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Summary and Comparison of Properties of the Actinide and Transactinide Elements

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TLDR
This chapter provides an opportunity to discuss the biological and environmental aspects of the actinide elements, subjects that were barely mentioned in the first edition of this work and discussed only briefly in the second edition, but have assumed great importance in recent years.
Abstract
This chapter is intended to provide a unified view of selected aspects of the physical, chemical, and biological properties of the actinide elements, their typical compounds, and their ions in aqueous solutions The f–block elements have many unique features, and a comparison of similar species of the lanthanide and actinide transition series provides valuable insights into the properties of both Comparative data are presented on the electronic configurations, oxidation states, oxidation–reduction (redox) potentials, thermochemical data, crystal structures, and ionic radii of the actinide elements, together with important topics related to their environmental properties and toxicology Many of the topics in this chapter, and some that are not discussed here, are the subjects of subsequent chapters of this work, which should be consulted for more comprehensive treatments This chapter provides an opportunity to discuss the biological and environmental aspects of the actinide elements, subjects that were barely mentioned in the first edition of this work and discussed only briefly in the second edition, but have assumed great importance in recent years This chapter also provides a summary of the chemical properties of the transactinide elements that have been characterized

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Citations
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Journal ArticleDOI

Extraction of Lanthanide and Actinide Ions from Aqueous Mixtures Using a Carboxylic Acid-Functionalized Porous Aromatic Framework

TL;DR: A study of the adsorption of selected metal ions, Sr2+, Fe3+, Nd3+, and Am3+, from aqueous solutions employing a carbon-based porous aromatic framework, BPP-7 (Berkeley Porous Polymer-7), which displays high metal loading capacities together with excellent Adsorption selectivity for neodymium over strontium.
Journal ArticleDOI

Exploring actinide materials through synchrotron radiation techniques

TL;DR: In this review, recent research progresses on actinide related materials by means of various SR techniques were selectively highlighted and summarized, with the emphasis on X-ray absorption spectroscopy,X-ray diffraction and scattering spectroscology, which are powerful tools to characterize actinid materials.
Journal ArticleDOI

Development of Targeted Alpha Particle Therapy for Solid Tumors.

TL;DR: This comprehensive review discusses the current consensus regarding the properties of the α-particle-emitting radionuclides that are potentially relevant for use in the clinic; the TAT-mediated mechanisms responsible for cell death; the different classes of targeting moieties and radiometal chelators available for TAT development; current approaches to calculating radiation dosimetry for T ATs; and lead optimization via medicinal chemistry to improve the T AT radiopharmaceutical properties.
Journal ArticleDOI

Persistent Superprotonic Conductivity in the Order of 10−1 S·cm−1 Achieved Through Thermally Induced Structural Transformation of a Uranyl Coordination Polymer

TL;DR: Despite tremendous efforts being made in the exploration of new highperformance proton-conducting materials, studies on systems with superprotonic conductivity higher than 10−1 S·cm−1 remain scarc...
Journal ArticleDOI

Prospects for laser spectroscopy, ion chemistry and mobility measurements of superheavy elements in buffer-gas traps

TL;DR: In this paper, a review of laser spectroscopic methods for the investigation of atomic and ionic level structures of superheavy elements is presented, which are defined as the trans-fermium elements with Z > 100 and which cannot be bred in high flux nuclear power reactors via successive neutron capture.
References
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Journal ArticleDOI

Revised effective ionic radii and systematic studies of interatomic distances in halides and chalcogenides

TL;DR: The effective ionic radii of Shannon & Prewitt [Acta Cryst. (1969), B25, 925-945] are revised to include more unusual oxidation states and coordinations as mentioned in this paper.

Recommendations of the international commission on radiological protection

R.M. Sievert, +1 more
TL;DR: Recommendations are presented which represent concepts and practices evolved from recent discussions at formal and informal meetings of the Commission and its Committees.
Book

Hydrolysis of Cations