Journal ArticleDOI
Study of SiGe oxidation kinetics for preferential SiO2 formation under a low O2 pressure condition
Woojin Song,Akira Toriumi +1 more
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TLDR
In this article, the authors studied the oxidation kinetics of SiGe as parameters of O2 pressure and temperature and found that Si was predominantly oxidized in the Si 0.5Ge0.5 oxidation under lower O2 pressures.Abstract:
We have studied the oxidation kinetics of SiGe as parameters of O2 pressure and temperature. This paper first discusses the SiGe oxidation experimentally and thermodynamically. It was found that Si was predominantly oxidized in the Si0.5Ge0.5 oxidation under lower O2 pressures. This fact is thermodynamically reasonable, but the Ge remaining after Si oxidation may be a big concern in terms of SiGe gate stacks, because it should form defects at the interface or inside the SiO2 film. Therefore, it is critically important to understand how the Ge atoms behave after the SiO2 formation. Second, the GeO2/Si reaction, which might be a key part to well controlled SiGe gate stacks in the preferential SiO2 formation, is discussed. Two kinds of metallic Ge formation kinetics at the SiGe interface in the annealing of GeO2/Si are conjectured: One is the metallic Ge diffusion into the Si substrate and the other is the Ge precipitation at the interface, which should be avoided for improving the SiGe interface properties. The experimental results indicate that the former case is made possible by annealing under the low O2 pressure condition in a very thin SiO2 formation region.read more
Citations
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Journal ArticleDOI
Impact of metal gate electrodes on electrical properties of Y2O3/Si0.78Ge0.22 gate stacks
Tsung-En Lee,Kimihiko Kato,Mengnan Ke,Kasidit Toprasertpong,Mitsuru Takenaka,Shinichi Takagi +5 more
TL;DR: In this paper, the physical origins of interface trap density reduction are examined from the viewpoint of the composition and the quality of interfacial layers (ILs) of Y2O3/SiGe metal-oxide-semiconductor (MOS) capacitors.
Journal ArticleDOI
Improving Interface State Density and Thermal Stability of High- $\kappa$ Gate Stack Through High-Vacuum Annealing on Si 0.5 Ge 0.5
TL;DR: In this article, HfO2-based gate stacks were fabricated on epi-Si0.5Ge 0.5 substrates and investigated the effect of thermal treatment on their structural and electrical properties at varying temperatures and pressures in oxygen ambient.
Journal ArticleDOI
Experimental study of the ultrathin oxides on SiGe alloy formed by low-temperature ozone oxidation
Xueli Ma,Xiaolei Wang,Lixing Zhou,Hao Xu,Yuanyuan Zhang,Jiahui Duan,Jinjuan Xiang,Hong Yang,Junjie Li,Yongliang Li,Huaxiang Yin,Wenwu Wang +11 more
Journal ArticleDOI
Reaction of GeO2 with Ge and crystallization of GeO2 on Ge
TL;DR: In this paper, a nonuniform reaction at the GeO2/Ge interface is observed on the initially flat Ge surface (rms: 0.3 nm) and crystalline Ge islands are demonstrated to form on Si.
Journal ArticleDOI
Strain evaluation in Ge and Sn implanted Si layers with laser and rapid thermal annealing
Shota Komago,Ryo Yokogawa,Kazutoshi Yoshioka,John Borland,Takashi Kuroi,Yoji Kawasaki,Atsushi Ogura +6 more
TL;DR: In this article, the authors evaluated the strain in Si layers annealed with laser or rapid thermal annealing (RTA) after Ge and Sn ion implantation, and found that the induced strain for the Sn-implanted SiGe after the RTA was more compressive than that for the SiGeafter the laser-annealing.
References
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Journal ArticleDOI
Oxidation studies of SiGe
TL;DR: In this paper, the authors studied the kinetics and mechanism of oxidation of SiGe alloys deposited epitaxially onto Si substrates by low-temperature chemical vapor deposition and demonstrated that Ge plays a purely catalytic role, i.e., it enhances the reaction rate while remaining unchanged itself.
Journal ArticleDOI
Fabrication of strained Si on an ultrathin SiGe-on-insulator virtual substrate with a high-Ge fraction
TL;DR: In this article, a promising fabrication method for a Si1−xGex-on-insulator (SGOI) virtual substrate and evaluation of strain in the Si layer on this SGOI substrate are presented.
Journal ArticleDOI
Desorption kinetics of GeO from GeO2/Ge structure
Shengkai Wang,Koji Kita,Lee Choonghyun,Toshiyuki Tabata,Tomonori Nishimura,Kosuke Nagashio,Akira Toriumi +6 more
TL;DR: In this paper, the desorption kinetics of germanium monoxide (GeO), including the diffusion process during GeO desoruption, the desoreption activation energy of GeO, and the different mechanisms of geO desoroption.
Journal ArticleDOI
Oxidation of Si1−xGex alloys at atmospheric and elevated pressure
TL;DR: In this paper, the authors explored the fundamental differences in the thermodynamics of the process and the kinetics of the oxidation reaction of alloys of Si1−xGex.
Journal ArticleDOI
Composition dependence of Si and Ge diffusion in relaxed Si1−xGex alloys
R. Kube,Hartmut Bracht,J. Lundsgaard Hansen,A. Nylandsted Larsen,E. E. Haller,S. Paul,Wilfried Lerch +6 more
TL;DR: In this paper, the diffusion of silicon (Si) and germanium (Ge) in silicon-germanium Si1−xGex-isotope heterostructures with Ge contents x=0, 0.05, 0., 25, and 0.70 was investigated in a temperature range between 690 and 1270 °C.