indeed, to a good approximation the depletion in isotopic composition in precipitation correlates well with the near-ground temperature, as shown by Dansgaard (1964) and Yurtsever (1975), or more precisely with the temperature at the cloud base (Rindsberger & Magaritz 1983)....

    [...]

  • ...Although the differential form of the Rayleigh equation (Equation 1a) still applies, the integration obviously has to be carried out for a prescribed change ofα throughout the process [as was first demonstrated by Dansgaard (1964)]....

    [...]

Journal ArticleDOI
TL;DR: This paper reviews the use of stable isotope analyses to trace nutritional origin and migration in animals and concludes that this technique will be extremely useful in helping to track migration and movement of a wide range of animals from insects to birds and mammals.
Abstract: To understand the ecology of migratory animals it is important to link geographic regions used by individuals including breeding, wintering, and intermediate stopover sites. Previous conventional approaches used to track animal movements have relied on extrinsic markers and typically the subsequent recovery of individuals. This approach has generally been inappropriate for most small, or non-game animals. The use of intrinsic markers such as fatty acid profiles, molecular DNA analyses, and the measurement of naturally occurring stable isotopes in animal tissues offer alternative approaches. This paper reviews the use of stable isotope analyses (primarily δ13C, δ15N, δ34S, δD, δ87Sr) to trace nutritional origin and migration in animals. This approach relies on the fact that foodweb isotopic signatures are reflected in the tissues of organisms and that such signatures can vary spatially based on a variety of biogeochemical processes. Organisms moving between isotopically distinct foodwebs can carry with them information on the location of previous feeding. Such an approach has been used to track animal use of inshore versus offshore, marine versus freshwater, terrestrial C3 versus marine, terrestrial mesic versus xeric, and C3 versus C4 or Crassulacean acid metabolism foodwebs. More recently, the use of stable hydrogen isotope analyses (δD) to link organisms to broad geographic origin in North America is based on large-scale isotopic contours of growing-season average δD values in precipitation. This technique, especially when combined with the assay of other stable isotopes, will be extremely useful in helping to track migration and movement of a wide range of animals from insects to birds and mammals. Future research to refine our understanding of natural and anthropogenic-induced isotopic gradients in nature, and to explore the use of stable isotopes of other elements, is recommended.

1,628 citations

Journal ArticleDOI
TL;DR: In this article, the authors provide an overview of isotope dendroclimatology, explaining the underlying theory and describing the steps taken in building and interpreting isotope chronologies.

1,531 citations

References
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Journal ArticleDOI
26 May 1961-Science
TL;DR: The relationship between deuterium and oxygen-18 concentrations in natural meteoric waters from many parts of the world has been determined with a mass spectrometer and shows a linear correlation over the entire range for waters which have not undergone excessive evaporation.
Abstract: The relationship between deuterium and oxygen-18 concentrations in natural meteoric waters from many parts of the world has been determined with a mass spectrometer. The isotopic enrichments, relative to ocean water, display a linear correlation over the entire range for waters which have not undergone excessive evaporation.

6,721 citations

Journal ArticleDOI
TL;DR: A number of marine water and fresh water samples were examined for the relative O18O16 ratio, and the variation of this ratio was determined to a precision of ± 1% as mentioned in this paper.

3,113 citations

Journal ArticleDOI
09 Jun 1961-Science
TL;DR: A standard, based on the set of ocean water samples used by Epstein and Mayeda to obtain a reference standard for oxygen-18 data, but defined relative to the National Bureau of Standards isotopic reference water sample, is proposed for reporting both deuterium and oxygen- 18 variations in natural watersrelative to the same water.
Abstract: A standard, based on the set of ocean water samples used by Epstein and Mayeda to obtain a reference standard for oxygen-18 data, but defined relative to the National Bureau of Standards isotopic reference water sample, is proposed for reporting both deuterium and oxygen-18 variations in natural waters relative to the same water. The range of absolute concentrations of both isotopes in meteoric-waters is discussed.

1,773 citations

Journal ArticleDOI
TL;DR: A mass spectrometric method for the accurate determination of the hydrogen-deuterium ratio has been developed as mentioned in this paper, which is possible to determine this ratio to ± 0.10% using material of "normal abundance" (i.e., 1 part D in 6700 parts H).

603 citations

Journal ArticleDOI
TL;DR: The deuterium and oxygen 18 concentrations of water evaporating into air of nonzero humidity do not follow the simple batch distillation equation but increase asymptotically to a stationary isotopic state as the mass of water decreases to zero as discussed by the authors.
Abstract: The deuterium and oxygen 18 concentrations of water evaporating into air of nonzero humidity do not follow the simple batch distillation equation but increase asymptotically to a stationary isotopic state as the mass of water decreases to zero. This effect is due to a rapid molecular exchange between liquid and vapor, which predominates over the simple separation effect of removal of vapor. In diy air the batch distillation law is obeyed, and the isotopic enrichment continually increases; however, the separation factor is larger than the equilibrium isotopic vapor pressure ratio when the evaporation rate is comparable to natural rates. The HDO and H2O18 enrichments in our experiments show a linear correlation with a slope of about 5.5, as found in the evaporation of natural water bodies. The mechanism of the molecular exchange will be described in following papers.

319 citations