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Study of Solution Grown Variable BandGap Pb1 − x Mn x S Semiconductor Nanoparticle Films

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TLDR
In this article, a single-phase Pb 1-x Mn x S (0.03 ≤ x ≤ 0.37) nanoparticle films were prepared using an electroless solution growth technique.
Abstract
Single-phase Pb 1-x Mn x S (0.03 ≤ x ≤ 0.37) nanoparticle films were prepared using an electroless solution growth technique. Face centered cubic structure with a decrease of lattice parameter for an increase of x in the alloy films was observed. Composition dependence of optical and electrical properties is discussed. The optical bandgap (E g ) could be varied from 1.50 to 2.50 eV by changing the x in the range 0.03 ≤ x ≤ 0.37 for the films. Effect of the grain size and the effect of alloying on optical properties are distinguished for the ternary nanoparticle films. Variable range hopping has been identified as mechanism for conduction in the p-type semiconductor Pb 1-x Mn x S nanoparticle films. Mobility (μ of the majority carriers shows a decrease with increase in Mn concentration x and follows a T -0.4 temperature dependence, indicating the surface scattering of carriers in the nanoparticle films.

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Citations
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Journal ArticleDOI

Recent status of chemical bath deposited metal chalcogenide and metal oxide thin films

TL;DR: In this article, a review is presented on the status of synthesizing thin films of metal chalcogenide and metal oxides by CBD and SILAR, and properties and applications of the thin films are also summarized.
Journal ArticleDOI

Improved performance of CdS/CdSe quantum dot-sensitized solar cells using Mn-doped PbS quantum dots as a catalyst in the counter electrode

TL;DR: In this article, the performance of Mn-doped PbS counter electrode was compared with those using the bare Pt/PbS/PBS counter electrode, achieving a power conversion efficiency of 361% under one sun illumination (100mW cm −2 ).
Journal ArticleDOI

Optical properties of (Pb 1- x Mn x S) 1- y Fe y materials from first-principles calculations

TL;DR: In this article, a theoretical study of the optical properties of Pb 0.25 Mn 0.125 S in the framework of the density functional theory using the linearized-augmented plane-wave method is reported in order to predict new optical materials for continuous-wave lasers.
Journal ArticleDOI

Mid-IR band gap engineering of CdxPb1−xS nanocrystals by mechanochemical reaction

Guolong Tan, +2 more
- 03 Jun 2014 - 
TL;DR: In this paper, a physical mechanical alloying (MA) process was applied to prepare tens of grams of surface clean Cdx Pb 1−xS nanocrystals within the composition range of x = 0.0 to 0.4.
Journal ArticleDOI

3-D Atomic-Scale Mapping of Manganese Dopants in Lead Sulfide Nanowires

TL;DR: In this paper, the authors study vapor-liquid-solid grown manganese-doped lead sulfide nanowires by atom-probe tomography for the first time for lead salt materials.
References
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Book

Handbook of Optical Constants of Solids

TL;DR: In this paper, E.D. Palik and R.R. Potter, Basic Parameters for Measuring Optical Properties, and W.W.Hunter, Measurement of Optical Constants in the Vacuum Ultraviolet Spectral Region.
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Elements of X-ray diffraction

TL;DR: In this article, the authors present a chemical analysis of X-ray diffraction by Xray Spectrometry and phase-diagram Determination of single crystal structures and phase diagrams.
Journal ArticleDOI

Synthesis and characterization of nearly monodisperse CdE (E = sulfur, selenium, tellurium) semiconductor nanocrystallites

TL;DR: In this paper, a simple route to the production of high-quality CdE (E=S, Se, Te) semiconductor nanocrystallites is presented, based on pyrolysis of organometallic reagents by injection into a hot coordinating solvent.
Book

Electronic processes in non-crystalline materials

TL;DR: The Fermi Glass and the Anderson Transition as discussed by the authorsermi glass and Anderson transition have been studied in the context of non-crystalline Semiconductors, such as tetrahedrally-bonded semiconductors.
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