Journal ArticleDOI
Studies on the reactivity of oxodihalobis(diethyldithiocarbamato) molybdenum(VI) and tungsten(VI) complexes
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The complexes OMoX 2 L 2 (L = S 2 )CNEt 2 ) 2 and OMoXL 2 (X = Cl, Br) as mentioned in this paper showed the lack of atom transfer ability of tungsten(VI) relative to its molybdenum analog.About:
This article is published in Inorganica Chimica Acta.The article was published on 1980-01-01. It has received 10 citations till now.read more
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Kinetic study on the reaction of cis-dioxo-(N-(5-X-salicylidene)-2-aminobenzenethiolato) molybdenum(VI) with ethyldiphenylphosphine
Joseph Topich,James T. Lyon +1 more
TL;DR: In this article, the reactions of ethyldiphenylphosphine with a number of cis-dioxomolybdenum(VI) Schiff base coordination complexes are described.
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Kinetic study of the oxidation of ethyldiphenylphosphine by cis-dioxo-[N-(5-X-salicylidene)-2-aminoethanethiolato] molybdenum(VI)
Joseph Topich,James T. Lyon +1 more
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Six-coordinate monooxo molybdenum(VI) complexes with N-4-diethylaminosalicylidene-N′-4-nitrobenzoyl hydrazine and catechol ligands: preparation and spectroscopic properties
TL;DR: In this paper, preparation and spectroscopic characterization for monooxo molybdenum (VI) complexes, MoO(cat)L, where L 2− ǫ=dianion of N -4-diethylaminosalicylidene- N ′-4-nitrobenzoyl hydrazine and cat 2−ǫ = catecholate (Cat 2− ), 4-methylcatecholate(Cat 2 − ), 4 -methylcacetolate (Mecat 2−), 3,5
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Illusive tungsten-imido-dithiocarbamate complexes: Facile carbon–nitrogen bond formation
TL;DR: In this article, it was shown that bis(imido) complexes can be obtained from the direct reaction of isocyanates (or amines) with [WO 2 (S 2 CNBu i 2 ) 2 ] in which both imido groups are linear.
References
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Synthesis of molybdenum(IV) and molybdenum(V) complexes using oxo abstraction by phosphines. Mechanistic implications
TL;DR: The Reaktionen der Mo(VI)-Verbindungen (I) mit tert. as discussed by the authors demonstrieren einen bequemen Weg zur Darstellung von Mo(V)-Spezies wie (IIa), (IIb) und (IIc).
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Molecular Basis of the Biological Function of Molybdenum MOLYBDENUM-FREE SULFITE OXIDASE FROM LIVERS OF TUNGSTEN-TREATED RATS
TL;DR: The difference spectrum of oxidized native sulfite oxidase minus inactive protein revealed subtle differences in the environments of the heme prosthetic group, hydrophobic aromatic residues, and possibly sulfhydrylmolybdenum linkages.
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Preparation and characterization of two series of dimeric molybdenum(V) N,N-dialkyldithiocarbamates. Their interrelation and chemistry as a model for the active site of nitrogenase
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The molybdenum site of xanthine oxidase. Structural evidence from x-ray absorption spectroscopy
TL;DR: In this article, extended x-ray absorption fine structure (EXAFS) data indicate that reduced xanthine oxidase contains molybdenum in the four valence oxidation state.
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The molybdenum site of sulfite oxidase. Structural information from x-ray absorption spectroscopy
TL;DR: In this article, a detailed structural model for the sulfite oxidase molybdenum site was proposed by correlating the Mo K-absorption edge changes with a variety of model compounds, and curve fitting the x-ray absorption fine structure data with previously determined phase shift and amplitude functions.